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Milan Gembicky

Title(s)RSCH AND DEV ENGR 4, Chemistry and Biochemistry
SchoolVc-academic Affairs
Address9500 Gilman Drive #0358
La Jolla CA 92093
Phone8/8-22--4903
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    1. Aqueous Stability and Ligand Substitution of a Layered Cu(I)/Isocyanide-Based Organometallic Network Material with a Well-Defined Channel Structure. Inorg Chem. 2020 Aug 19. Arroyave A, Gembicky M, Rheingold AL, Figueroa JS. PMID: 32813502.
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    2. Cation-Controlled Assembly of Polyoxotungstate-Based Coordination Networks. Angew Chem Int Ed Engl. 2020 Jun 02. Chen L, Turo MJ, Gembicky M, Reinicke RA, Schimpf AM. PMID: 32488927.
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    3. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
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    4. Tunable Metal Oxide Frameworks via Coordination Assembly of Preyssler-Type Molecular Clusters. J Am Chem Soc. 2019 12 26; 141(51):20261-20268. Chen L, San KA, Turo MJ, Gembicky M, Fereidouni S, Kalaj M, Schimpf AM. PMID: 31775506.
      View in: PubMed   Mentions: 1     Fields:    
    5. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed ß-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
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    6. Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C-H Bond Activation in a Tris(aryloxide)mesitylene Ligand System. Inorg Chem. 2018 Oct 15; 57(20):12876-12884. Palumbo CT, Halter DP, Voora VK, Chen GP, Ziller JW, Gembicky M, Rheingold AL, Furche F, Meyer K, Evans WJ. PMID: 30246533.
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    7. Covalent attachment of [Ni(alkynyl-cyclam)]2+ catalysts to glassy carbon electrodes. Chem Commun (Camb). 2018 Apr 19; 54(33):4116-4119. Zhanaidarova A, Moore CE, Gembicky M, Kubiak CP. PMID: 29620782.
      View in: PubMed   Mentions: 2     Fields:    
    8. Electrocatalytic H2O Reduction with f-Elements: Mechanistic Insight and Overpotential Tuning in a Series of Lanthanide Complexes. J Am Chem Soc. 2018 02 21; 140(7):2587-2594. Halter DP, Palumbo CT, Ziller JW, Gembicky M, Rheingold AL, Evans WJ, Meyer K. PMID: 29378127.
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    9. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. J Am Chem Soc. 2017 12 06; 139(48):17257-17260. Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa JS. PMID: 29131949.
      View in: PubMed   Mentions:    Fields:    Translation:Cells
    10. Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2. Chem Commun (Camb). 2017 Aug 11; 53(62):8664-8666. Huh DN, Kotyk CM, Gembicky M, Rheingold AL, Ziller JW, Evans WJ. PMID: 28722066.
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    11. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
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    12. Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides. J Am Chem Soc. 2016 11 23; 138(46):15138-15141. Agnew DW, Gembicky M, Moore CE, Rheingold AL, Figueroa JS. PMID: 27802031.
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    13. Thiocyanate-Ligated Heterobimetallic {PtM} Lantern Complexes Including a Ferromagnetically Coupled 1D Coordination Polymer. Inorg Chem. 2016 Aug 15; 55(16):8099-109. Guillet JL, Bhowmick I, Shores MP, Daley CJ, Gembicky M, Golen JA, Rheingold AL, Doerrer LH. PMID: 27486841.
      View in: PubMed   Mentions: 2     Fields:    
    14. Erratum: (Glycol-?O,O')nitros-yl(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e26. Munie S, Larsen A, Gembicky M. PMID: 21578981.
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    15. Erratum: Di-µ-nitrosyl-bis-[(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(0)](Ru-Ru). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e25. Pearsal M, Gembicky M, Dominiak P, Larsen A, Coppens P. PMID: 21578980.
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    16. Ligand-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand in ruthenium-based metathesis catalysts. J Am Chem Soc. 2009 May 20; 131(19):6822-32. Galan BR, Pitak M, Gembicky M, Keister JB, Diver ST. PMID: 19397262.
      View in: PubMed   Mentions: 3     Fields:    
    17. Capturing and analyzing the excited-state structure of a Cu(I) phenanthroline complex by time-resolved diffraction and theoretical calculations. J Am Chem Soc. 2009 May 13; 131(18):6566-73. Vorontsov II, Graber T, Kovalevsky AY, Novozhilova IV, Gembicky M, Chen YS, Coppens P. PMID: 19378949.
      View in: PubMed   Mentions: 7     Fields:    
    18. Charge density analysis of the (C-C)-->Ti agostic interactions in a titanacyclobutane complex. J Am Chem Soc. 2009 May 06; 131(17):6154-60. Scheins S, Messerschmidt M, Gembicky M, Pitak M, Volkov A, Coppens P, Harvey BG, Turpin GC, Arif AM, Ernst RD. PMID: 19366267.
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    19. The RATIO method for time-resolved Laue crystallography. J Synchrotron Radiat. 2009 Mar; 16(Pt 2):226-30. Coppens P, Pitak M, Gembicky M, Messerschmidt M, Scheins S, Benedict J, Adachi SI, Sato T, Nozawa S, Ichiyanagi K, Chollet M, Koshihara SY. PMID: 19240334.
      View in: PubMed   Mentions: 17     Fields:    
    20. Competitive isomerization and dimerization in co-crystals of 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol and sorbic acid: a new look at stereochemical requirements for [2+2] dimerization. Chem Commun (Camb). 2008 Jun 14; (22):2538-40. Zheng SL, Pham O, Vande Velde CM, Gembicky M, Coppens P. PMID: 18506236.
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    21. (Glycol-?O,O')nitros-yl(?-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 04; 64(Pt 2):m293. Munie S, Larsen A, Gembicky M. PMID: 21201270.
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    22. Supramolecular solids as a medium for single-crystal-to-single-crystal E/Z photoisomerization: kinetic study of the photoreactions of two Zn-coordinated tiglic acid molecules. Chemistry. 2008; 14(2):706-13. Zheng SL, Vande Velde CM, Messerschmidt M, Volkov A, Gembicky M, Coppens P. PMID: 17955556.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    23. Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization. Chem Commun (Camb). 2007 Jun 21; (23):2399-401. Zhang J, Gembicky M, Messerschmidt M, Coppens P. PMID: 17844759.
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    24. A kHz heat-load shutter for white-beam experiments at synchrotron sources. J Synchrotron Radiat. 2007 May; 14(Pt 3):295-6. Gembicky M, Adachi SI, Coppens P. PMID: 17435306.
      View in: PubMed   Mentions: 1     Fields:    
    25. On the design of ultrafast shutters for time-resolved synchrotron experiments. J Synchrotron Radiat. 2007 Jan; 14(Pt 1):133-7. Gembicky M, Coppens P. PMID: 17211080.
      View in: PubMed   Mentions: 2     Fields:    
    26. Effect of the environment on molecular properties: synthesis, structure, and photoluminescence of Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) nanoclusters in eight different supramolecular frameworks. Inorg Chem. 2006 Nov 13; 45(23):9281-9. Zheng SL, Gembicky M, Messerschmidt M, Dominiak PM, Coppens P. PMID: 17083227.
      View in: PubMed   Mentions: 4     Fields:    
    27. Carbon monoxide-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand: Buchner reaction in a ruthenium carbene complex. J Am Chem Soc. 2005 Nov 16; 127(45):15702-3. Galan BR, Gembicky M, Dominiak PM, Keister JB, Diver ST. PMID: 16277502.
      View in: PubMed   Mentions: 4     Fields:    
    28. A fast mechanical shutter for submicrosecond time-resolved synchrotron experiments. J Synchrotron Radiat. 2005 Sep; 12(Pt 5):665-9. Gembicky M, Oss D, Fuchs R, Coppens P. PMID: 16120992.
      View in: PubMed   Mentions: 4     Fields:    
    29. Two novel bis(2,9-dimethyl-1,10-phenanthroline)copper(I) complexes: [Cu(dmp)2]2(PF6)2.0.5(bpmh).CH3CN and [Cu(dmp)2][N(CN)2]. Acta Crystallogr C. 2005 Jul; 61(Pt 7):m329-32. King G, Gembicky M, Coppens P. PMID: 15997055.
      View in: PubMed   Mentions: 2     Fields:    
    30. Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction. Phys Rev Lett. 2005 May 20; 94(19):193003. Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV, Omary MA, Coppens P. PMID: 16090170.
      View in: PubMed   Mentions: 5     Fields:    
    31. The structure of short-lived excited states of molecular complexes by time-resolved X-ray diffraction. Acta Crystallogr A. 2005 Mar; 61(Pt 2):162-72. Coppens P, Vorontsov II, Graber T, Gembicky M, Kovalevsky AY. PMID: 15724066.
      View in: PubMed   Mentions: 11     Fields:    
    32. Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties. Inorg Chem. 2004 Dec 27; 43(26):8282-9. Kovalevsky AY, Gembicky M, Coppens P. PMID: 15606174.
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    33. A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction. Chem Commun (Camb). 2004 Oct 07; (19):2144-5. Coppens P, Gerlits O, Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV. PMID: 15467843.
      View in: PubMed   Mentions: 5     Fields:    
    34. Geometry changes of a Cu(I) phenanthroline complex on photoexcitation in a confining medium by time-resolved X-ray diffraction. J Am Chem Soc. 2004 May 19; 126(19):5980-1. Coppens P, Vorontsov II, Graber T, Kovalevsky AY, Chen YS, Wu G, Gembicky M, Novozhilova IV. PMID: 15137759.
      View in: PubMed   Mentions: 1     Fields:    
    35. Solid-state structure dependence of the molecular distortion and spectroscopic properties of the Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) ion. Inorg Chem. 2003 Dec 29; 42(26):8794-802. Kovalevsky AY, Gembicky M, Novozhilova IV, Coppens P. PMID: 14686859.
      View in: PubMed   Mentions: 2     Fields:    
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