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Intuitive Control of Low-Energy Magnetic Excitations via Directed Dipolar Interactions in a Series of Er(III)-Based Complexes. J Am Chem Soc. 2022 Jun 17.
Orlova AP, Hilgar JD, Bernbeck MG, Gembicky M, Rinehart JD. PMID: 35713679.
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PubMed Mentions: Fields:
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Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes. Nat Chem. 2022 Jun; 14(6):632-639.
Jankins TC, Bell WC, Zhang Y, Qin ZY, Chen JS, Gembicky M, Liu P, Engle KM. PMID: 35655006.
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PubMed Mentions:
1 Fields:
Translation:
Cells
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Sterically crowded 1,4-diiodobenzene as a precursor to difunctional hypervalent iodine compounds. Chem Commun (Camb). 2022 Jan 25; 58(8):1159-1162.
Li G, Smith R, Gembicky M, Rheingold AL, Protasiewicz JD. PMID: 34981095.
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PubMed Mentions: Fields:
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Icosahedral m-Carboranes Containing Exopolyhedral B-Se and B-Te Bonds. Inorg Chem. 2021 Dec 20; 60(24):19165-19174.
Mills HA, Alsarhan F, Ong TC, Gembicky M, Rheingold AL, Spokoyny AM. PMID: 34855370; PMCID: PMC8761389.
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Crystalline Hydrogen-Bonding Networks and Mixed-Metal Framework Materials Enabled by an Electronically Differentiated Heteroditopic Isocyanide/Carboxylate Linker Group. Inorg Chem. 2021 Aug 16; 60(16):12545-12554.
Balto KP, Gembicky M, Rheingold AL, Figueroa JS. PMID: 34347461.
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Corrigendum: ReI Tricarbonyl Complexes as Coordinate Covalent Inhibitors for the SARS-CoV-2 Main Cysteine Protease. Angew Chem Int Ed Engl. 2021 Jul 26; 60(31):16740.
Karges J, Kalaj M, Gembicky M, Cohen SM. PMID: 34278669; PMCID: PMC8426708.
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PubMed Mentions: Fields:
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Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes. Organometallics. 2021 Jul 26; 40(14):2311-2319.
Romine AM, Demer MJ, Gembicky M, Rheingold AL, Engle KM. PMID: 34433997; PMCID: PMC8382225.
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PubMed Mentions:
1
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ReI Tricarbonyl Complexes as Coordinate Covalent Inhibitors for the SARS-CoV-2 Main Cysteine Protease. Angew Chem Int Ed Engl. 2021 05 03; 60(19):10716-10723.
Karges J, Kalaj M, Gembicky M, Cohen SM. PMID: 33606889; PMCID: PMC8014511.
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PubMed Mentions:
11 Fields:
Translation:
HumansCells
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Aqueous Stability and Ligand Substitution of a Layered Cu(I)/Isocyanide-Based Organometallic Network Material with a Well-Defined Channel Structure. Inorg Chem. 2020 Sep 08; 59(17):11868-11878.
Arroyave A, Gembicky M, Rheingold AL, Figueroa JS. PMID: 32813502.
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PubMed Mentions: Fields:
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Cation-Controlled Assembly of Polyoxotungstate-Based Coordination Networks. Angew Chem Int Ed Engl. 2020 Sep 14; 59(38):16609-16615.
Chen L, Turo MJ, Gembicky M, Reinicke RA, Schimpf AM. PMID: 32488927.
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PubMed Mentions:
1 Fields:
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Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430.
Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
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PubMed Mentions:
2 Fields:
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Tunable Metal Oxide Frameworks via Coordination Assembly of Preyssler-Type Molecular Clusters. J Am Chem Soc. 2019 12 26; 141(51):20261-20268.
Chen L, San KA, Turo MJ, Gembicky M, Fereidouni S, Kalaj M, Schimpf AM. PMID: 31775506.
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3 Fields:
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Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733.
Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
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PubMed Mentions:
3 Fields:
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Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C-H Bond Activation in a Tris(aryloxide)mesitylene Ligand System. Inorg Chem. 2018 Oct 15; 57(20):12876-12884.
Palumbo CT, Halter DP, Voora VK, Chen GP, Ziller JW, Gembicky M, Rheingold AL, Furche F, Meyer K, Evans WJ. PMID: 30246533.
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PubMed Mentions:
1 Fields:
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Covalent attachment of [Ni(alkynyl-cyclam)]2+ catalysts to glassy carbon electrodes. Chem Commun (Camb). 2018 Apr 19; 54(33):4116-4119.
Zhanaidarova A, Moore CE, Gembicky M, Kubiak CP. PMID: 29620782.
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PubMed Mentions:
4 Fields:
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Electrocatalytic H2O Reduction with f-Elements: Mechanistic Insight and Overpotential Tuning in a Series of Lanthanide Complexes. J Am Chem Soc. 2018 02 21; 140(7):2587-2594.
Halter DP, Palumbo CT, Ziller JW, Gembicky M, Rheingold AL, Evans WJ, Meyer K. PMID: 29378127.
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PubMed Mentions:
1 Fields:
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Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. J Am Chem Soc. 2017 12 06; 139(48):17257-17260.
Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa JS. PMID: 29131949.
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PubMed Mentions:
5 Fields:
Translation:
Cells
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Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2. Chem Commun (Camb). 2017 Aug 11; 53(62):8664-8666.
Huh DN, Kotyk CM, Gembicky M, Rheingold AL, Ziller JW, Evans WJ. PMID: 28722066.
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PubMed Mentions:
1 Fields:
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Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027.
Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
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1 Fields:
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Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides. J Am Chem Soc. 2016 11 23; 138(46):15138-15141.
Agnew DW, Gembicky M, Moore CE, Rheingold AL, Figueroa JS. PMID: 27802031.
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1 Fields:
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Thiocyanate-Ligated Heterobimetallic {PtM} Lantern Complexes Including a Ferromagnetically Coupled 1D Coordination Polymer. Inorg Chem. 2016 Aug 15; 55(16):8099-109.
Guillet JL, Bhowmick I, Shores MP, Daley CJ, Gembicky M, Golen JA, Rheingold AL, Doerrer LH. PMID: 27486841.
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4 Fields:
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Erratum: (Glycol-κO,O')nitros-yl(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e26.
Munie S, Larsen A, Gembicky M. PMID: 21578981; PMCID: PMC2979039.
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Erratum: Di-μ-nitrosyl-bis-[(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(0)](Ru-Ru). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e25.
Pearsal M, Gembicky M, Dominiak P, Larsen A, Coppens P. PMID: 21578980; PMCID: PMC2979091.
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Ligand-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand in ruthenium-based metathesis catalysts. J Am Chem Soc. 2009 May 20; 131(19):6822-32.
Galan BR, Pitak M, Gembicky M, Keister JB, Diver ST. PMID: 19397262.
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PubMed Mentions:
3 Fields:
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Capturing and analyzing the excited-state structure of a Cu(I) phenanthroline complex by time-resolved diffraction and theoretical calculations. J Am Chem Soc. 2009 May 13; 131(18):6566-73.
Vorontsov II, Graber T, Kovalevsky AY, Novozhilova IV, Gembicky M, Chen YS, Coppens P. PMID: 19378949.
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PubMed Mentions:
8 Fields:
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Charge density analysis of the (C-C)-->Ti agostic interactions in a titanacyclobutane complex. J Am Chem Soc. 2009 May 06; 131(17):6154-60.
Scheins S, Messerschmidt M, Gembicky M, Pitak M, Volkov A, Coppens P, Harvey BG, Turpin GC, Arif AM, Ernst RD. PMID: 19366267.
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PubMed Mentions:
1 Fields:
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The RATIO method for time-resolved Laue crystallography. J Synchrotron Radiat. 2009 Mar; 16(Pt 2):226-30.
Coppens P, Pitak M, Gembicky M, Messerschmidt M, Scheins S, Benedict J, Adachi SI, Sato T, Nozawa S, Ichiyanagi K, Chollet M, Koshihara SY. PMID: 19240334; PMCID: PMC2651764.
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PubMed Mentions:
23 Fields:
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Competitive isomerization and dimerization in co-crystals of 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol and sorbic acid: a new look at stereochemical requirements for [2+2] dimerization. Chem Commun (Camb). 2008 Jun 14; (22):2538-40.
Zheng SL, Pham O, Vande Velde CM, Gembicky M, Coppens P. PMID: 18506236.
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PubMed Mentions:
3 Fields:
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(Glycol-κO,O')nitros-yl(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Acta Crystallogr Sect E Struct Rep Online. 2008 01 04; 64(Pt 2):m293.
Munie S, Larsen A, Gembicky M. PMID: 21201270; PMCID: PMC2960154.
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PubMed Mentions:
1
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Supramolecular solids as a medium for single-crystal-to-single-crystal E/Z photoisomerization: kinetic study of the photoreactions of two Zn-coordinated tiglic acid molecules. Chemistry. 2008; 14(2):706-13.
Zheng SL, Vande Velde CM, Messerschmidt M, Volkov A, Gembicky M, Coppens P. PMID: 17955556.
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PubMed Mentions:
6 Fields:
Translation:
Cells
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Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization. Chem Commun (Camb). 2007 Jun 21; (23):2399-401.
Zhang J, Gembicky M, Messerschmidt M, Coppens P. PMID: 17844759.
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PubMed Mentions: Fields:
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A kHz heat-load shutter for white-beam experiments at synchrotron sources. J Synchrotron Radiat. 2007 May; 14(Pt 3):295-6.
Gembicky M, Adachi SI, Coppens P. PMID: 17435306.
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PubMed Mentions:
1 Fields:
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On the design of ultrafast shutters for time-resolved synchrotron experiments. J Synchrotron Radiat. 2007 Jan; 14(Pt 1):133-7.
Gembicky M, Coppens P. PMID: 17211080.
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PubMed Mentions:
3 Fields:
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Effect of the environment on molecular properties: synthesis, structure, and photoluminescence of Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) nanoclusters in eight different supramolecular frameworks. Inorg Chem. 2006 Nov 13; 45(23):9281-9.
Zheng SL, Gembicky M, Messerschmidt M, Dominiak PM, Coppens P. PMID: 17083227.
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PubMed Mentions:
4 Fields:
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Carbon monoxide-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand: Buchner reaction in a ruthenium carbene complex. J Am Chem Soc. 2005 Nov 16; 127(45):15702-3.
Galan BR, Gembicky M, Dominiak PM, Keister JB, Diver ST. PMID: 16277502.
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PubMed Mentions:
5 Fields:
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A fast mechanical shutter for submicrosecond time-resolved synchrotron experiments. J Synchrotron Radiat. 2005 Sep; 12(Pt 5):665-9.
Gembicky M, Oss D, Fuchs R, Coppens P. PMID: 16120992.
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PubMed Mentions:
4 Fields:
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Two novel bis(2,9-dimethyl-1,10-phenanthroline)copper(I) complexes: [Cu(dmp)2]2(PF6)2.0.5(bpmh).CH3CN and [Cu(dmp)2][N(CN)2]. Acta Crystallogr C. 2005 Jul; 61(Pt 7):m329-32.
King G, Gembicky M, Coppens P. PMID: 15997055.
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PubMed Mentions:
2 Fields:
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Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction. Phys Rev Lett. 2005 May 20; 94(19):193003.
Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV, Omary MA, Coppens P. PMID: 16090170.
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PubMed Mentions:
6 Fields:
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The structure of short-lived excited states of molecular complexes by time-resolved X-ray diffraction. Acta Crystallogr A. 2005 Mar; 61(Pt 2):162-72.
Coppens P, Vorontsov II, Graber T, Gembicky M, Kovalevsky AY. PMID: 15724066.
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PubMed Mentions:
12 Fields:
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Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties. Inorg Chem. 2004 Dec 27; 43(26):8282-9.
Kovalevsky AY, Gembicky M, Coppens P. PMID: 15606174.
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A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction. Chem Commun (Camb). 2004 Oct 07; (19):2144-5.
Coppens P, Gerlits O, Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV. PMID: 15467843.
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PubMed Mentions:
6 Fields:
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Geometry changes of a Cu(I) phenanthroline complex on photoexcitation in a confining medium by time-resolved X-ray diffraction. J Am Chem Soc. 2004 May 19; 126(19):5980-1.
Coppens P, Vorontsov II, Graber T, Kovalevsky AY, Chen YS, Wu G, Gembicky M, Novozhilova IV. PMID: 15137759.
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PubMed Mentions:
3 Fields:
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Solid-state structure dependence of the molecular distortion and spectroscopic properties of the Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) ion. Inorg Chem. 2003 Dec 29; 42(26):8794-802.
Kovalevsky AY, Gembicky M, Novozhilova IV, Coppens P. PMID: 14686859.
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PubMed Mentions:
4 Fields: