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Guy Bertrand

Title(s)Professor, Chemistry and Biochemistry
SchoolVc-academic Affairs
Address9500 Gilman Drive #
La Jolla CA 92093
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    1. Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO. J Am Chem Soc. 2020 Oct 15. Peltier JL, Tomás-Mendivil E, Tolentino DR, Hansmann MM, Jazzar R, Bertrand G. PMID: 33054191.
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    2. Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. J Am Chem Soc. 2020 Sep 23; 142(38):16479-16485. Peltier JL, Soleilhavoup M, Martin D, Jazzar R, Bertrand G. PMID: 32872772.
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    3. The Influence of C(sp3 )H-Selenium Interactions on the 77 Se NMR Quantification of the p-Accepting Properties of Carbenes. Angew Chem Int Ed Engl. 2020 Aug 21. Junor GP, Lorkowski J, Weinstein CM, Jazzar R, Pietraszuk C, Bertrand G. PMID: 32822513.
      View in: PubMed   Mentions: 1     Fields:    
    4. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications. Chem Rev. 2020 May 13; 120(9):4141-4168. Jazzar R, Soleilhavoup M, Bertrand G. PMID: 32239922.
      View in: PubMed   Mentions: 1     Fields:    
    5. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
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    6. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed ß-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
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    7. Reductive Elimination at Carbon under Steric Control. J Am Chem Soc. 2019 Jun 26; 141(25):9823-9826. Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. PMID: 31180660.
      View in: PubMed   Mentions: 1     Fields:    
    8. Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. Angew Chem Int Ed Engl. 2019 Feb 25; 58(9):2875-2878. Junor GP, Romero EA, Chen X, Jazzar R, Bertrand G. PMID: 30618172.
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    9. A crystalline monosubstituted carbene. Nat Chem. 2018 12; 10(12):1196-1200. Nakano R, Jazzar R, Bertrand G. PMID: 30323332.
      View in: PubMed   Mentions: 1     Fields:    
    10. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 07 25; 140(29):9255-9260. Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G. PMID: 29954178.
      View in: PubMed   Mentions: 3     Fields:    
    11. Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 21; 140(7):2546-2554. Hansmann MM, Melaimi M, Munz D, Bertrand G. PMID: 29382199.
      View in: PubMed   Mentions: 5     Fields:    
    12. Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 14; 140(6):2206-2213. Hansmann MM, Melaimi M, Bertrand G. PMID: 29342351.
      View in: PubMed   Mentions: 4     Fields:    
    13. Crystalline Monomeric Allenyl/Propargyl Radical. J Am Chem Soc. 2017 11 08; 139(44):15620-15623. Hansmann MM, Melaimi M, Bertrand G. PMID: 29046060.
      View in: PubMed   Mentions: 3     Fields:    
    14. Borylenes: An Emerging Class of Compounds. Angew Chem Int Ed Engl. 2017 08 21; 56(35):10282-10292. Soleilhavoup M, Bertrand G. PMID: 28577325.
      View in: PubMed   Mentions: 5     Fields:    
    15. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Angew Chem Int Ed Engl. 2017 08 14; 56(34):10046-10068. Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G. PMID: 28376253.
      View in: PubMed   Mentions: 21     Fields:    
    16. Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. J Am Chem Soc. 2017 06 14; 139(23):7753-7756. Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G. PMID: 28541687.
      View in: PubMed   Mentions: 2     Fields:    
    17. (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. Chem Sci. 2017 May 01; 8(5):3720-3725. Hansmann MM, Ruiz DA, Liu LL, Jazzar R, Bertrand G. PMID: 28580107.
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    18. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
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    19. The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals. Chemistry. 2017 May 02; 23(25):6206-6212. Mahoney JK, Jazzar R, Royal G, Martin D, Bertrand G. PMID: 28105672.
      View in: PubMed   Mentions: 1     Fields:    
    20. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. J Am Chem Soc. 2016 12 14; 138(49):15885-15888. Hansmann MM, Bertrand G. PMID: 27960331.
      View in: PubMed   Mentions: 5     Fields:    
    21. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angew Chem Int Ed Engl. 2016 10 04; 55(41):12886-90. Munz D, Chu J, Melaimi M, Bertrand G. PMID: 27628756.
      View in: PubMed   Mentions: 6     Fields:    
    22. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chem Commun (Camb). 2016 Aug 18; 52(69):10563-5. Romero EA, Peltier JL, Jazzar R, Bertrand G. PMID: 27498971.
      View in: PubMed   Mentions: 2     Fields:    
    23. Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. Chem Sci. 2017 Jan 01; 8(1):165-168. Romero EA, Jazzar R, Bertrand G. PMID: 28451161.
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    24. Singlet (Phosphino)phosphinidenes are Electrophilic. J Am Chem Soc. 2016 07 13; 138(27):8356-9. Hansmann MM, Jazzar R, Bertrand G. PMID: 27340902.
      View in: PubMed   Mentions: 8     Fields:    
    25. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. J Am Chem Soc. 2016 06 29; 138(25):7884-7. Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. PMID: 27304485.
      View in: PubMed   Mentions: 4     Fields:    
    26. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chem Commun (Camb). 2016 Feb 14; 52(13):2733-5. Peltier JL, Jazzar R, Melaimi M, Bertrand G. PMID: 26757745.
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    27. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Adv Synth Catal. 2016 Mar 17; 358(6):965-969. Martin D, Marx VM, Grubbs RH, Bertrand G. PMID: 27594819.
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    28. Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chem Sci. 2016 Mar 01; 7(3):2335-2341. Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. PMID: 29997776.
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    29. The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. J Am Chem Soc. 2015 Dec 23; 137(50):15696-8. Jin L, Romero EA, Melaimi M, Bertrand G. PMID: 26611196.
      View in: PubMed   Mentions: 4     Fields:    
    30. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes. Chem Sci. 2016 Jan 01; 7(1):150-154. Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. PMID: 28966767.
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    31. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chem Commun (Camb). 2015 Aug 18; 51(64):12732-5. Liu L, Ruiz DA, Dahcheh F, Bertrand G. PMID: 26166485.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    32. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Sci Adv. 2015 Jun; 1(5):e1500304. Jin L, Tolentino DR, Melaimi M, Bertrand G. PMID: 26601202.
      View in: PubMed   Mentions: 13     Fields:    
    33. Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2015 Jun 17; 137(23):7519-25. Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. PMID: 26011769.
      View in: PubMed   Mentions: 6     Fields:    
    34. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry. 2015 Jun 01; 21(23):8441-6. Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. PMID: 25925367.
      View in: PubMed   Mentions: 5     Fields:    
    35. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. Angew Chem Int Ed Engl. 2015 May 11; 54(20):6008-11. Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. PMID: 25802096.
      View in: PubMed   Mentions: 2     Fields:    
    36. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chem Asian J. 2015 Oct; 10(10):2139-42. Tolentino DR, Jin L, Melaimi M, Bertrand G. PMID: 25597889.
      View in: PubMed   Mentions: 1     Fields:    
    37. Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Acc Chem Res. 2015 Feb 17; 48(2):256-66. Soleilhavoup M, Bertrand G. PMID: 25515548.
      View in: PubMed   Mentions: 40     Fields:    
    38. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry. 2015 Jan 02; 21(1):199-204. Dahcheh F, Stephan DW, Bertrand G. PMID: 25414006.
      View in: PubMed   Mentions: 1     Fields:    
    39. Reactivity of a stable phosphinonitrene towards small molecules. Chemistry. 2015 Jan 02; 21(1):191-8. Dielmann F, Bertrand G. PMID: 25395098.
      View in: PubMed   Mentions: 1     Fields:    
    40. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angew Chem Int Ed Engl. 2014 Nov 24; 53(48):13159-63. Dahcheh F, Martin D, Stephan DW, Bertrand G. PMID: 25267591.
      View in: PubMed   Mentions: 17     Fields:    
    41. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. J Am Chem Soc. 2014 Oct 01; 136(39):13594-7. Hu X, Martin D, Melaimi M, Bertrand G. PMID: 25222130.
      View in: PubMed   Mentions: 9     Fields:    
    42. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb). 2014 Jul 25; 50(58):7837-9. Ruiz DA, Melaimi M, Bertrand G. PMID: 24909943.
      View in: PubMed   Mentions: 16     Fields:    
    43. Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. Angew Chem Int Ed Engl. 2014 Aug 18; 53(34):9059-63. Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. PMID: 24985149.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    44. One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl3 adduct. Angew Chem Int Ed Engl. 2014 Jul 28; 53(31):8176-9. Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. PMID: 24961494.
      View in: PubMed   Mentions: 8     Fields:    
    45. Cross-coupling reactions between stable carbenes. Angew Chem Int Ed Engl. 2014 Jun 16; 53(25):6550-3. Weinstein CM, Martin CD, Liu L, Bertrand G. PMID: 24838590.
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    46. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc. 2014 Apr 30; 136(17):6235-8. Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. PMID: 24731250.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    47. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. J Am Chem Soc. 2014 Apr 02; 136(13):5023-30. Martin D, Canac Y, Lavallo V, Bertrand G. PMID: 24634983.
      View in: PubMed   Mentions: 7     Fields:    
    48. Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc. 2014 Mar 12; 136(10):3800-2. Dielmann F, Andrada DM, Frenking G, Bertrand G. PMID: 24559041.
      View in: PubMed   Mentions: 6     Fields:    
    49. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2013 Dec 18; 135(50):18766-9. Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 24304381.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    50. Experimental and computational studies of anti-Bredt amidinium salts. Chemistry. 2013 Oct 25; 19(44):14895-901. Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. PMID: 24105742.
      View in: PubMed   Mentions: 2     Fields:    
    51. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). J Am Chem Soc. 2013 Sep 25; 135(38):14071-3. Dielmann F, Moore CE, Rheingold AL, Bertrand G. PMID: 24007472.
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    52. ß- and a-Hydride abstraction in Gold(I) alkyl complexes. Angew Chem Int Ed Engl. 2013 Oct 18; 52(43):11388-91. Ung G, Bertrand G. PMID: 24027200.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    53. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chem Asian J. 2013 Dec; 8(12):2940-2. Ruiz DA, Melaimi M, Bertrand G. PMID: 23960023.
      View in: PubMed   Mentions: 1     Fields:    
    54. Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci. 2013 Aug 01; 4(8):3020-3030. Martin CD, Soleilhavoup M, Bertrand G. PMID: 23878717.
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    55. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8964-7. Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. PMID: 23861304.
      View in: PubMed   Mentions: 11     Fields:    
    56. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl. 2013 Jul 15; 52(29):7590-2. Ruiz DA, Ung G, Melaimi M, Bertrand G. PMID: 23765789.
      View in: PubMed   Mentions: 14     Fields:    Translation:Cells
    57. An air-stable oxyallyl radical cation. Angew Chem Int Ed Engl. 2013 Jul 01; 52(27):7014-7. Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 23720417.
      View in: PubMed   Mentions: 2     Fields:    
    58. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb). 2013 May 18; 49(40):4486-8. Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. PMID: 23571800.
      View in: PubMed   Mentions: 7     Fields:    Translation:Cells
    59. Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. Chem Commun (Camb). 2013 May 18; 49(40):4483-5. López-Gómez MJ, Martin D, Bertrand G. PMID: 23552965.
      View in: PubMed   Mentions: 3     Fields:    Translation:Cells
    60. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the p-accepting properties of carbenes. Angew Chem Int Ed Engl. 2013 Mar 04; 52(10):2939-43. Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. PMID: 23364832.
      View in: PubMed   Mentions: 24     Fields:    
    61. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angew Chem Int Ed Engl. 2013 Jan 07; 52(2):758-61. Ung G, Soleilhavoup M, Bertrand G. PMID: 23169762.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
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