Milan Gembicky

Title(s)	RSCH AND DEV ENGR 4, Chemistry and Biochemistry
School	Vc-academic Affairs
Address	9500 Gilman Drive # La Jolla CA 92093
vCard	Download vCard

Bibliographic

Publications

Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help. to make corrections and additions.

Altmetrics Details

PMC Citations indicate the number of times the publication was cited by articles in PubMed Central, and the Altmetric score represents citations in news articles and social media. (Note that publications are often cited in additional ways that are not shown here.) Fields are based on how the National Library of Medicine (NLM) classifies the publication's journal and might not represent the specific topic of the publication. Translation tags are based on the publication type and the MeSH terms NLM assigns to the publication. Some publications (especially newer ones and publications not in PubMed) might not yet be assigned Field or Translation tags.) Click a Field or Translation tag to filter the publications.

Intuitive Control of Low-Energy Magnetic Excitations via Directed Dipolar Interactions in a Series of Er(III)-Based Complexes. J Am Chem Soc. 2022 Jun 17. Orlova AP, Hilgar JD, Bernbeck MG, Gembicky M, Rinehart JD. PMID: 35713679.

View in: PubMed Mentions: Fields:
Che Chemistry
Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes. Nat Chem. 2022 Jun; 14(6):632-639. Jankins TC, Bell WC, Zhang Y, Qin ZY, Chen JS, Gembicky M, Liu P, Engle KM. PMID: 35655006.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Translation:Cells
Sterically crowded 1,4-diiodobenzene as a precursor to difunctional hypervalent iodine compounds. Chem Commun (Camb). 2022 Jan 25; 58(8):1159-1162. Li G, Smith R, Gembicky M, Rheingold AL, Protasiewicz JD. PMID: 34981095.

View in: PubMed Mentions: Fields:
Che Chemistry
Icosahedral m-Carboranes Containing Exopolyhedral B-Se and B-Te Bonds. Inorg Chem. 2021 Dec 20; 60(24):19165-19174. Mills HA, Alsarhan F, Ong TC, Gembicky M, Rheingold AL, Spokoyny AM. PMID: 34855370; PMCID: PMC8761389.

View in: PubMed Mentions: Fields:
Che Chemistry
Crystalline Hydrogen-Bonding Networks and Mixed-Metal Framework Materials Enabled by an Electronically Differentiated Heteroditopic Isocyanide/Carboxylate Linker Group. Inorg Chem. 2021 Aug 16; 60(16):12545-12554. Balto KP, Gembicky M, Rheingold AL, Figueroa JS. PMID: 34347461.

View in: PubMed Mentions: Fields:
Che Chemistry
Corrigendum: ReI Tricarbonyl Complexes as Coordinate Covalent Inhibitors for the SARS-CoV-2 Main Cysteine Protease. Angew Chem Int Ed Engl. 2021 Jul 26; 60(31):16740. Karges J, Kalaj M, Gembicky M, Cohen SM. PMID: 34278669; PMCID: PMC8426708.

View in: PubMed Mentions: Fields:
Che Chemistry
Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes. Organometallics. 2021 Jul 26; 40(14):2311-2319. Romine AM, Demer MJ, Gembicky M, Rheingold AL, Engle KM. PMID: 34433997; PMCID: PMC8382225.

View in: PubMed Mentions: 1
ReI Tricarbonyl Complexes as Coordinate Covalent Inhibitors for the SARS-CoV-2 Main Cysteine Protease. Angew Chem Int Ed Engl. 2021 05 03; 60(19):10716-10723. Karges J, Kalaj M, Gembicky M, Cohen SM. PMID: 33606889; PMCID: PMC8014511.

View in: PubMed Mentions: 11 Fields:
Che Chemistry
Translation:Humans Cells
Aqueous Stability and Ligand Substitution of a Layered Cu(I)/Isocyanide-Based Organometallic Network Material with a Well-Defined Channel Structure. Inorg Chem. 2020 Sep 08; 59(17):11868-11878. Arroyave A, Gembicky M, Rheingold AL, Figueroa JS. PMID: 32813502.

View in: PubMed Mentions: Fields:
Che Chemistry
Cation-Controlled Assembly of Polyoxotungstate-Based Coordination Networks. Angew Chem Int Ed Engl. 2020 Sep 14; 59(38):16609-16615. Chen L, Turo MJ, Gembicky M, Reinicke RA, Schimpf AM. PMID: 32488927.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.

View in: PubMed Mentions: 2 Fields:
Che Chemistry
Tunable Metal Oxide Frameworks via Coordination Assembly of Preyssler-Type Molecular Clusters. J Am Chem Soc. 2019 12 26; 141(51):20261-20268. Chen L, San KA, Turo MJ, Gembicky M, Fereidouni S, Kalaj M, Schimpf AM. PMID: 31775506.

View in: PubMed Mentions: 3 Fields:
Che Chemistry
Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.

View in: PubMed Mentions: 3 Fields:
Che Chemistry
Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C-H Bond Activation in a Tris(aryloxide)mesitylene Ligand System. Inorg Chem. 2018 Oct 15; 57(20):12876-12884. Palumbo CT, Halter DP, Voora VK, Chen GP, Ziller JW, Gembicky M, Rheingold AL, Furche F, Meyer K, Evans WJ. PMID: 30246533.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Covalent attachment of [Ni(alkynyl-cyclam)]2+ catalysts to glassy carbon electrodes. Chem Commun (Camb). 2018 Apr 19; 54(33):4116-4119. Zhanaidarova A, Moore CE, Gembicky M, Kubiak CP. PMID: 29620782.

View in: PubMed Mentions: 4 Fields:
Che Chemistry
Electrocatalytic H2O Reduction with f-Elements: Mechanistic Insight and Overpotential Tuning in a Series of Lanthanide Complexes. J Am Chem Soc. 2018 02 21; 140(7):2587-2594. Halter DP, Palumbo CT, Ziller JW, Gembicky M, Rheingold AL, Evans WJ, Meyer K. PMID: 29378127.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. J Am Chem Soc. 2017 12 06; 139(48):17257-17260. Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa JS. PMID: 29131949.

View in: PubMed Mentions: 5 Fields:
Che Chemistry
Translation:Cells
Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)]2+, from Sm2+, Eu2+, and Yb2+ silyl metallocenes (C5H4SiMe3)2Ln(THF)2. Chem Commun (Camb). 2017 Aug 11; 53(62):8664-8666. Huh DN, Kotyk CM, Gembicky M, Rheingold AL, Ziller JW, Evans WJ. PMID: 28722066.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides. J Am Chem Soc. 2016 11 23; 138(46):15138-15141. Agnew DW, Gembicky M, Moore CE, Rheingold AL, Figueroa JS. PMID: 27802031.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
Thiocyanate-Ligated Heterobimetallic {PtM} Lantern Complexes Including a Ferromagnetically Coupled 1D Coordination Polymer. Inorg Chem. 2016 Aug 15; 55(16):8099-109. Guillet JL, Bhowmick I, Shores MP, Daley CJ, Gembicky M, Golen JA, Rheingold AL, Doerrer LH. PMID: 27486841.

View in: PubMed Mentions: 4 Fields:
Che Chemistry
Erratum: (Glycol-κO,O')nitros-yl(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e26. Munie S, Larsen A, Gembicky M. PMID: 21578981; PMCID: PMC2979039.

View in: PubMed Mentions:
Erratum: Di-μ-nitrosyl-bis-[(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(0)](Ru-Ru). Corrigendum. Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14; 66(Pt 5):e25. Pearsal M, Gembicky M, Dominiak P, Larsen A, Coppens P. PMID: 21578980; PMCID: PMC2979091.

View in: PubMed Mentions:
Ligand-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand in ruthenium-based metathesis catalysts. J Am Chem Soc. 2009 May 20; 131(19):6822-32. Galan BR, Pitak M, Gembicky M, Keister JB, Diver ST. PMID: 19397262.

View in: PubMed Mentions: 3 Fields:
Che Chemistry
Capturing and analyzing the excited-state structure of a Cu(I) phenanthroline complex by time-resolved diffraction and theoretical calculations. J Am Chem Soc. 2009 May 13; 131(18):6566-73. Vorontsov II, Graber T, Kovalevsky AY, Novozhilova IV, Gembicky M, Chen YS, Coppens P. PMID: 19378949.

View in: PubMed Mentions: 8 Fields:
Che Chemistry
Charge density analysis of the (C-C)-->Ti agostic interactions in a titanacyclobutane complex. J Am Chem Soc. 2009 May 06; 131(17):6154-60. Scheins S, Messerschmidt M, Gembicky M, Pitak M, Volkov A, Coppens P, Harvey BG, Turpin GC, Arif AM, Ernst RD. PMID: 19366267.

View in: PubMed Mentions: 1 Fields:
Che Chemistry
The RATIO method for time-resolved Laue crystallography. J Synchrotron Radiat. 2009 Mar; 16(Pt 2):226-30. Coppens P, Pitak M, Gembicky M, Messerschmidt M, Scheins S, Benedict J, Adachi SI, Sato T, Nozawa S, Ichiyanagi K, Chollet M, Koshihara SY. PMID: 19240334; PMCID: PMC2651764.

View in: PubMed Mentions: 23 Fields:
Rad Radiology
Competitive isomerization and dimerization in co-crystals of 1,1,6,6-tetraphenyl-2,4-hexadiyne-1,6-diol and sorbic acid: a new look at stereochemical requirements for [2+2] dimerization. Chem Commun (Camb). 2008 Jun 14; (22):2538-40. Zheng SL, Pham O, Vande Velde CM, Gembicky M, Coppens P. PMID: 18506236.

View in: PubMed Mentions: 3 Fields:
Che Chemistry
(Glycol-κO,O')nitros-yl(η-penta-methyl-cyclo-penta-dien-yl)ruthenium(II) bis-(tri-fluoro-methane-sulfonate). Acta Crystallogr Sect E Struct Rep Online. 2008 01 04; 64(Pt 2):m293. Munie S, Larsen A, Gembicky M. PMID: 21201270; PMCID: PMC2960154.

View in: PubMed Mentions: 1
Supramolecular solids as a medium for single-crystal-to-single-crystal E/Z photoisomerization: kinetic study of the photoreactions of two Zn-coordinated tiglic acid molecules. Chemistry. 2008; 14(2):706-13. Zheng SL, Vande Velde CM, Messerschmidt M, Volkov A, Gembicky M, Coppens P. PMID: 17955556.

View in: PubMed Mentions: 6 Fields:
Che Chemistry
Translation:Cells
Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization. Chem Commun (Camb). 2007 Jun 21; (23):2399-401. Zhang J, Gembicky M, Messerschmidt M, Coppens P. PMID: 17844759.

View in: PubMed Mentions: Fields:
Che Chemistry
A kHz heat-load shutter for white-beam experiments at synchrotron sources. J Synchrotron Radiat. 2007 May; 14(Pt 3):295-6. Gembicky M, Adachi SI, Coppens P. PMID: 17435306.

View in: PubMed Mentions: 1 Fields:
Rad Radiology
On the design of ultrafast shutters for time-resolved synchrotron experiments. J Synchrotron Radiat. 2007 Jan; 14(Pt 1):133-7. Gembicky M, Coppens P. PMID: 17211080.

View in: PubMed Mentions: 3 Fields:
Rad Radiology
Effect of the environment on molecular properties: synthesis, structure, and photoluminescence of Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) nanoclusters in eight different supramolecular frameworks. Inorg Chem. 2006 Nov 13; 45(23):9281-9. Zheng SL, Gembicky M, Messerschmidt M, Dominiak PM, Coppens P. PMID: 17083227.

View in: PubMed Mentions: 4 Fields:
Che Chemistry
Carbon monoxide-promoted carbene insertion into the aryl substituent of an N-heterocyclic carbene ligand: Buchner reaction in a ruthenium carbene complex. J Am Chem Soc. 2005 Nov 16; 127(45):15702-3. Galan BR, Gembicky M, Dominiak PM, Keister JB, Diver ST. PMID: 16277502.

View in: PubMed Mentions: 5 Fields:
Che Chemistry
A fast mechanical shutter for submicrosecond time-resolved synchrotron experiments. J Synchrotron Radiat. 2005 Sep; 12(Pt 5):665-9. Gembicky M, Oss D, Fuchs R, Coppens P. PMID: 16120992.

View in: PubMed Mentions: 4 Fields:
Rad Radiology
Two novel bis(2,9-dimethyl-1,10-phenanthroline)copper(I) complexes: [Cu(dmp)2]2(PF6)2.0.5(bpmh).CH3CN and [Cu(dmp)2][N(CN)2]. Acta Crystallogr C. 2005 Jul; 61(Pt 7):m329-32. King G, Gembicky M, Coppens P. PMID: 15997055.

View in: PubMed Mentions: 2 Fields:
Che Chemistry Techniques
Shedding light on the structure of a photoinduced transient excimer by time-resolved diffraction. Phys Rev Lett. 2005 May 20; 94(19):193003. Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV, Omary MA, Coppens P. PMID: 16090170.

View in: PubMed Mentions: 6 Fields:
Med Medicine (General)
The structure of short-lived excited states of molecular complexes by time-resolved X-ray diffraction. Acta Crystallogr A. 2005 Mar; 61(Pt 2):162-72. Coppens P, Vorontsov II, Graber T, Gembicky M, Kovalevsky AY. PMID: 15724066.

View in: PubMed Mentions: 12 Fields:
Bio Biophysics Che Chemistry Che Chemistry Techniques Phy Physics
Cu(I)(2,9-bis(trifluoromethyl)-1,10-phenanthroline)2+ complexes: correlation between solid-state structure and photoluminescent properties. Inorg Chem. 2004 Dec 27; 43(26):8282-9. Kovalevsky AY, Gembicky M, Coppens P. PMID: 15606174.

View in: PubMed Mentions: Fields:
Che Chemistry
A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction. Chem Commun (Camb). 2004 Oct 07; (19):2144-5. Coppens P, Gerlits O, Vorontsov II, Kovalevsky AY, Chen YS, Graber T, Gembicky M, Novozhilova IV. PMID: 15467843.

View in: PubMed Mentions: 6 Fields:
Che Chemistry
Geometry changes of a Cu(I) phenanthroline complex on photoexcitation in a confining medium by time-resolved X-ray diffraction. J Am Chem Soc. 2004 May 19; 126(19):5980-1. Coppens P, Vorontsov II, Graber T, Kovalevsky AY, Chen YS, Wu G, Gembicky M, Novozhilova IV. PMID: 15137759.

View in: PubMed Mentions: 3 Fields:
Che Chemistry
Solid-state structure dependence of the molecular distortion and spectroscopic properties of the Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) ion. Inorg Chem. 2003 Dec 29; 42(26):8794-802. Kovalevsky AY, Gembicky M, Novozhilova IV, Coppens P. PMID: 14686859.

View in: PubMed Mentions: 4 Fields:
Che Chemistry