Milan Gembicky

Title(s)RSCH AND DEV ENGR 4, Chemistry and Biochemistry
SchoolVc-academic Affairs
Address9500 Gilman Drive #
La Jolla CA 92093
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    1. Identification of clickable HIV-1 capsid-targeting probes for viral replication inhibition. Cell Chem Biol. 2024 Mar 21; 31(3):477-486.e7. McFadden WM, Casey-Moore MC, Bare GAL, Kirby KA, Wen X, Li G, Wang H, Slack RL, Snyder AA, Lorson ZC, Kaufman IL, Cilento ME, Tedbury PR, Gembicky M, Olson AJ, Torbett BE, Sharpless KB, Sarafianos SG. PMID: 38518746.
      View in: PubMed   Mentions:    Fields:    Translation:Cells
    2. Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets. J Am Chem Soc. 2024 Mar 20; 146(11):7243-7256. Bernbeck MG, Orlova AP, Hilgar JD, Gembicky M, Ozerov M, Rinehart JD. PMID: 38456803; PMCID: PMC10958522.
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    3. Exploring the Versatility of the Amidation of Aryl Acid Fluorides using the Germylamines R3 GeNMe2. Chem Asian J. 2023 Dec 14; 18(24):e202300788. Fortney VA, Murphy JK, Stancil TR, Gembicky M, Rheingold AL, Weinert CS. PMID: 37883375.
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    4. Molecular Network Approach to Anisotropic Ising Lattices: Parsing Magnetization Dynamics in Er3+ Systems with 0-3-Dimensional Spin Interactivity. J Am Chem Soc. 2023 Oct 11; 145(40):22265-22275. Orlova AP, Varley MS, Bernbeck MG, Kirkpatrick KM, Bunting PC, Gembicky M, Rinehart JD. PMID: 37774116; PMCID: PMC10571078.
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    5. A crystalline doubly oxidized carbene. Nature. 2023 Nov; 623(7985):66-70. Loh YK, Melaimi M, Gembicky M, Munz D, Bertrand G. PMID: 37730995.
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    6. Vertex Differentiation Strategy for Tuning the Physical Properties of closo-Dodecaborate Weakly Coordinating Anions. Inorg Chem. 2023 Sep 18; 62(37):15084-15093. Nelson YA, Irshad A, Kim S, Waddington MA, Salamat CZ, Gembicky M, Rheingold AL, Carta V, Tolbert SH, Narayan SR, Spokoyny AM. PMID: 37667823.
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    7. Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers. Angew Chem Int Ed Engl. 2023 Aug 14; 62(33):e202305404. Lorkowski J, Bouetard D, Yorkgitis P, Gembicky M, Roisnel T, Vanthuyne N, Munz D, Favereau L, Bertrand G, Mauduit M, Jazzar R. PMID: 37221132.
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    8. Electrochemical Cycling of Redox-Active Boron Cluster-Based Materials in the Solid State. J Am Chem Soc. 2023 Jul 05; 145(26):14345-14353. Ready AD, Irshad A, Kallistova A, Carrillo M, Gembicky M, Seshadri R, Narayan S, Spokoyny AM. PMID: 37351898.
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    9. Synthesis and crystal structure of bis-(2-phthal-imido-eth-yl)ammonium chloride dihydrate. Acta Crystallogr E Crystallogr Commun. 2023 May 01; 79(Pt 6):575-577. Young BS, Lee JL, Gembicky M, Bailey J, Smith GLN. PMID: 37288457; PMCID: PMC10242743.
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    10. Arene C-H borylation strategy enabled by a non-classical boron cluster-based electrophile. Nat Commun. 2023 Mar 25; 14(1):1671. Kim S, Treacy JW, Nelson YA, Gonzalez JAM, Gembicky M, Houk KN, Spokoyny AM. PMID: 36966132; PMCID: PMC10039867.
      View in: PubMed   Mentions: 1     Fields:    
    11. Structurally Diverse Bench-Stable Nickel(0) Pre-Catalysts: A Practical Toolkit for In Situ Ligation Protocols. Angew Chem Int Ed Engl. 2023 Feb 20; 62(9):e202211794. Tran VT, Kim N, Rubel CZ, Wu X, Kang T, Jankins TC, Li ZQ, Joannou MV, Ayers S, Gembicky M, Bailey J, Sturgell EJ, Sanchez BB, Chen JS, Lin S, Eastgate MD, Wisniewski SR, Engle KM. PMID: 36524997; PMCID: PMC9987410.
      View in: PubMed   Mentions: 1     Fields:    
    12. Programmable synthesis of well-defined, glycosylated iron(ii) supramolecular assemblies with multivalent protein-binding capabilities. Chem Sci. 2023 Jan 25; 14(4):1018-1026. Schwab JH, Bailey JB, Gembicky M, Stauber JM. PMID: 36755719; PMCID: PMC9890585.
      View in: PubMed   Mentions: 1  
    13. PM-IRRAS and DFT investigation of the surface orientation of new Ir piano-stool complexes attached to Au(111). Dalton Trans. 2022 Nov 29; 51(46):17688-17699. Miller CJ, Brunner FM, Kelly HR, Cheung PL, Torquato NA, Gembicky M, Okuno S, Chan T, Batista VS, Kubiak CP. PMID: 36345597.
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    14. Elemental, fatty acid, and protein composition of appendicoliths. Sci Rep. 2022 11 17; 12(1):19764. Prieto JM, Wang AW, Halbach J, Cauvi DM, Day JMD, Gembicky M, Ghassemian M, Quehenberger O, Kling K, Ignacio R, DeMaio A, Bickler SW. PMID: 36396724; PMCID: PMC9671961.
      View in: PubMed   Mentions:    Fields:    Translation:Humans
    15. Mixed-Isocyanide Complexes of Technetium under Steric and Electronic Control. Inorg Chem. 2022 Oct 10; 61(40):16163-16176. Claude G, Genz J, Weh D, Roca Jungfer M, Hagenbach A, Gembicky M, Figueroa JS, Abram U. PMID: 36167508.
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    16. PEG-Infiltrated Polyoxometalate Frameworks with Flexible Form-Factors. ACS Mater Lett. 2022 Oct 03; 4(10):1937-1943. Alves LS, Chen L, Lemmon CE, Gembicky M, Xu M, Schimpf AM. PMID: 36213253; PMCID: PMC9533303.
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    17. Synthesis, structure and reactivity of μ3-SnH capped trinuclear nickel cluster. Chem Sci. 2022 Oct 05; 13(38):11382-11387. Torquato NA, Palasz JM, Bertrand QC, Brunner FM, Chan T, Gembicky M, Mrse AA, Kubiak CP. PMID: 36320577; PMCID: PMC9533397.
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    18. Intuitive Control of Low-Energy Magnetic Excitations via Directed Dipolar Interactions in a Series of Er(III)-Based Complexes. J Am Chem Soc. 2022 06 29; 144(25):11316-11325. Orlova AP, Hilgar JD, Bernbeck MG, Gembicky M, Rinehart JD. PMID: 35713679.
      View in: PubMed   Mentions: 3     Fields:    
    19. Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes. Nat Chem. 2022 06; 14(6):632-639. Jankins TC, Bell WC, Zhang Y, Qin ZY, Chen JS, Gembicky M, Liu P, Engle KM. PMID: 35655006; PMCID: PMC9674112.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    20. Sterically crowded 1,4-diiodobenzene as a precursor to difunctional hypervalent iodine compounds. Chem Commun (Camb). 2022 Jan 25; 58(8):1159-1162. Li G, Smith R, Gembicky M, Rheingold AL, Protasiewicz JD. PMID: 34981095.
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    21. Icosahedral m-Carboranes Containing Exopolyhedral B-Se and B-Te Bonds. Inorg Chem. 2021 Dec 20; 60(24):19165-19174. Mills HA, Alsarhan F, Ong TC, Gembicky M, Rheingold AL, Spokoyny AM. PMID: 34855370; PMCID: PMC8761389.
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    22. Crystalline Hydrogen-Bonding Networks and Mixed-Metal Framework Materials Enabled by an Electronically Differentiated Heteroditopic Isocyanide/Carboxylate Linker Group. Inorg Chem. 2021 Aug 16; 60(16):12545-12554. Balto KP, Gembicky M, Rheingold AL, Figueroa JS. PMID: 34347461.
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    23. Corrigendum: ReI Tricarbonyl Complexes as Coordinate Covalent Inhibitors for the SARS-CoV-2 Main Cysteine Protease. Angew Chem Int Ed Engl. 2021 Jul 26; 60(31):16740. Karges J, Kalaj M, Gembicky M, Cohen SM. PMID: 34278669; PMCID: PMC8426708.
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    24. Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes. Organometallics. 2021 Jul 26; 40(14):2311-2319. Romine AM, Demer MJ, Gembicky M, Rheingold AL, Engle KM. PMID: 34433997; PMCID: PMC8382225.
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    25. ReI Tricarbonyl Complexes as Coordinate Covalent Inhibitors for the SARS-CoV-2 Main Cysteine Protease. Angew Chem Int Ed Engl. 2021 05 03; 60(19):10716-10723. Karges J, Kalaj M, Gembicky M, Cohen SM. PMID: 33606889; PMCID: PMC8014511.
      View in: PubMed   Mentions: 23     Fields:    Translation:HumansCells
    26. Aqueous Stability and Ligand Substitution of a Layered Cu(I)/Isocyanide-Based Organometallic Network Material with a Well-Defined Channel Structure. Inorg Chem. 2020 Sep 08; 59(17):11868-11878. Arroyave A, Gembicky M, Rheingold AL, Figueroa JS. PMID: 32813502.
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    27. Cation-Controlled Assembly of Polyoxotungstate-Based Coordination Networks. Angew Chem Int Ed Engl. 2020 Sep 14; 59(38):16609-16615. Chen L, Turo MJ, Gembicky M, Reinicke RA, Schimpf AM. PMID: 32488927.
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    28. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
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    29. Tunable Metal Oxide Frameworks via Coordination Assembly of Preyssler-Type Molecular Clusters. J Am Chem Soc. 2019 12 26; 141(51):20261-20268. Chen L, San KA, Turo MJ, Gembicky M, Fereidouni S, Kalaj M, Schimpf AM. PMID: 31775506.
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    30. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
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    31. Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C-H Bond Activation in a Tris(aryloxide)mesitylene Ligand System. Inorg Chem. 2018 Oct 15; 57(20):12876-12884. Palumbo CT, Halter DP, Voora VK, Chen GP, Ziller JW, Gembicky M, Rheingold AL, Furche F, Meyer K, Evans WJ. PMID: 30246533.
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    32. Covalent attachment of [Ni(alkynyl-cyclam)]2+ catalysts to glassy carbon electrodes. Chem Commun (Camb). 2018 Apr 19; 54(33):4116-4119. Zhanaidarova A, Moore CE, Gembicky M, Kubiak CP. PMID: 29620782.
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    33. Electrocatalytic H2O Reduction with f-Elements: Mechanistic Insight and Overpotential Tuning in a Series of Lanthanide Complexes. J Am Chem Soc. 2018 02 21; 140(7):2587-2594. Halter DP, Palumbo CT, Ziller JW, Gembicky M, Rheingold AL, Evans WJ, Meyer K. PMID: 29378127.
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    34. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. J Am Chem Soc. 2017 12 06; 139(48):17257-17260. Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa JS. PMID: 29131949.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    35. Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2. Chem Commun (Camb). 2017 Aug 11; 53(62):8664-8666. Huh DN, Kotyk CM, Gembicky M, Rheingold AL, Ziller JW, Evans WJ. PMID: 28722066.
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    36. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
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    37. Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides. J Am Chem Soc. 2016 11 23; 138(46):15138-15141. Agnew DW, Gembicky M, Moore CE, Rheingold AL, Figueroa JS. PMID: 27802031.
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    38. Thiocyanate-Ligated Heterobimetallic {PtM} Lantern Complexes Including a Ferromagnetically Coupled 1D Coordination Polymer. Inorg Chem. 2016 Aug 15; 55(16):8099-109. Guillet JL, Bhowmick I, Shores MP, Daley CJ, Gembicky M, Golen JA, Rheingold AL, Doerrer LH. PMID: 27486841.
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    39. Erratum: (Glycol-κO,O')nitros-yl(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e26. Munie S, Larsen A, Gembicky M. PMID: 21578981; PMCID: PMC2979039.
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    40. Erratum: Di-μ-nitrosyl-bis-[(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(0)](Ru-Ru). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e25. Pearsal M, Gembicky M, Dominiak P, Larsen A, Coppens P. PMID: 21578980; PMCID: PMC2979091.
      View in: PubMed   Mentions: 3  
    41. Ligand-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand in ruthenium-based metathesis catalysts. J Am Chem Soc. 2009 May 20; 131(19):6822-32. Galan BR, Pitak M, Gembicky M, Keister JB, Diver ST. PMID: 19397262.
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    42. Capturing and analyzing the excited-state structure of a Cu(I) phenanthroline complex by time-resolved diffraction and theoretical calculations. J Am Chem Soc. 2009 May 13; 131(18):6566-73. Vorontsov II, Graber T, Kovalevsky AY, Novozhilova IV, Gembicky M, Chen YS, Coppens P. PMID: 19378949.
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    43. Charge density analysis of the (C-C)-->Ti agostic interactions in a titanacyclobutane complex. J Am Chem Soc. 2009 May 06; 131(17):6154-60. Scheins S, Messerschmidt M, Gembicky M, Pitak M, Volkov A, Coppens P, Harvey BG, Turpin GC, Arif AM, Ernst RD. PMID: 19366267.
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    44. The RATIO method for time-resolved Laue crystallography. J Synchrotron Radiat. 2009 Mar; 16(Pt 2):226-30. Coppens P, Pitak M, Gembicky M, Messerschmidt M, Scheins S, Benedict J, Adachi SI, Sato T, Nozawa S, Ichiyanagi K, Chollet M, Koshihara SY. PMID: 19240334; PMCID: PMC2651764.
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    45. Competitive isomerization and dimerization in co-crystals of 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol and sorbic acid: a new look at stereochemical requirements for [2+2] dimerization. Chem Commun (Camb). 2008 Jun 14; (22):2538-40. Zheng SL, Pham O, Vande Velde CM, Gembicky M, Coppens P. PMID: 18506236.
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    46. (Glycol-κO,O')nitros-yl(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Acta Crystallogr Sect E Struct Rep Online. 2008 01 04; 64(Pt 2):m293. Munie S, Larsen A, Gembicky M. PMID: 21201270; PMCID: PMC2960154.
      View in: PubMed   Mentions: 1  
    47. Supramolecular solids as a medium for single-crystal-to-single-crystal E/Z photoisomerization: kinetic study of the photoreactions of two Zn-coordinated tiglic acid molecules. Chemistry. 2008; 14(2):706-13. Zheng SL, Vande Velde CM, Messerschmidt M, Volkov A, Gembicky M, Coppens P. PMID: 17955556.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    48. Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization. Chem Commun (Camb). 2007 Jun 21; (23):2399-401. Zhang J, Gembicky M, Messerschmidt M, Coppens P. PMID: 17844759.
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    49. A kHz heat-load shutter for white-beam experiments at synchrotron sources. J Synchrotron Radiat. 2007 May; 14(Pt 3):295-6. Gembicky M, Adachi SI, Coppens P. PMID: 17435306.
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    50. On the design of ultrafast shutters for time-resolved synchrotron experiments. J Synchrotron Radiat. 2007 Jan; 14(Pt 1):133-7. Gembicky M, Coppens P. PMID: 17211080.
      View in: PubMed   Mentions: 3     Fields:    
    51. Effect of the environment on molecular properties: synthesis, structure, and photoluminescence of Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) nanoclusters in eight different supramolecular frameworks. Inorg Chem. 2006 Nov 13; 45(23):9281-9. Zheng SL, Gembicky M, Messerschmidt M, Dominiak PM, Coppens P. PMID: 17083227.
      View in: PubMed   Mentions: 6     Fields:    
    52. Carbon monoxide-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand: Buchner reaction in a ruthenium carbene complex. J Am Chem Soc. 2005 Nov 16; 127(45):15702-3. Galan BR, Gembicky M, Dominiak PM, Keister JB, Diver ST. PMID: 16277502.
      View in: PubMed   Mentions: 5     Fields:    
    53. A fast mechanical shutter for submicrosecond time-resolved synchrotron experiments. J Synchrotron Radiat. 2005 Sep; 12(Pt 5):665-9. Gembicky M, Oss D, Fuchs R, Coppens P. PMID: 16120992.
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    54. Two novel bis(2,9-dimethyl-1,10-phenanthroline)copper(I) complexes: [Cu(dmp)2]2(PF6)2.0.5(bpmh).CH3CN and [Cu(dmp)2][N(CN)2]. Acta Crystallogr C. 2005 Jul; 61(Pt 7):m329-32. King G, Gembicky M, Coppens P. PMID: 15997055.
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    55. Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction. Phys Rev Lett. 2005 May 20; 94(19):193003. Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV, Omary MA, Coppens P. PMID: 16090170.
      View in: PubMed   Mentions: 7     Fields:    
    56. The structure of short-lived excited states of molecular complexes by time-resolved X-ray diffraction. Acta Crystallogr A. 2005 Mar; 61(Pt 2):162-72. Coppens P, Vorontsov II, Graber T, Gembicky M, Kovalevsky AY. PMID: 15724066.
      View in: PubMed   Mentions: 12     Fields:    
    57. Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties. Inorg Chem. 2004 Dec 27; 43(26):8282-9. Kovalevsky AY, Gembicky M, Coppens P. PMID: 15606174.
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    58. A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction. Chem Commun (Camb). 2004 Oct 07; (19):2144-5. Coppens P, Gerlits O, Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV. PMID: 15467843.
      View in: PubMed   Mentions: 6     Fields:    
    59. Geometry changes of a Cu(I) phenanthroline complex on photoexcitation in a confining medium by time-resolved X-ray diffraction. J Am Chem Soc. 2004 May 19; 126(19):5980-1. Coppens P, Vorontsov II, Graber T, Kovalevsky AY, Chen YS, Wu G, Gembicky M, Novozhilova IV. PMID: 15137759.
      View in: PubMed   Mentions: 3     Fields:    
    60. Solid-state structure dependence of the molecular distortion and spectroscopic properties of the Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) ion. Inorg Chem. 2003 Dec 29; 42(26):8794-802. Kovalevsky AY, Gembicky M, Novozhilova IV, Coppens P. PMID: 14686859.
      View in: PubMed   Mentions: 6     Fields:    
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