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Guy Bertrand

Title(s)Professor, Chemistry and Biochemistry
SchoolAcademic Aff
Address9500 Gilman Drive #0358
La Jolla CA 92093
Phone858-534-5412
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    Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help. to make corrections and additions.
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    1. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications. Chem Rev. 2020 May 13; 120(9):4141-4168. Jazzar R, Soleilhavoup M, Bertrand G. PMID: 32239922.
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    2. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
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    3. Stable abnormal N-heterocyclic carbenes and their applications. Chem Soc Rev. 2020 Feb 21; 49(4):1233-1252. Sau SC, Hota PK, Mandal SK, Soleilhavoup M, Bertrand G. PMID: 31998907.
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    4. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed ß-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
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    5. The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis. Chem Sci. 2019 Sep 07; 10(33):7807-7811. Pichon D, Soleilhavoup M, Morvan J, Junor GP, Vives T, Crévisy C, Lavallo V, Campagne JM, Mauduit M, Jazzar R, Bertrand G. PMID: 31588330.
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    6. Reductive Elimination at Carbon under Steric Control. J Am Chem Soc. 2019 Jun 26; 141(25):9823-9826. Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. PMID: 31180660.
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    7. Correction to "?'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes". J Am Chem Soc. 2019 Jun 26; 141(25):10118. Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. PMID: 31199623.
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    8. "Quick-Silver" from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes. J Am Chem Soc. 2019 May 29; 141(21):8616-8626. Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. PMID: 31062972.
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    9. Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes. Inorg Chem. 2019 Mar 04; 58(5):3256-3264. Schiegerl LJ, Melaimi M, Tolentino DR, Klein W, Bertrand G, Fässler TF. PMID: 30741546.
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    10. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime. Science. 2019 02 08; 363(6427):601-606. Hamze R, Peltier JL, Sylvinson D, Jung M, Cardenas J, Haiges R, Soleilhavoup M, Jazzar R, Djurovich PI, Bertrand G, Thompson ME. PMID: 30733411.
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    11. Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. Angew Chem Int Ed Engl. 2019 Feb 25; 58(9):2875-2878. Junor GP, Romero EA, Chen X, Jazzar R, Bertrand G. PMID: 30618172.
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    12. What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis? J Am Chem Soc. 2019 01 16; 141(2):1109-1117. Regnier V, Romero EA, Molton F, Jazzar R, Bertrand G, Martin D. PMID: 30561990.
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    13. 1 H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes. Acc Chem Res. 2018 12 18; 51(12):3236-3244. Guisado-Barrios G, Soleilhavoup M, Bertrand G. PMID: 30417642.
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    14. A crystalline monosubstituted carbene. Nat Chem. 2018 12; 10(12):1196-1200. Nakano R, Jazzar R, Bertrand G. PMID: 30323332.
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    15. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 07 25; 140(29):9255-9260. Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G. PMID: 29954178.
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    16. Intercepting a Transient Phosphino-Arsinidene. Chemistry. 2018 Jul 05; 24(38):9514-9519. Hinz A, Hansmann MM, Bertrand G, Goicoechea JM. PMID: 29723432.
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    17. Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 21; 140(7):2546-2554. Hansmann MM, Melaimi M, Munz D, Bertrand G. PMID: 29382199.
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    18. Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 14; 140(6):2206-2213. Hansmann MM, Melaimi M, Bertrand G. PMID: 29342351.
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    19. L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2018 01 02; 57(1):198-202. Li Z, Hou Y, Li Y, Hinz A, Harmer JR, Su CY, Bertrand G, Grützmacher H. PMID: 29106069.
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    20. Crystalline Monomeric Allenyl/Propargyl Radical. J Am Chem Soc. 2017 11 08; 139(44):15620-15623. Hansmann MM, Melaimi M, Bertrand G. PMID: 29046060.
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    21. Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(i) complexes. Chem Commun (Camb). 2017 Aug 08; 53(64):9008-9011. Hamze R, Jazzar R, Soleilhavoup M, Djurovich PI, Bertrand G, Thompson ME. PMID: 28745735.
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    22. Borylenes: An Emerging Class of Compounds. Angew Chem Int Ed Engl. 2017 08 21; 56(35):10282-10292. Soleilhavoup M, Bertrand G. PMID: 28577325.
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    23. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Angew Chem Int Ed Engl. 2017 08 14; 56(34):10046-10068. Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G. PMID: 28376253.
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    24. Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. J Am Chem Soc. 2017 06 14; 139(23):7753-7756. Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G. PMID: 28541687.
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    25. (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. Chem Sci. 2017 May 01; 8(5):3720-3725. Hansmann MM, Ruiz DA, Liu LL, Jazzar R, Bertrand G. PMID: 28580107.
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    26. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
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    27. The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals. Chemistry. 2017 May 02; 23(25):6206-6212. Mahoney JK, Jazzar R, Royal G, Martin D, Bertrand G. PMID: 28105672.
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    28. Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation. J Am Chem Soc. 2016 12 14; 138(49):15873-15876. Kleinhans G, Hansmann MM, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. PMID: 27960301.
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    29. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. J Am Chem Soc. 2016 12 14; 138(49):15885-15888. Hansmann MM, Bertrand G. PMID: 27960331.
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    30. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angew Chem Int Ed Engl. 2016 10 04; 55(41):12886-90. Munz D, Chu J, Melaimi M, Bertrand G. PMID: 27628756.
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    31. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chem Commun (Camb). 2016 Aug 18; 52(69):10563-5. Romero EA, Peltier JL, Jazzar R, Bertrand G. PMID: 27498971.
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    32. Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. Chem Sci. 2017 Jan 01; 8(1):165-168. Romero EA, Jazzar R, Bertrand G. PMID: 28451161.
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    33. Singlet (Phosphino)phosphinidenes are Electrophilic. J Am Chem Soc. 2016 07 13; 138(27):8356-9. Hansmann MM, Jazzar R, Bertrand G. PMID: 27340902.
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    34. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. J Am Chem Soc. 2016 06 29; 138(25):7884-7. Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. PMID: 27304485.
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    35. Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. Chemistry. 2016 Jun 27; 22(27):9404-9. Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. PMID: 27238837.
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    36. N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. Angew Chem Int Ed Engl. 2016 05 10; 55(20):6018-22. Li Z, Chen X, Benko Z, Liu L, Ruiz DA, Peltier JL, Bertrand G, Su CY, Grützmacher H. PMID: 27060924.
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    37. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angew Chem Int Ed Engl. 2016 04 25; 55(18):5536-40. Pranckevicius C, Liu L, Bertrand G, Stephan DW. PMID: 27028936.
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    38. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chem Commun (Camb). 2016 Feb 14; 52(13):2733-5. Peltier JL, Jazzar R, Melaimi M, Bertrand G. PMID: 26757745.
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    39. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Adv Synth Catal. 2016 Mar 17; 358(6):965-969. Martin D, Marx VM, Grubbs RH, Bertrand G. PMID: 27594819.
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    40. A rhodium(I)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chem Commun (Camb). 2016 Feb 28; 52(17):3504-7. Kleinhans G, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. PMID: 26838677.
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    41. Isolation of Au-, Co-?1PCO and Cu-?2PCO complexes, conversion of an Ir-?1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chem Sci. 2016 Mar 01; 7(3):2335-2341. Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. PMID: 29997776.
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    42. The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. J Am Chem Soc. 2015 Dec 23; 137(50):15696-8. Jin L, Romero EA, Melaimi M, Bertrand G. PMID: 26611196.
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    43. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes. Chem Sci. 2016 Jan 01; 7(1):150-154. Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. PMID: 28966767.
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    44. Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong s-Donating and p-Accepting Ligands for Transition Metals. Angew Chem Int Ed Engl. 2015 Dec 01; 54(49):14915-9. Rao B, Tang H, Zeng X, Liu L, Melaimi M, Bertrand G. PMID: 26457345.
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    45. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chem Commun (Camb). 2015 Aug 18; 51(64):12732-5. Liu L, Ruiz DA, Dahcheh F, Bertrand G. PMID: 26166485.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    46. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Sci Adv. 2015 Jun; 1(5):e1500304. Jin L, Tolentino DR, Melaimi M, Bertrand G. PMID: 26601202.
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    47. Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2015 Jun 17; 137(23):7519-25. Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. PMID: 26011769.
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    48. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry. 2015 Jun 01; 21(23):8441-6. Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. PMID: 25925367.
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    49. A simple access to transition metal cyclopropenylidene complexes. Chem Commun (Camb). 2015 Mar 21; 51(23):4778-81. Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. PMID: 25621852.
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    50. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. Angew Chem Int Ed Engl. 2015 May 11; 54(20):6008-11. Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. PMID: 25802096.
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    51. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chem Asian J. 2015 Oct; 10(10):2139-42. Tolentino DR, Jin L, Melaimi M, Bertrand G. PMID: 25597889.
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    52. Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis. Angew Chem Int Ed Engl. 2015 Feb 02; 54(6):1919-23. Marx VM, Sullivan AH, Melaimi M, Virgil SC, Keitz BK, Weinberger DS, Bertrand G, Grubbs RH. PMID: 25522160.
      View in: PubMed   Mentions: 8     Fields:    Translation:Cells
    53. Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Acc Chem Res. 2015 Feb 17; 48(2):256-66. Soleilhavoup M, Bertrand G. PMID: 25515548.
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    54. Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). J Am Chem Soc. 2014 Dec 10; 136(49):17123-35. Jerabek P, Roesky HW, Bertrand G, Frenking G. PMID: 25394669.
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    55. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry. 2015 Jan 02; 21(1):199-204. Dahcheh F, Stephan DW, Bertrand G. PMID: 25414006.
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    56. Reactivity of a stable phosphinonitrene towards small molecules. Chemistry. 2015 Jan 02; 21(1):191-8. Dielmann F, Bertrand G. PMID: 25395098.
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    57. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angew Chem Int Ed Engl. 2014 Nov 24; 53(48):13159-63. Dahcheh F, Martin D, Stephan DW, Bertrand G. PMID: 25267591.
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    58. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. J Am Chem Soc. 2014 Oct 01; 136(39):13594-7. Hu X, Martin D, Melaimi M, Bertrand G. PMID: 25222130.
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    59. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb). 2014 Jul 25; 50(58):7837-9. Ruiz DA, Melaimi M, Bertrand G. PMID: 24909943.
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    60. Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. Angew Chem Int Ed Engl. 2014 Aug 18; 53(34):9059-63. Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. PMID: 24985149.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    61. One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl3 adduct. Angew Chem Int Ed Engl. 2014 Jul 28; 53(31):8176-9. Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. PMID: 24961494.
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    62. Two-coordinate Fe° and Co° complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2014 Aug 04; 53(32):8427-31. Ung G, Rittle J, Soleilhavoup M, Bertrand G, Peters JC. PMID: 24953342.
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    63. Cross-coupling reactions between stable carbenes. Angew Chem Int Ed Engl. 2014 Jun 16; 53(25):6550-3. Weinstein CM, Martin CD, Liu L, Bertrand G. PMID: 24838590.
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    64. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc. 2014 Apr 30; 136(17):6235-8. Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. PMID: 24731250.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    65. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. J Am Chem Soc. 2014 Apr 02; 136(13):5023-30. Martin D, Canac Y, Lavallo V, Bertrand G. PMID: 24634983.
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    66. Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc. 2014 Mar 12; 136(10):3800-2. Dielmann F, Andrada DM, Frenking G, Bertrand G. PMID: 24559041.
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    67. Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. Chem Commun (Camb). 2014 Mar 07; 50(19):2431-3. Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G. PMID: 24448261.
      View in: PubMed   Mentions: 4     Fields:    
    68. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2013 Dec 18; 135(50):18766-9. Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 24304381.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    69. Experimental and computational studies of anti-Bredt amidinium salts. Chemistry. 2013 Oct 25; 19(44):14895-901. Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. PMID: 24105742.
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    70. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). J Am Chem Soc. 2013 Sep 25; 135(38):14071-3. Dielmann F, Moore CE, Rheingold AL, Bertrand G. PMID: 24007472.
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    71. ß- and a-Hydride abstraction in Gold(I) alkyl complexes. Angew Chem Int Ed Engl. 2013 Oct 18; 52(43):11388-91. Ung G, Bertrand G. PMID: 24027200.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    72. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chem Asian J. 2013 Dec; 8(12):2940-2. Ruiz DA, Melaimi M, Bertrand G. PMID: 23960023.
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    73. Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci. 2013 Aug 01; 4(8):3020-3030. Martin CD, Soleilhavoup M, Bertrand G. PMID: 23878717.
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    74. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8964-7. Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. PMID: 23861304.
      View in: PubMed   Mentions: 10     Fields:    
    75. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl. 2013 Jul 15; 52(29):7590-2. Ruiz DA, Ung G, Melaimi M, Bertrand G. PMID: 23765789.
      View in: PubMed   Mentions: 10     Fields:    Translation:Cells
    76. An air-stable oxyallyl radical cation. Angew Chem Int Ed Engl. 2013 Jul 01; 52(27):7014-7. Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 23720417.
      View in: PubMed   Mentions: 1     Fields:    
    77. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb). 2013 May 18; 49(40):4486-8. Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. PMID: 23571800.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    78. Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. Chem Commun (Camb). 2013 May 18; 49(40):4483-5. López-Gómez MJ, Martin D, Bertrand G. PMID: 23552965.
      View in: PubMed   Mentions: 3     Fields:    Translation:Cells
    79. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the p-accepting properties of carbenes. Angew Chem Int Ed Engl. 2013 Mar 04; 52(10):2939-43. Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. PMID: 23364832.
      View in: PubMed   Mentions: 17     Fields:    
    80. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angew Chem Int Ed Engl. 2013 Jan 07; 52(2):758-61. Ung G, Soleilhavoup M, Bertrand G. PMID: 23169762.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    81. Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes. Chemistry. 2012 Nov 12; 18(46):14627-31. Yan X, Bouffard J, Guisado-Barrios G, Donnadieu B, Bertrand G. PMID: 23042507.
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    82. A crystalline singlet phosphinonitrene: a nitrogen atom-transfer agent. Science. 2012 Sep 21; 337(6101):1526-8. Dielmann F, Back O, Henry-Ellinger M, Jerabek P, Frenking G, Bertrand G. PMID: 22997335.
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    83. C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions. Chemistry. 2012 Oct 08; 18(41):12955-7. Ung G, Bertrand G. PMID: 22961643.
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    84. Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). Chem Commun (Camb). 2012 Jul 18; 48(56):7088-90. Ung G, Mendoza-Espinosa D, Bertrand G. PMID: 22684100.
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    85. A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity. Angew Chem Int Ed Engl. 2012 Jun 18; 51(25):6172-5. Martin D, Lassauque N, Donnadieu B, Bertrand G. PMID: 22565863.
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    86. Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry. 2012 Apr 27; 18(18):5676-92. Celik MA, Sure R, Klein S, Kinjo R, Bertrand G, Frenking G. PMID: 22434609.
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    87. Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C=C-S-C(S)NR2. Angew Chem Int Ed Engl. 2011 Oct 10; 50(42):9923-5. Ung G, Frey GD, Schoeller WW, Bertrand G. PMID: 23210141.
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    88. A Brief Survey of our Contribution to Stable Carbene Chemistry. Organometallics. 2011 Oct 24; 30(20):5304-5313. Martin D, Melaimi M, Soleilhavoup M, Bertrand G. PMID: 22707843.
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    89. Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. Chem Commun (Camb). 2011 Oct 14; 47(38):10614-6. Mendoza-Espinosa D, Ung G, Donnadieu B, Bertrand G. PMID: 21879048.
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    90. Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene. J Organomet Chem. 2011 Aug 15; 696(17):2899-2903. Dehope A, Donnadieu B, Bertrand G. PMID: 21765542.
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    91. Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science. 2011 Jul 29; 333(6042):610-3. Kinjo R, Donnadieu B, Celik MA, Frenking G, Bertrand G. PMID: 21798945.
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    92. Stability and electronic properties of imidazole-based mesoionic carbenes. Chemistry. 2011 Jul 18; 17(30):8269-72. Ung G, Bertrand G. PMID: 21656597.
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    93. Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. J Am Chem Soc. 2011 Jun 08; 133(22):8498-501. Keitz BK, Bouffard J, Bertrand G, Grubbs RH. PMID: 21574621.
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    94. Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. Angew Chem Int Ed Engl. 2011 Jun 06; 50(24):5560-3. Kinjo R, Donnadieu B, Bertrand G. PMID: 21574224.
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    95. A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene. Angew Chem Int Ed Engl. 2011 Apr 26; 50(18):4215-8. Ung G, Mendoza-Espinosa D, Bouffard J, Bertrand G. PMID: 21472947.
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    96. Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics. 2011 Mar 09; 30(9):2617-2627. Bouffard J, Keitz BK, Tonner R, Lavallo V, Guisado-Barrios G, Frenking G, Grubbs RH, Bertrand G. PMID: 21572542.
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    97. Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts. Chem Asian J. 2011 Apr 04; 6(4):1099-103. Mendoza-Espinosa D, Donnadieu B, Bertrand G. PMID: 21322115.
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    98. Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. Angew Chem Int Ed Engl. 2011 Jan 03; 50(1):268-71. Lavallo V, El-Batta A, Bertrand G, Grubbs RH. PMID: 21110365.
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    99. Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). Organometallics. 2011; 30(21):6017-6021. Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. PMID: 22096269.
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    100. Stable singlet carbenes as mimics for transition metal centers. Chem Sci. 2011 Jan 01; 2(3):389-399. Martin D, Soleilhavoup M, Bertrand G. PMID: 21743834.
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    101. A persistent (amino)(ferrocenyl)carbene(). New J Chem. 2011 Jan 01; 35(10):2037-2042. Dehope A, Mendoza-Espinosa D, Donnadieu B, Bertrand G. PMID: 22707878.
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    102. Activation of Si-H, B-H, and P-H bonds at a single nonmetal center. Angew Chem Int Ed Engl. 2010 Dec 03; 49(49):9444-7. Frey GD, Masuda JD, Donnadieu B, Bertrand G. PMID: 21031393.
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    103. Stable cyclic carbenes and related species beyond diaminocarbenes. Angew Chem Int Ed Engl. 2010 Nov 15; 49(47):8810-49. Melaimi M, Soleilhavoup M, Bertrand G. PMID: 20836099.
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    104. Synthesis of a room-temperature-stable dimeric copper(I) hydride. Chem Asian J. 2011 Feb 01; 6(2):402-5. Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 20945453.
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    105. Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). Angew Chem Int Ed Engl. 2010 Aug 09; 49(34):5930-3. Kinjo R, Donnadieu B, Bertrand G. PMID: 20632430.
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    106. A crystalline phosphinyl radical cation. J Am Chem Soc. 2010 Aug 04; 132(30):10262-3. Back O, Celik MA, Frenking G, Melaimi M, Donnadieu B, Bertrand G. PMID: 20662507.
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    107. Introduction to main group chemistry. Chem Rev. 2010 Jul 14; 110(7):3851. Bertrand G. PMID: 20672857.
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    108. Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). Angew Chem Int Ed Engl. 2010 Jun 28; 49(28):4759-62. Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. PMID: 20509134.
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    109. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. J Am Chem Soc. 2010 Jun 02; 132(21):7264-5. Mendoza-Espinosa D, Donnadieu B, Bertrand G. PMID: 20443633.
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    110. Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nat Chem. 2010 May; 2(5):369-73. Back O, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. PMID: 20414236.
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    111. Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. Angew Chem Int Ed Engl. 2010; 49(5):942-5. Zeng X, Kinjo R, Donnadieu B, Bertrand G. PMID: 20058283.
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    112. Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts. Chem Asian J. 2009 Nov 02; 4(11):1745-50. Kuchenbeiser G, Soleilhavoup M, Donnadieu B, Bertrand G. PMID: 19780080.
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    113. Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science. 2009 Oct 23; 326(5952):556-9. Aldeco-Perez E, Rosenthal AJ, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. PMID: 19900893.
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    114. Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids. J Am Chem Soc. 2009 Sep 30; 131(38):13681-9. Fuks G, Saffon N, Maron L, Bertrand G, Bourissou D. PMID: 19772363.
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    115. Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. J Am Chem Soc. 2009 Aug 26; 131(33):11875-81. Fernández I, Dyker CA, DeHope A, Donnadieu B, Frenking G, Bertrand G. PMID: 19645451.
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    116. Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. Org Lett. 2009 Aug 06; 11(15):3166-9. Zeng X, Soleilhavoup M, Bertrand G. PMID: 19719176.
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    117. Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes. Chem Asian J. 2009 Aug 03; 4(8):1225-8. Tran HN, Donnadieu B, Bertrand G, Mathey F. PMID: 19557786.
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    118. Carbenes introduction. Chem Rev. 2009 Aug; 109(8):3209-10. Arduengo AJ, Bertrand G. PMID: 19642638.
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    119. Chemical bonding: Rethinking carbon. Nat Chem. 2009 Jul; 1(4):265-6. Dyker CA, Bertrand G. PMID: 21378867.
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    120. Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. J Am Chem Soc. 2009 Jun 24; 131(24):8690-6. Zeng X, Frey GD, Kinjo R, Donnadieu B, Bertrand G. PMID: 19456108.
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    121. Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. Angew Chem Int Ed Engl. 2009; 48(26):4792-5. Melaimi M, Parameswaran P, Donnadieu B, Frenking G, Bertrand G. PMID: 19472243.
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    122. Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions. Angew Chem Int Ed Engl. 2009; 48(26):4796-9. Asay M, Donnadieu B, Schoeller WW, Bertrand G. PMID: 19472245.
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    123. Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angew Chem Int Ed Engl. 2009; 48(30):5530-3. Back O, Kuchenbeiser G, Donnadieu B, Bertrand G. PMID: 19544519.
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    124. Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family. Angew Chem Int Ed Engl. 2009; 48(3):517-20. Kinjo R, Ishida Y, Donnadieu B, Bertrand G. PMID: 19072812.
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    125. A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine. Chemistry. 2009; 15(13):3056-60. Zeng X, Frey GD, Kousar S, Bertrand G. PMID: 19219866.
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    126. Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines. Inorg Chem. 2008 Nov 03; 47(21):9751-3. Giziroglu E, Donnadieu B, Bertrand G. PMID: 18841958.
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    127. A persistent P,N-heterocyclic carbene. Chem Commun (Camb). 2008 Oct 21; (39):4711-3. Frey GD, Song M, Bourg JB, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 18830468.
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    128. Chemistry. Soluble allotropes of main-group elements. Science. 2008 Aug 22; 321(5892):1050-1. Dyker CA, Bertrand G. PMID: 18719272.
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    129. 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker. Dalton Trans. 2008 Sep 07; (33):4482-7. Rodriguez A, Fuks G, Bourg JB, Bourissou D, Tham FS, Bertrand G. PMID: 18698452.
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    130. Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes. Inorg Chem. 2008 May 19; 47(10):3949-51. Asay M, Donnadieu B, Baceiredo A, Soleilhavoup M, Bertrand G. PMID: 18422308.
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    131. Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. J Organomet Chem. 2008 Apr; 693(8-9):1674-1682. Frey GD, Dewhurst RD, Kousar S, Donnadieu B, Bertrand G. PMID: 19343084.
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    133. Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. Organometallics. 2008 Jan 12; 27(4):563-566. Anderson DR, Ung T, Mkrtumyan G, Bertrand G, Grubbs RH, Schrodi Y. PMID: 18584055.
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    134. Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane. Angew Chem Int Ed Engl. 2008; 47(39):7530-3. Asay M, Kato T, Saffon-Merceron N, Cossío FP, Baceiredo A, Bertrand G. PMID: 18704912.
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    135. The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus. Angew Chem Int Ed Engl. 2008; 47(1):155-9. Gandon V, Bourg JB, Tham FS, Schoeller WW, Bertrand G. PMID: 18022990.
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    136. Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes. Angew Chem Int Ed Engl. 2008; 47(12):2271-4. Vignolle J, Gornitzka H, Donnadieu B, Bourissou D, Bertrand G. PMID: 18273845.
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    137. Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. Angew Chem Int Ed Engl. 2008; 47(17):3206-9. Dyker CA, Lavallo V, Donnadieu B, Bertrand G. PMID: 18311741.
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    138. Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. Angew Chem Int Ed Engl. 2008; 47(29):5411-4. Lavallo V, Dyker CA, Donnadieu B, Bertrand G. PMID: 18551494.
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    139. Tuning the nucleophilicity in cyclopropenylidenes. Chemistry. 2008; 14(15):4711-8. Schoeller WW, Frey GD, Bertrand G. PMID: 18404754.
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    140. Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. Angew Chem Int Ed Engl. 2008; 47(28):5224-8. Lavallo V, Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 18528830.
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    141. NHC-mediated aggregation of P4: isolation of a P12 cluster. J Am Chem Soc. 2007 Nov 21; 129(46):14180-1. Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. PMID: 17973395.
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    142. Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. Proc Natl Acad Sci U S A. 2007 Aug 21; 104(34):13569-73. Lavallo V, Frey GD, Kousar S, Donnadieu B, Bertrand G. PMID: 17698808.
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    143. Synthesis of phosphaformamidines and phosphaformamidinates. Chem Asian J. 2007 Jul 02; 2(7):904-8. Song M, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 17551916.
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    144. Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. Science. 2007 Apr 20; 316(5823):439-41. Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. PMID: 17446400.
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    145. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. J Org Chem. 2007 Apr 27; 72(9):3492-9. Jazzar R, Bourg JB, Dewhurst RD, Donnadieu B, Bertrand G. PMID: 17408289.
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    146. Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation). J Am Chem Soc. 2007 Jan 31; 129(4):978-85. Vignolle J, Gornitzka H, Maron L, Schoeller WW, Bourissou D, Bertrand G. PMID: 17243835.
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    147. Stable P-heterocyclic carbenes: scope and limitations. Chem Asian J. 2007 Jan 08; 2(1):178-87. Masuda JD, Martin D, Lyon-Saunier C, Baceiredo A, Gornitzka H, Donnadieu B, Bertrand G. PMID: 17441152.
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    148. Carbene activation of P4 and subsequent derivatization. Angew Chem Int Ed Engl. 2007; 46(37):7052-5. Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. PMID: 17705209.
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    149. Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2. Angew Chem Int Ed Engl. 2007; 46(47):9078-80. Pascual S, Asay M, Illa O, Kato T, Bertrand G, Saffon-Merceron N, Branchadell V, Baceiredo A. PMID: 17960549.
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    150. Recently reported crystalline isothiazole carbenes: myth or reality. Angew Chem Int Ed Engl. 2007; 46(36):6922-5; discussion 6926. DeHope A, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. PMID: 17661300.
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    151. Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls. Angew Chem Int Ed Engl. 2007; 46(30):5741-5. Bourg JB, Rodriguez A, Scheschkewitz D, Gornitzka H, Bourissou D, Bertrand G. PMID: 17592605.
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    152. Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2007; 46(38):7262-5. Anderson DR, Lavallo V, O'Leary DJ, Bertrand G, Grubbs RH. PMID: 17623287.
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    153. Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Angew Chem Int Ed Engl. 2007; 46(16):2899-902. Jazzar R, Dewhurst RD, Bourg JB, Donnadieu B, Canac Y, Bertrand G. PMID: 17352445.
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    154. A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane. Eur J Inorg Chem. 2006 Dec 01; 2006(24):5076-5080. Canac Y, Aniol GE, Conejero S, Donnadieu B, Bertrand G. PMID: 19763185.
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    156. Synthesis of extended polyphosphacumulenes. Chemistry. 2006 Nov 15; 12(33):8444-50. Martin D, Tham FS, Baceiredo A, Bertrand G. PMID: 17009365.
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    157. Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. Angew Chem Int Ed Engl. 2006 Oct 13; 45(40):6652-5. Lavallo V, Ishida Y, Donnadieu B, Bertrand G. PMID: 16986195.
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    158. Stable four-pi-electron, four-membered heterocyclic cations and carbenes. Proc Natl Acad Sci U S A. 2006 Sep 12; 103(37):13585-8. Ishida Y, Donnadieu B, Bertrand G. PMID: 16950877.
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    159. New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. Chem Asian J. 2006 Jul 17; 1(1-2):155-60. Conejero S, Song M, Martin D, Canac Y, Soleilhavoup M, Bertrand G. PMID: 17441050.
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    160. CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. Angew Chem Int Ed Engl. 2006 May 19; 45(21):3488-91. Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. PMID: 16637087.
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    161. Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory. Science. 2006 May 05; 312(5774):722-4. Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. PMID: 16614171.
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    162. Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. J Am Chem Soc. 2006 Jan 18; 128(2):459-64. Canac Y, Conejero S, Soleilhavoup M, Donnadieu B, Bertrand G. PMID: 16402832.
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    163. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. J Organomet Chem. 2006; 691(14):3201-3205. Jazzar R, Liang H, Donnadieu B, Bertrand G. PMID: 19543436.
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    164. A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. Angew Chem Int Ed Engl. 2005 Nov 11; 44(44):7236-9. Lavallo V, Canac Y, DeHope A, Donnadieu B, Bertrand G. PMID: 16229037.
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    165. Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. Angew Chem Int Ed Engl. 2005 Sep 05; 44(35):5705-9. Lavallo V, Canac Y, Präsang C, Donnadieu B, Bertrand G. PMID: 16059961.
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    166. Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds. Angew Chem Int Ed Engl. 2005 Aug 26; 44(34):5497-500. Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. PMID: 16052642.
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    167. Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. J Am Chem Soc. 2005 Jul 27; 127(29):10182-3. Präsang C, Donnadieu B, Bertrand G. PMID: 16028925.
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    168. Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. J Org Chem. 2005 Jul 08; 70(14):5671-7. Martin D, Illa O, Baceiredo A, Bertrand G, Ortuño RM, Branchadell V. PMID: 15989352.
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    169. Persistent (amino)(silyl)carbenes. J Am Chem Soc. 2005 May 25; 127(20):7312-3. Canac Y, Conejero S, Donnadieu B, Schoeller WW, Bertrand G. PMID: 15898770.
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    170. Evidence for radical fragmentations from persistent singlet carbenes. J Am Chem Soc. 2005 Mar 16; 127(10):3292-3. Cattoën X, Miqueu K, Gornitzka H, Bourissou D, Bertrand G. PMID: 15755142.
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    171. A stable P-heterocyclic carbene. Angew Chem Int Ed Engl. 2005 Mar 04; 44(11):1700-3. Martin D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G. PMID: 15712311.
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    172. A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity. J Organomet Chem. 2005; 690(24-25):5541-5545. Teuma E, Lyon-Saunier C, Gornitzka H, Mignani G, Baceiredo A, Bertrand G. PMID: 19543437.
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    173. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. Inorg Chem. 2004 Oct 18; 43(21):6546-8. Dumitrescu A, Rudzevich VL, Romanenko VD, Mari A, Schoeller WW, Bourissou D, Bertrand G. PMID: 15476350.
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    174. Evidence for the coexistence of two bond-stretch isomers in solution. Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4880-3. Rodriguez A, Olsen RA, Ghaderi N, Scheschkewitz D, Tham FS, Mueller LJ, Bertrand G. PMID: 15372558.
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    175. Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid). Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4876-80. Rodriguez A, Tham FS, Schoeller WW, Bertrand G. PMID: 15372559.
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    176. Chemistry. The modest undressing of a silicon center. Science. 2004 Aug 06; 305(5685):783-5. Bertrand G. PMID: 15297652.
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    177. Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. Angew Chem Int Ed Engl. 2004 Aug 06; 43(31):4089-93. Conejero S, Canac Y, Tham FS, Bertrand G. PMID: 15300703.
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    178. Synthesis, reactivity, and ligand properties of a stable alkyl carbene. J Am Chem Soc. 2004 Jul 21; 126(28):8670-1. Lavallo V, Mafhouz J, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. PMID: 15250717.
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    179. Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. Chemistry. 2004 Apr 19; 10(8):1982-6. Krysiak J, Lyon C, Baceiredo A, Gornitzka H, Mikolajczyk M, Bertrand G. PMID: 15079838.
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    180. Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. J Am Chem Soc. 2004 Feb 04; 126(4):1016-7. Otto M, Conejero S, Canac Y, Romanenko VD, Rudzevitch V, Bertrand G. PMID: 14746458.
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    181. Sigma-bond stretching: a static approach for a dynamic process. Angew Chem Int Ed Engl. 2004 Feb 01; 43(5):585-7. Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. PMID: 14743410.
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    182. Theoretical study of rhodium(I) carbene complexes: the structural versatility of phosphino- compared with aminocarbenes. Chemistry. 2003 Dec 05; 9(23):5858-64. Miqueu K, Despagnet-Ayoub E, Dyer PW, Bourissou D, Bertrand G. PMID: 14673857.
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    183. Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a nucleophilic stable carbene to aromatic aldehydes. J Org Chem. 2003 Oct 03; 68(20):7707-10. Illa O, Gornitzka H, Baceiredo A, Bertrand G, Branchadell V, Ortuño RM. PMID: 14510546.
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    184. Synthesis of carbenes through substitution reactions at a carbene center. Science. 2003 Aug 29; 301(5637):1223-5. Merceron-Saffon N, Baceiredo A, Gornitzka H, Bertrand G. PMID: 12947194.
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    185. nido-Five-vertex clusters: in and out of boron chemistry. Angew Chem Int Ed Engl. 2003 Aug 11; 42(31):3578-80. Canac Y, Bertrand G. PMID: 12916028.
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    186. On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As). Chemistry. 2003 Aug 04; 9(15):3611-7. Schoeller WW, Rozhenko A, Bourissou D, Bertrand G. PMID: 12898688.
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    187. A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete. Chemistry. 2002 Dec 02; 8(23):5305-11. Amsallem D, Mazières S, Piquet-Fauré V, Gornitzka H, Baceiredo A, Bertrand G. PMID: 12432498.
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    188. C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents. Chem Commun (Camb). 2002 Oct 07; (19):2250-1. Merceron N, Baceiredo A, Gornitzka H, Bertrand G. PMID: 12398001.
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    189. Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene. Angew Chem Int Ed Engl. 2002 Aug 02; 41(15):2835-7. Despagnet E, Gornitzka H, Rozhenko AB, Schoeller WW, Bourissou D, Bertrand G. PMID: 12203501.
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    190. The stable pentamethylcyclopentadienyl cation remains unknown. Angew Chem Int Ed Engl. 2002 Jul 02; 41(13):2275-6. Otto M, Scheschkewitz D, Kato T, Midland MM, Lambert JB, Bertrand G. PMID: 12203563.
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    191. Stable (amino)(phosphino)carbenes: difunctional molecules. J Am Chem Soc. 2002 Jun 19; 124(24):6806-7. Merceron N, Miqueu K, Baceiredo A, Bertrand G. PMID: 12059184.
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    192. The first "naked" primary phosphanide anion [ArPH](-). Angew Chem Int Ed Engl. 2002 Apr 02; 41(7):1193-5. Rudzevich VL, Gornitzka H, Miqueu K, Sotiropoulos JM, Pfister-Guillouzo G, Romanenko VD, Bertrand G. PMID: 12491256.
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    193. Synthesis and rearrangement of diphosphorus analogues of amidinium salts. J Am Chem Soc. 2002 Mar 20; 124(11):2506-12. Kato T, Gornitzka H, Baceiredo A, Schoeller WW, Bertrand G. PMID: 11890799.
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    194. Singlet diradicals: from transition states to crystalline compounds. Science. 2002 Mar 08; 295(5561):1880-1. Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. PMID: 11884750.
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    195. Stable Carbenes. Chem Rev. 2000 Jan 12; 100(1):39-92. Bourissou D, Guerret O, Gabbaï FP, Bertrand G. PMID: 11749234.
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    196. Synthetic Utility of Stable Phosphanylcarbenes: Synthesis and Crystal Structure of an a-(Lithiomethylene)phosphorane. Angew Chem Int Ed Engl. 1999 Mar 01; 38(5):678-680. Goumri-Magnet S, Gornitzka H, Baceiredo A, Bertrand G. PMID: 29711539.
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    197. The Azide-Nitrilimine Analogy in Aluminum Chemistry. Angew Chem Int Ed Engl. 1998 Apr 20; 37(7):989-992. Emig N, Gabbaï FP, Krautscheid H, Réau R, Bertrand G. PMID: 29711487.
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    198. Ylidic Four p Electron Four-Membered ?5 -Phosphorus Heterocycles: Electronical Isomers of Heterocyclobutadienes. Angew Chem Int Ed Engl. 1998 Feb 16; 37(3):270-281. Bertrand G. PMID: 29711272.
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    199. N-Phosphino- and N-Phosphonionitrilimines: From Nucleophilic to Electrophilic 1,3-Dipoles. J Org Chem. 1997 Jan 24; 62(2):292-296. Palacios F, Pagalday J, Piquet V, Dahan F, Baceiredo A, Bertrand G. PMID: 11671401.
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    200. X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2lambda(5)-Diazaphosphetes: A New Type of 4-pi-Electron 4-Membered Heterocycle. Inorg Chem. 1996 Apr 24; 35(9):2458-2462. Alcaraz G, Baceiredo A, Nieger M, Schoeller WW, Bertrand G. PMID: 11666457.
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