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Guy Bertrand

Title(s)Professor, Chemistry and Biochemistry
SchoolVc-academic Affairs
Address9500 Gilman Drive #
La Jolla CA 92093
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    Altmetrics Details PMC Citations indicate the number of times the publication was cited by articles in PubMed Central, and the Altmetric score represents citations in news articles and social media. (Note that publications are often cited in additional ways that are not shown here.) Fields are based on how the National Library of Medicine (NLM) classifies the publication's journal and might not represent the specific topic of the publication. Translation tags are based on the publication type and the MeSH terms NLM assigns to the publication. Some publications (especially newer ones and publications not in PubMed) might not yet be assigned Field or Translation tags.) Click a Field or Translation tag to filter the publications.
    1. Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. J Am Chem Soc. 2020 Sep 14. Peltier JL, Soleilhavoup M, Martin D, Jazzar R, Bertrand G. PMID: 32872772.
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    2. The influence of C(sp3)H-Selenium Interactions on the 77 Se NMR Quantification of the p -Accepting Properties of Carbenes. Angew Chem Int Ed Engl. 2020 Aug 21. Bertrand G, Junor G, Lorkowski J, Weinstein C, Jazzar R, Pietraszuk C. PMID: 32822513.
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    3. Injury, Illness, and Mental Health Risks in United States Domestic Mariners. J Occup Environ Med. 2020 Aug 05. Lefkowitz RY, Null DB, Slade MD, Redlich CA. PMID: 32769797.
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    4. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications. Chem Rev. 2020 May 13; 120(9):4141-4168. Jazzar R, Soleilhavoup M, Bertrand G. PMID: 32239922.
      View in: PubMed   Mentions: 1     Fields:    
    5. Imaging examination, diagnosis, and control and prevention of nosocomial infection for coronavirus disease 2019: Expert consensus of Hunan radiologist. Zhong Nan Da Xue Xue Bao Yi Xue Ban. 2020 Mar 28; 45(3):221-228. Liu J, Wang W. PMID: 32386011.
      View in: PubMed   Mentions: 1     Fields:    Translation:HumansCellsPHPublic Health
    6. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
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    7. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed ß-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
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    8. Reductive Elimination at Carbon under Steric Control. J Am Chem Soc. 2019 Jun 26; 141(25):9823-9826. Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. PMID: 31180660.
      View in: PubMed   Mentions: 1     Fields:    
    9. Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. Angew Chem Int Ed Engl. 2019 Feb 25; 58(9):2875-2878. Junor GP, Romero EA, Chen X, Jazzar R, Bertrand G. PMID: 30618172.
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    10. A crystalline monosubstituted carbene. Nat Chem. 2018 12; 10(12):1196-1200. Nakano R, Jazzar R, Bertrand G. PMID: 30323332.
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    11. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 07 25; 140(29):9255-9260. Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G. PMID: 29954178.
      View in: PubMed   Mentions: 3     Fields:    
    12. Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 21; 140(7):2546-2554. Hansmann MM, Melaimi M, Munz D, Bertrand G. PMID: 29382199.
      View in: PubMed   Mentions: 4     Fields:    
    13. Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 14; 140(6):2206-2213. Hansmann MM, Melaimi M, Bertrand G. PMID: 29342351.
      View in: PubMed   Mentions: 4     Fields:    
    14. Crystalline Monomeric Allenyl/Propargyl Radical. J Am Chem Soc. 2017 11 08; 139(44):15620-15623. Hansmann MM, Melaimi M, Bertrand G. PMID: 29046060.
      View in: PubMed   Mentions: 3     Fields:    
    15. Borylenes: An Emerging Class of Compounds. Angew Chem Int Ed Engl. 2017 08 21; 56(35):10282-10292. Soleilhavoup M, Bertrand G. PMID: 28577325.
      View in: PubMed   Mentions: 5     Fields:    
    16. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Angew Chem Int Ed Engl. 2017 08 14; 56(34):10046-10068. Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G. PMID: 28376253.
      View in: PubMed   Mentions: 21     Fields:    
    17. Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. J Am Chem Soc. 2017 06 14; 139(23):7753-7756. Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G. PMID: 28541687.
      View in: PubMed   Mentions: 2     Fields:    
    18. (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. Chem Sci. 2017 May 01; 8(5):3720-3725. Hansmann MM, Ruiz DA, Liu LL, Jazzar R, Bertrand G. PMID: 28580107.
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    19. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
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    20. The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals. Chemistry. 2017 May 02; 23(25):6206-6212. Mahoney JK, Jazzar R, Royal G, Martin D, Bertrand G. PMID: 28105672.
      View in: PubMed   Mentions: 1     Fields:    
    21. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. J Am Chem Soc. 2016 12 14; 138(49):15885-15888. Hansmann MM, Bertrand G. PMID: 27960331.
      View in: PubMed   Mentions: 4     Fields:    
    22. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angew Chem Int Ed Engl. 2016 10 04; 55(41):12886-90. Munz D, Chu J, Melaimi M, Bertrand G. PMID: 27628756.
      View in: PubMed   Mentions: 5     Fields:    
    23. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chem Commun (Camb). 2016 Aug 18; 52(69):10563-5. Romero EA, Peltier JL, Jazzar R, Bertrand G. PMID: 27498971.
      View in: PubMed   Mentions: 2     Fields:    
    24. Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. Chem Sci. 2017 Jan 01; 8(1):165-168. Romero EA, Jazzar R, Bertrand G. PMID: 28451161.
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    25. Singlet (Phosphino)phosphinidenes are Electrophilic. J Am Chem Soc. 2016 07 13; 138(27):8356-9. Hansmann MM, Jazzar R, Bertrand G. PMID: 27340902.
      View in: PubMed   Mentions: 6     Fields:    
    26. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. J Am Chem Soc. 2016 06 29; 138(25):7884-7. Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. PMID: 27304485.
      View in: PubMed   Mentions: 3     Fields:    
    27. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chem Commun (Camb). 2016 Feb 14; 52(13):2733-5. Peltier JL, Jazzar R, Melaimi M, Bertrand G. PMID: 26757745.
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    28. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Adv Synth Catal. 2016 Mar 17; 358(6):965-969. Martin D, Marx VM, Grubbs RH, Bertrand G. PMID: 27594819.
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    29. Isolation of Au-, Co-?1PCO and Cu-?2PCO complexes, conversion of an Ir-?1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chem Sci. 2016 Mar 01; 7(3):2335-2341. Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. PMID: 29997776.
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    30. The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. J Am Chem Soc. 2015 Dec 23; 137(50):15696-8. Jin L, Romero EA, Melaimi M, Bertrand G. PMID: 26611196.
      View in: PubMed   Mentions: 4     Fields:    
    31. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes. Chem Sci. 2016 Jan 01; 7(1):150-154. Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. PMID: 28966767.
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    32. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chem Commun (Camb). 2015 Aug 18; 51(64):12732-5. Liu L, Ruiz DA, Dahcheh F, Bertrand G. PMID: 26166485.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    33. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Sci Adv. 2015 Jun; 1(5):e1500304. Jin L, Tolentino DR, Melaimi M, Bertrand G. PMID: 26601202.
      View in: PubMed   Mentions: 13     Fields:    
    34. Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2015 Jun 17; 137(23):7519-25. Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. PMID: 26011769.
      View in: PubMed   Mentions: 6     Fields:    
    35. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry. 2015 Jun 01; 21(23):8441-6. Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. PMID: 25925367.
      View in: PubMed   Mentions: 5     Fields:    
    36. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. Angew Chem Int Ed Engl. 2015 May 11; 54(20):6008-11. Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. PMID: 25802096.
      View in: PubMed   Mentions: 2     Fields:    
    37. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chem Asian J. 2015 Oct; 10(10):2139-42. Tolentino DR, Jin L, Melaimi M, Bertrand G. PMID: 25597889.
      View in: PubMed   Mentions: 1     Fields:    
    38. Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Acc Chem Res. 2015 Feb 17; 48(2):256-66. Soleilhavoup M, Bertrand G. PMID: 25515548.
      View in: PubMed   Mentions: 39     Fields:    
    39. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry. 2015 Jan 02; 21(1):199-204. Dahcheh F, Stephan DW, Bertrand G. PMID: 25414006.
      View in: PubMed   Mentions: 1     Fields:    
    40. Reactivity of a stable phosphinonitrene towards small molecules. Chemistry. 2015 Jan 02; 21(1):191-8. Dielmann F, Bertrand G. PMID: 25395098.
      View in: PubMed   Mentions: 1     Fields:    
    41. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angew Chem Int Ed Engl. 2014 Nov 24; 53(48):13159-63. Dahcheh F, Martin D, Stephan DW, Bertrand G. PMID: 25267591.
      View in: PubMed   Mentions: 17     Fields:    
    42. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. J Am Chem Soc. 2014 Oct 01; 136(39):13594-7. Hu X, Martin D, Melaimi M, Bertrand G. PMID: 25222130.
      View in: PubMed   Mentions: 9     Fields:    
    43. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb). 2014 Jul 25; 50(58):7837-9. Ruiz DA, Melaimi M, Bertrand G. PMID: 24909943.
      View in: PubMed   Mentions: 16     Fields:    
    44. Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. Angew Chem Int Ed Engl. 2014 Aug 18; 53(34):9059-63. Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. PMID: 24985149.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    45. One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl3 adduct. Angew Chem Int Ed Engl. 2014 Jul 28; 53(31):8176-9. Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. PMID: 24961494.
      View in: PubMed   Mentions: 8     Fields:    
    46. Cross-coupling reactions between stable carbenes. Angew Chem Int Ed Engl. 2014 Jun 16; 53(25):6550-3. Weinstein CM, Martin CD, Liu L, Bertrand G. PMID: 24838590.
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    47. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc. 2014 Apr 30; 136(17):6235-8. Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. PMID: 24731250.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    48. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. J Am Chem Soc. 2014 Apr 02; 136(13):5023-30. Martin D, Canac Y, Lavallo V, Bertrand G. PMID: 24634983.
      View in: PubMed   Mentions: 6     Fields:    
    49. Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc. 2014 Mar 12; 136(10):3800-2. Dielmann F, Andrada DM, Frenking G, Bertrand G. PMID: 24559041.
      View in: PubMed   Mentions: 6     Fields:    
    50. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2013 Dec 18; 135(50):18766-9. Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 24304381.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    51. Experimental and computational studies of anti-Bredt amidinium salts. Chemistry. 2013 Oct 25; 19(44):14895-901. Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. PMID: 24105742.
      View in: PubMed   Mentions: 2     Fields:    
    52. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). J Am Chem Soc. 2013 Sep 25; 135(38):14071-3. Dielmann F, Moore CE, Rheingold AL, Bertrand G. PMID: 24007472.
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    53. ß- and a-Hydride abstraction in Gold(I) alkyl complexes. Angew Chem Int Ed Engl. 2013 Oct 18; 52(43):11388-91. Ung G, Bertrand G. PMID: 24027200.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    54. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chem Asian J. 2013 Dec; 8(12):2940-2. Ruiz DA, Melaimi M, Bertrand G. PMID: 23960023.
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    55. Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci. 2013 Aug 01; 4(8):3020-3030. Martin CD, Soleilhavoup M, Bertrand G. PMID: 23878717.
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    56. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8964-7. Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. PMID: 23861304.
      View in: PubMed   Mentions: 11     Fields:    
    57. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl. 2013 Jul 15; 52(29):7590-2. Ruiz DA, Ung G, Melaimi M, Bertrand G. PMID: 23765789.
      View in: PubMed   Mentions: 14     Fields:    Translation:Cells
    58. An air-stable oxyallyl radical cation. Angew Chem Int Ed Engl. 2013 Jul 01; 52(27):7014-7. Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 23720417.
      View in: PubMed   Mentions: 2     Fields:    
    59. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb). 2013 May 18; 49(40):4486-8. Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. PMID: 23571800.
      View in: PubMed   Mentions: 7     Fields:    Translation:Cells
    60. Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. Chem Commun (Camb). 2013 May 18; 49(40):4483-5. López-Gómez MJ, Martin D, Bertrand G. PMID: 23552965.
      View in: PubMed   Mentions: 3     Fields:    Translation:Cells
    61. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the p-accepting properties of carbenes. Angew Chem Int Ed Engl. 2013 Mar 04; 52(10):2939-43. Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. PMID: 23364832.
      View in: PubMed   Mentions: 20     Fields:    
    62. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angew Chem Int Ed Engl. 2013 Jan 07; 52(2):758-61. Ung G, Soleilhavoup M, Bertrand G. PMID: 23169762.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
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