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Guy Bertrand

Title(s)Professor, Chemistry and Biochemistry
SchoolVc-academic Affairs
Address9500 Gilman Drive #
La Jolla CA 92093
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    New Carbon-based Ligands for Hydroamination and olefin metathesis catalysts
    NIH R01GM068825Aug 1, 2005 - Jul 31, 2014
    Role: Principal Investigator

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    Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help. to make corrections and additions.
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    Altmetrics Details PMC Citations indicate the number of times the publication was cited by articles in PubMed Central, and the Altmetric score represents citations in news articles and social media. (Note that publications are often cited in additional ways that are not shown here.) Fields are based on how the National Library of Medicine (NLM) classifies the publication's journal and might not represent the specific topic of the publication. Translation tags are based on the publication type and the MeSH terms NLM assigns to the publication. Some publications (especially newer ones and publications not in PubMed) might not yet be assigned Field or Translation tags.) Click a Field or Translation tag to filter the publications.
    1. Organocatalysis promoted by 1,2,3-triazolylidenes (MICs): carbenes which make a difference. Chem Soc Rev. 2025 Oct 01; 54(19):9008-9026. Gao F, Yan X, Bertrand G. PMID: 40916743.
      View in: PubMed   Mentions:    Fields:    
    2. A Crystalline Annelated Pyridin-1-ylidene and Its Isomerization into a Pyridin-3-ylidene. J Am Chem Soc. 2025 May 07; 147(18):14972-14977. Lorkowski J, Gojiashvili L, Yorkgitis P, Pichon D, Talcik J, Gembicky M, Roisnel T, Baslé O, Jazzar R, Mauduit M, Bertrand G. PMID: 40294399.
      View in: PubMed   Mentions: 1     Fields:    
    3. Switching mesoionic carbene-organocatalysis from radical to ionic pathway through base-controlled formation of Breslow intermediates versus Breslow enolates. Chem Sci. 2025 May 28; 16(21):9163-9168. Jiao J, Zhang Z, Lu G, Huang S, Bian Y, Gao F, Bertrand G, Yan X. PMID: 40313515; PMCID: PMC12041792.
      View in: PubMed   Mentions:
    4. Singlet Carbenes Are Stereoinductive Main Group Ambiphiles. J Am Chem Soc. 2025 Apr 30; 147(17):14777-14784. Lorkowski J, Yorkgitis P, Morvan F, Morvan J, Vanthuyne N, Roisnel T, Gembicky M, Bertrand G, Mauduit M, Jazzar R. PMID: 40257435.
      View in: PubMed   Mentions: 1     Fields:    
    5. A carbene-stabilized diphosphorus: a triple-bonded diphosphorus (P[triple bond, length as m-dash]P) and a bis(phosphinidene) (P-P) transfer agent. Chem Sci. 2024 Sep 02. Yoon JS, Abdellaoui M, Gembicky M, Bertrand G. PMID: 39246371; PMCID: PMC11379058.
      View in: PubMed   Mentions: 1  
    6. Genuine carbene versus carbene-like reactivity. Angew Chem Int Ed Engl. 2024 Jul 01; 63(27):e202401020. Lorkowski J, Yorkgitis P, Serrato MR, Gembicky M, Pietraszuk C, Bertrand G, Jazzar R. PMID: 38632078.
      View in: PubMed   Mentions: 2     Fields:    
    7. Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis. Dalton Trans. 2024 Mar 19; 53(12):5346-5350. Talcik J, Serrato MR, Del Vecchio A, Colombel-Rouen S, Morvan J, Roisnel T, Jazzar R, Melaimi M, Bertrand G, Mauduit M. PMID: 38450432.
      View in: PubMed   Mentions: 1     Fields:    
    8. Ambiphilicity of ring-expanded N-heterocyclic carbenes. Chem Sci. 2024 Mar 06; 15(10):3707-3710. Vermersch F, Wang VT, Abdellaoui M, Jazzar R, Bertrand G. PMID: 38455021; PMCID: PMC10915854.
      View in: PubMed   Mentions: 2  
    9. 1H-1,2,3-Triazol-5-ylidenes as Catalytic Organic Single-Electron Reductants. J Am Chem Soc. 2024 Feb 07; 146(5):2933-2938. Abdellaoui M, Oppel K, Vianna A, Soleilhavoup M, Yan X, Melaimi M, Bertrand G. PMID: 38253007.
      View in: PubMed   Mentions: 1     Fields:    
    10. A crystalline doubly oxidized carbene. Nature. 2023 Nov; 623(7985):66-70. Loh YK, Melaimi M, Gembicky M, Munz D, Bertrand G. PMID: 37730995.
      View in: PubMed   Mentions: 4     Fields:    
    11. Enhancing Substrate-Metal Catalyst Affinity via Hydrogen Bonding: Pd(II)-Catalyzed β-C(sp3)-H Bromination of Free Carboxylic Acids. J Am Chem Soc. 2023 Aug 02; 145(30):16297-16304. Hu L, Meng G, Chen X, Yoon JS, Shan JR, Chekshin N, Strassfeld DA, Sheng T, Zhuang Z, Jazzar R, Bertrand G, Houk KN, Yu JQ. PMID: 37487009.
      View in: PubMed   Mentions: 5     Fields:    
    12. Circularly Polarized Luminescence from Cyclic (Alkyl)(Amino) Carbene Derived Propellers. Angew Chem Int Ed Engl. 2023 Aug 14; 62(33):e202305404. Lorkowski J, Bouetard D, Yorkgitis P, Gembicky M, Roisnel T, Vanthuyne N, Munz D, Favereau L, Bertrand G, Mauduit M, Jazzar R. PMID: 37221132.
      View in: PubMed   Mentions: 3     Fields:    
    13. Mesoionic Carbene-Catalyzed Formyl Alkylation of Aldehydes. Angew Chem Int Ed Engl. 2023 Jun 12; 62(24):e202303478. Liu C, Zhang Z, Zhao LL, Bertrand G, Yan X. PMID: 37070460.
      View in: PubMed   Mentions: 2     Fields:    
    14. Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). Chemistry. 2023 Jun 19; 29(34):e202300280. Haimerl M, Schwarzmaier C, Riesinger C, Timoshkin AY, Melaimi M, Bertrand G, Scheer M. PMID: 37015017.
      View in: PubMed   Mentions:    Fields:    
    15. How To Enhance the Efficiency of Breslow Intermediates for SET Catalysis. J Org Chem. 2023 Feb 17; 88(4):2535-2542. Mulks FF, Melaimi M, Yan X, Baik MH, Bertrand G. PMID: 36719963.
      View in: PubMed   Mentions: 2     Fields:    
    16. An Air-Stable "Masked" Bis(imino)carbene: A Carbon-Based Dual Ambiphile. J Am Chem Soc. 2023 Feb 01; 145(4):2064-2069. Loh YK, Melaimi M, Munz D, Bertrand G. PMID: 36649656.
      View in: PubMed   Mentions: 9     Fields:    
    17. An air-stable radical with a redox-chameleonic amide. Chem Commun (Camb). 2023 Jan 12; 59(5):595-598. Peltier JL, Serrato MR, Thery V, Pecaut J, Tomás-Mendivil E, Bertrand G, Jazzar R, Martin D. PMID: 36524847.
      View in: PubMed   Mentions: 1     Fields:    Translation:AnimalsCells
    18. Correction to " 'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes. J Am Chem Soc. 2023 Jan 18; 145(2):1470-1471. Schaab J, Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. PMID: 36576490.
      View in: PubMed   Mentions:    Fields:    
    19. Cyclic (amino)(barrelene)carbenes: an original family of CAACs through a novel synthetic pathway. Chem Commun (Camb). 2022 Jul 05; 58(54):7519-7521. Serrato MR, Melaimi M, Bertrand G. PMID: 35699417.
      View in: PubMed   Mentions: 2     Fields:    Translation:Cells
    20. (CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes. ACS Catal. 2022 Jun 17; 12(12):7243-7247. Gao Y, Kim N, Mendoza SD, Yazdani S, Faria-Vieira A, Liu M, Kendrick A, Grotjahn DB, Bertrand G, Jazzar R, Engle KM. PMID: 37143933; PMCID: PMC10153597.
      View in: PubMed   Mentions: 6  
    21. Cyclic (Alkyl)(amino)carbenes: Synthesis of Iminium Precursors and Structural Properties. J Org Chem. 2022 03 04; 87(5):3511-3518. Vermersch F, Oliveira L, Hunter J, Soleilhavoup M, Jazzar R, Bertrand G. PMID: 35133152.
      View in: PubMed   Mentions: 5     Fields:    
    22. Stable Singlet Carbenes as Organic Superbases. Angew Chem Int Ed Engl. 2021 Dec 20; 60(52):27253-27257. Vermersch F, Yazdani S, Junor GP, Grotjahn DB, Jazzar R, Bertrand G. PMID: 34729888.
      View in: PubMed   Mentions: 2     Fields:    
    23. Cyclic (Alkyl)(amino)carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes*. Angew Chem Int Ed Engl. 2021 09 01; 60(36):19871-19878. Gao Y, Yazdani S, Kendrick A, Junor GP, Kang T, Grotjahn DB, Bertrand G, Jazzar R, Engle KM. PMID: 34159696; PMCID: PMC8390441.
      View in: PubMed   Mentions: 12     Fields:    Translation:Cells
    24. Cyclic (Alkyl)(Amino)Carbene (CAAC) Gold(I) Complexes as Chemotherapeutic Agents. Chemistry. 2021 Feb 19; 27(11):3772-3778. Proetto MT, Alexander K, Melaimi M, Bertrand G, Gianneschi NC. PMID: 33090571.
      View in: PubMed   Mentions: 4     Fields:    Translation:HumansCells
    25. Optically Pure C1-Symmetric Cyclic(alkyl)(amino)carbene Ruthenium Complexes for Asymmetric Olefin Metathesis. J Am Chem Soc. 2020 11 25; 142(47):19895-19901. Morvan J, Vermersch F, Zhang Z, Falivene L, Vives T, Dorcet V, Roisnel T, Crévisy C, Cavallo L, Vanthuyne N, Bertrand G, Jazzar R, Mauduit M. PMID: 33185429.
      View in: PubMed   Mentions: 5     Fields:    
    26. Realizing Metal-Free Carbene-Catalyzed Carbonylation Reactions with CO. J Am Chem Soc. 2020 10 28; 142(43):18336-18340. Peltier JL, Tomás-Mendivil E, Tolentino DR, Hansmann MM, Jazzar R, Bertrand G. PMID: 33054191.
      View in: PubMed   Mentions: 2     Fields:    
    27. The Influence of C(sp3 )H-Selenium Interactions on the 77 Se NMR Quantification of the π-Accepting Properties of Carbenes. Angew Chem Int Ed Engl. 2020 Dec 01; 59(49):22028-22033. Junor GP, Lorkowski J, Weinstein CM, Jazzar R, Pietraszuk C, Bertrand G. PMID: 32822513.
      View in: PubMed   Mentions: 20     Fields:    
    28. Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. J Am Chem Soc. 2020 Sep 23; 142(38):16479-16485. Peltier JL, Soleilhavoup M, Martin D, Jazzar R, Bertrand G. PMID: 32872772.
      View in: PubMed   Mentions: 5     Fields:    
    29. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications. Chem Rev. 2020 05 13; 120(9):4141-4168. Jazzar R, Soleilhavoup M, Bertrand G. PMID: 32239922.
      View in: PubMed   Mentions: 43     Fields:    
    30. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 25; 49(8):2426-2430. Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. PMID: 32048665.
      View in: PubMed   Mentions: 5     Fields:    
    31. Stable abnormal N-heterocyclic carbenes and their applications. Chem Soc Rev. 2020 Feb 21; 49(4):1233-1252. Sau SC, Hota PK, Mandal SK, Soleilhavoup M, Bertrand G. PMID: 31998907.
      View in: PubMed   Mentions: 32     Fields:    
    32. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 10 23; 141(42):16726-16733. Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. PMID: 31565934.
      View in: PubMed   Mentions: 4     Fields:    
    33. The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis. Chem Sci. 2019 Sep 07; 10(33):7807-7811. Pichon D, Soleilhavoup M, Morvan J, Junor GP, Vives T, Crévisy C, Lavallo V, Campagne JM, Mauduit M, Jazzar R, Bertrand G. PMID: 31588330; PMCID: PMC6761915.
      View in: PubMed   Mentions: 7  
    34. Reductive Elimination at Carbon under Steric Control. J Am Chem Soc. 2019 Jun 26; 141(25):9823-9826. Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. PMID: 31180660.
      View in: PubMed   Mentions: 12     Fields:    
    35. Correction to " 'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes". J Am Chem Soc. 2019 Jun 26; 141(25):10118. Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. PMID: 31199623.
      View in: PubMed   Mentions: 1     Fields:    
    36. "Quick-Silver" from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes. J Am Chem Soc. 2019 May 29; 141(21):8616-8626. Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. PMID: 31062972.
      View in: PubMed   Mentions: 37     Fields:    
    37. Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes. Inorg Chem. 2019 Mar 04; 58(5):3256-3264. Schiegerl LJ, Melaimi M, Tolentino DR, Klein W, Bertrand G, Fässler TF. PMID: 30741546.
      View in: PubMed   Mentions: 4     Fields:    
    38. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime. Science. 2019 02 08; 363(6427):601-606. Hamze R, Peltier JL, Sylvinson D, Jung M, Cardenas J, Haiges R, Soleilhavoup M, Jazzar R, Djurovich PI, Bertrand G, Thompson ME. PMID: 30733411.
      View in: PubMed   Mentions: 95     Fields:    
    39. Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. Angew Chem Int Ed Engl. 2019 Feb 25; 58(9):2875-2878. Junor GP, Romero EA, Chen X, Jazzar R, Bertrand G. PMID: 30618172.
      View in: PubMed   Mentions: 3     Fields:    
    40. What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis? J Am Chem Soc. 2019 01 16; 141(2):1109-1117. Regnier V, Romero EA, Molton F, Jazzar R, Bertrand G, Martin D. PMID: 30561990.
      View in: PubMed   Mentions: 24     Fields:    
    41. 1 H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes. Acc Chem Res. 2018 12 18; 51(12):3236-3244. Guisado-Barrios G, Soleilhavoup M, Bertrand G. PMID: 30417642.
      View in: PubMed   Mentions: 40     Fields:    
    42. A crystalline monosubstituted carbene. Nat Chem. 2018 12; 10(12):1196-1200. Nakano R, Jazzar R, Bertrand G. PMID: 30323332.
      View in: PubMed   Mentions: 8     Fields:    
    43. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 07 25; 140(29):9255-9260. Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G. PMID: 29954178.
      View in: PubMed   Mentions: 24     Fields:    
    44. Intercepting a Transient Phosphino-Arsinidene. Chemistry. 2018 Jul 05; 24(38):9514-9519. Hinz A, Hansmann MM, Bertrand G, Goicoechea JM. PMID: 29723432.
      View in: PubMed   Mentions: 5     Fields:    
    45. Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 21; 140(7):2546-2554. Hansmann MM, Melaimi M, Munz D, Bertrand G. PMID: 29382199.
      View in: PubMed   Mentions: 19     Fields:    
    46. Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 14; 140(6):2206-2213. Hansmann MM, Melaimi M, Bertrand G. PMID: 29342351.
      View in: PubMed   Mentions: 16     Fields:    
    47. L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2018 01 02; 57(1):198-202. Li Z, Hou Y, Li Y, Hinz A, Harmer JR, Su CY, Bertrand G, Grützmacher H. PMID: 29106069.
      View in: PubMed   Mentions: 9     Fields:    
    48. Crystalline Monomeric Allenyl/Propargyl Radical. J Am Chem Soc. 2017 11 08; 139(44):15620-15623. Hansmann MM, Melaimi M, Bertrand G. PMID: 29046060.
      View in: PubMed   Mentions: 12     Fields:    
    49. Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(i) complexes. Chem Commun (Camb). 2017 Aug 08; 53(64):9008-9011. Hamze R, Jazzar R, Soleilhavoup M, Djurovich PI, Bertrand G, Thompson ME. PMID: 28745735.
      View in: PubMed   Mentions: 7     Fields:    
    50. Borylenes: An Emerging Class of Compounds. Angew Chem Int Ed Engl. 2017 08 21; 56(35):10282-10292. Soleilhavoup M, Bertrand G. PMID: 28577325.
      View in: PubMed   Mentions: 21     Fields:    
    51. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Angew Chem Int Ed Engl. 2017 08 14; 56(34):10046-10068. Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G. PMID: 28376253.
      View in: PubMed   Mentions: 106     Fields:    
    52. Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. J Am Chem Soc. 2017 06 14; 139(23):7753-7756. Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G. PMID: 28541687.
      View in: PubMed   Mentions: 13     Fields:    
    53. (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. Chem Sci. 2017 May 01; 8(5):3720-3725. Hansmann MM, Ruiz DA, Liu LL, Jazzar R, Bertrand G. PMID: 28580107; PMCID: PMC5437511.
      View in: PubMed   Mentions: 8  
    54. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. PMID: 28251762.
      View in: PubMed   Mentions: 4     Fields:    
    55. The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals. Chemistry. 2017 May 02; 23(25):6206-6212. Mahoney JK, Jazzar R, Royal G, Martin D, Bertrand G. PMID: 28105672.
      View in: PubMed   Mentions: 5     Fields:    
    56. Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation. J Am Chem Soc. 2016 12 14; 138(49):15873-15876. Kleinhans G, Hansmann MM, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. PMID: 27960301.
      View in: PubMed   Mentions: 15     Fields:    
    57. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. J Am Chem Soc. 2016 12 14; 138(49):15885-15888. Hansmann MM, Bertrand G. PMID: 27960331.
      View in: PubMed   Mentions: 31     Fields:    
    58. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angew Chem Int Ed Engl. 2016 10 04; 55(41):12886-90. Munz D, Chu J, Melaimi M, Bertrand G. PMID: 27628756.
      View in: PubMed   Mentions: 15     Fields:    
    59. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chem Commun (Camb). 2016 Aug 18; 52(69):10563-5. Romero EA, Peltier JL, Jazzar R, Bertrand G. PMID: 27498971.
      View in: PubMed   Mentions: 13     Fields:    
    60. Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. Chem Sci. 2017 Jan 01; 8(1):165-168. Romero EA, Jazzar R, Bertrand G. PMID: 28451161; PMCID: PMC5308285.
      View in: PubMed   Mentions: 13  
    61. Singlet (Phosphino)phosphinidenes are Electrophilic. J Am Chem Soc. 2016 07 13; 138(27):8356-9. Hansmann MM, Jazzar R, Bertrand G. PMID: 27340902.
      View in: PubMed   Mentions: 28     Fields:    
    62. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. J Am Chem Soc. 2016 06 29; 138(25):7884-7. Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. PMID: 27304485.
      View in: PubMed   Mentions: 26     Fields:    
    63. Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. Chemistry. 2016 Jun 27; 22(27):9404-9. Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. PMID: 27238837.
      View in: PubMed   Mentions: 4     Fields:    
    64. N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. Angew Chem Int Ed Engl. 2016 05 10; 55(20):6018-22. Li Z, Chen X, Benko Z, Liu LL, Ruiz DA, Peltier JL, Bertrand G, Su CY, Grützmacher H. PMID: 27060924.
      View in: PubMed   Mentions: 12     Fields:    
    65. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angew Chem Int Ed Engl. 2016 04 25; 55(18):5536-40. Pranckevicius C, Liu LL, Bertrand G, Stephan DW. PMID: 27028936.
      View in: PubMed   Mentions: 11     Fields:    
    66. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chem Commun (Camb). 2016 Feb 14; 52(13):2733-5. Peltier JL, Jazzar R, Melaimi M, Bertrand G. PMID: 26757745.
      View in: PubMed   Mentions: 1     Fields:    
    67. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Adv Synth Catal. 2016 Mar 17; 358(6):965-969. Martin D, Marx VM, Grubbs RH, Bertrand G. PMID: 27594819; PMCID: PMC5007067.
      View in: PubMed   Mentions: 2  
    68. A rhodium(I)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chem Commun (Camb). 2016 Feb 28; 52(17):3504-7. Kleinhans G, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. PMID: 26838677.
      View in: PubMed   Mentions: 7     Fields:    
    69. Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chem Sci. 2016 Mar 01; 7(3):2335-2341. Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. PMID: 29997776; PMCID: PMC6003603.
      View in: PubMed   Mentions: 22  
    70. The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. J Am Chem Soc. 2015 Dec 23; 137(50):15696-8. Jin L, Romero EA, Melaimi M, Bertrand G. PMID: 26611196.
      View in: PubMed   Mentions: 7     Fields:    
    71. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes. Chem Sci. 2016 Jan 01; 7(1):150-154. Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. PMID: 28966767; PMCID: PMC5580305.
      View in: PubMed   Mentions: 6  
    72. Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals. Angew Chem Int Ed Engl. 2015 12 01; 54(49):14915-9. Rao B, Tang H, Zeng X, Liu LL, Melaimi M, Bertrand G. PMID: 26457345.
      View in: PubMed   Mentions: 17     Fields:    
    73. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chem Commun (Camb). 2015 Aug 18; 51(64):12732-12735. Liu LL, Ruiz DA, Dahcheh F, Bertrand G. PMID: 26166485.
      View in: PubMed   Mentions: 12     Fields:    Translation:Cells
    74. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Sci Adv. 2015 Jun; 1(5):e1500304. Jin L, Tolentino DR, Melaimi M, Bertrand G. PMID: 26601202; PMCID: PMC4640605.
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    75. Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2015 Jun 17; 137(23):7519-25. Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. PMID: 26011769.
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    76. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry. 2015 Jun 01; 21(23):8441-6. Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. PMID: 25925367.
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    77. A simple access to transition metal cyclopropenylidene complexes. Chem Commun (Camb). 2015 Mar 21; 51(23):4778-81. Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. PMID: 25621852.
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    78. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. Angew Chem Int Ed Engl. 2015 May 11; 54(20):6008-11. Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. PMID: 25802096.
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    79. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chem Asian J. 2015 Oct; 10(10):2139-42. Tolentino DR, Jin L, Melaimi M, Bertrand G. PMID: 25597889.
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    80. Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis. Angew Chem Int Ed Engl. 2015 Feb 02; 54(6):1919-23. Marx VM, Sullivan AH, Melaimi M, Virgil SC, Keitz BK, Weinberger DS, Bertrand G, Grubbs RH. PMID: 25522160; PMCID: PMC4713124.
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    81. Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Acc Chem Res. 2015 Feb 17; 48(2):256-66. Soleilhavoup M, Bertrand G. PMID: 25515548.
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    82. Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). J Am Chem Soc. 2014 Dec 10; 136(49):17123-35. Jerabek P, Roesky HW, Bertrand G, Frenking G. PMID: 25394669.
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    83. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry. 2015 Jan 02; 21(1):199-204. Dahcheh F, Stephan DW, Bertrand G. PMID: 25414006.
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    84. Reactivity of a stable phosphinonitrene towards small molecules. Chemistry. 2015 Jan 02; 21(1):191-8. Dielmann F, Bertrand G. PMID: 25395098.
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    85. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angew Chem Int Ed Engl. 2014 Nov 24; 53(48):13159-63. Dahcheh F, Martin D, Stephan DW, Bertrand G. PMID: 25267591.
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    86. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. J Am Chem Soc. 2014 Oct 01; 136(39):13594-7. Hu X, Martin D, Melaimi M, Bertrand G. PMID: 25222130.
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    87. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb). 2014 Jul 25; 50(58):7837-9. Ruiz DA, Melaimi M, Bertrand G. PMID: 24909943.
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    88. Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. Angew Chem Int Ed Engl. 2014 Aug 18; 53(34):9059-63. Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. PMID: 24985149.
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    89. One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl₃ adduct. Angew Chem Int Ed Engl. 2014 Jul 28; 53(31):8176-9. Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. PMID: 24961494.
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    90. Two-coordinate Fe⁰ and Co⁰ complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2014 Aug 04; 53(32):8427-31. Ung G, Rittle J, Soleilhavoup M, Bertrand G, Peters JC. PMID: 24953342.
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    91. Cross-coupling reactions between stable carbenes. Angew Chem Int Ed Engl. 2014 06 16; 53(25):6550-3. Weinstein CM, Martin CD, Liu LL, Bertrand G. PMID: 24838590.
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    92. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc. 2014 Apr 30; 136(17):6235-8. Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. PMID: 24731250.
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    93. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. J Am Chem Soc. 2014 Apr 02; 136(13):5023-30. Martin D, Canac Y, Lavallo V, Bertrand G. PMID: 24634983.
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    94. Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc. 2014 Mar 12; 136(10):3800-2. Dielmann F, Andrada DM, Frenking G, Bertrand G. PMID: 24559041.
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    95. Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. Chem Commun (Camb). 2014 Mar 07; 50(19):2431-3. Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G. PMID: 24448261.
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    96. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2013 Dec 18; 135(50):18766-9. Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 24304381.
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    97. Experimental and computational studies of anti-Bredt amidinium salts. Chemistry. 2013 Oct 25; 19(44):14895-901. Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. PMID: 24105742.
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    98. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). J Am Chem Soc. 2013 Sep 25; 135(38):14071-3. Dielmann F, Moore CE, Rheingold AL, Bertrand G. PMID: 24007472.
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    99. β- and α-Hydride abstraction in Gold(I) alkyl complexes. Angew Chem Int Ed Engl. 2013 Oct 18; 52(43):11388-91. Ung G, Bertrand G. PMID: 24027200.
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    100. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chem Asian J. 2013 Dec; 8(12):2940-2. Ruiz DA, Melaimi M, Bertrand G. PMID: 23960023.
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    101. Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci. 2013 Aug 01; 4(8):3020-3030. Martin CD, Soleilhavoup M, Bertrand G. PMID: 23878717; PMCID: PMC3714118.
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    102. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8964-7. Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. PMID: 23861304.
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    103. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl. 2013 Jul 15; 52(29):7590-2. Ruiz DA, Ung G, Melaimi M, Bertrand G. PMID: 23765789; PMCID: PMC3712875.
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    104. An air-stable oxyallyl radical cation. Angew Chem Int Ed Engl. 2013 Jul 01; 52(27):7014-7. Martin D, Moore CE, Rheingold AL, Bertrand G. PMID: 23720417.
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    105. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb). 2013 May 18; 49(40):4486-8. Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. PMID: 23571800.
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    106. Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. Chem Commun (Camb). 2013 May 18; 49(40):4483-5. López-Gómez MJ, Martin D, Bertrand G. PMID: 23552965.
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    107. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the π-accepting properties of carbenes. Angew Chem Int Ed Engl. 2013 Mar 04; 52(10):2939-43. Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. PMID: 23364832.
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    108. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angew Chem Int Ed Engl. 2013 Jan 07; 52(2):758-61. Ung G, Soleilhavoup M, Bertrand G. PMID: 23169762; PMCID: PMC3712865.
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    109. Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes. Chemistry. 2012 Nov 12; 18(46):14627-31. Yan X, Bouffard J, Guisado-Barrios G, Donnadieu B, Bertrand G. PMID: 23042507.
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    110. A crystalline singlet phosphinonitrene: a nitrogen atom-transfer agent. Science. 2012 Sep 21; 337(6101):1526-8. Dielmann F, Back O, Henry-Ellinger M, Jerabek P, Frenking G, Bertrand G. PMID: 22997335.
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    111. C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions. Chemistry. 2012 Oct 08; 18(41):12955-7. Ung G, Bertrand G. PMID: 22961643.
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    112. Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). Chem Commun (Camb). 2012 Jul 18; 48(56):7088-90. Ung G, Mendoza-Espinosa D, Bertrand G. PMID: 22684100.
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    113. A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity. Angew Chem Int Ed Engl. 2012 Jun 18; 51(25):6172-5. Martin D, Lassauque N, Donnadieu B, Bertrand G. PMID: 22565863; PMCID: PMC3374898.
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    114. Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry. 2012 Apr 27; 18(18):5676-92. Celik MA, Sure R, Klein S, Kinjo R, Bertrand G, Frenking G. PMID: 22434609.
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    115. Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C≡C-S-C(S)NR2. Angew Chem Int Ed Engl. 2011 Oct 10; 50(42):9923-5. Ung G, Frey GD, Schoeller WW, Bertrand G. PMID: 23210141.
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    116. A Brief Survey of our Contribution to Stable Carbene Chemistry. Organometallics. 2011 Oct 24; 30(20):5304-5313. Martin D, Melaimi M, Soleilhavoup M, Bertrand G. PMID: 22707843; PMCID: PMC3374658.
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    117. Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. Chem Commun (Camb). 2011 Oct 14; 47(38):10614-6. Mendoza-Espinosa D, Ung G, Donnadieu B, Bertrand G. PMID: 21879048; PMCID: PMC3371234.
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    118. Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene. J Organomet Chem. 2011 Aug 15; 696(17):2899-2903. Dehope A, Donnadieu B, Bertrand G. PMID: 21765542; PMCID: PMC3134370.
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    119. Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science. 2011 Jul 29; 333(6042):610-3. Kinjo R, Donnadieu B, Celik MA, Frenking G, Bertrand G. PMID: 21798945.
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    120. Stability and electronic properties of imidazole-based mesoionic carbenes. Chemistry. 2011 Jul 18; 17(30):8269-72. Ung G, Bertrand G. PMID: 21656597.
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    121. Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. J Am Chem Soc. 2011 Jun 08; 133(22):8498-501. Keitz BK, Bouffard J, Bertrand G, Grubbs RH. PMID: 21574621; PMCID: PMC3121189.
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    122. Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. Angew Chem Int Ed Engl. 2011 Jun 06; 50(24):5560-3. Kinjo R, Donnadieu B, Bertrand G. PMID: 21574224.
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    123. A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene. Angew Chem Int Ed Engl. 2011 Apr 26; 50(18):4215-8. Ung G, Mendoza-Espinosa D, Bouffard J, Bertrand G. PMID: 21472947; PMCID: PMC3121240.
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    124. Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics. 2011 Mar 09; 30(9):2617-2627. Bouffard J, Keitz BK, Tonner R, Lavallo V, Guisado-Barrios G, Frenking G, Grubbs RH, Bertrand G. PMID: 21572542; PMCID: PMC3092707.
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    125. Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts. Chem Asian J. 2011 Apr 04; 6(4):1099-103. Mendoza-Espinosa D, Donnadieu B, Bertrand G. PMID: 21322115; PMCID: PMC3118523.
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    126. Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. Angew Chem Int Ed Engl. 2011 Jan 03; 50(1):268-71. Lavallo V, El-Batta A, Bertrand G, Grubbs RH. PMID: 21110365; PMCID: PMC3057625.
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    127. Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). Organometallics. 2011; 30(21):6017-6021. Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. PMID: 22096269; PMCID: PMC3215102.
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    128. Stable singlet carbenes as mimics for transition metal centers. Chem Sci. 2011 Jan 01; 2(3):389-399. Martin D, Soleilhavoup M, Bertrand G. PMID: 21743834; PMCID: PMC3129870.
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    129. A persistent (amino)(ferrocenyl)carbene(). New J Chem. 2011 Jan 01; 35(10):2037-2042. Dehope A, Mendoza-Espinosa D, Donnadieu B, Bertrand G. PMID: 22707878; PMCID: PMC3374656.
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    130. Activation of Si-H, B-H, and P-H bonds at a single nonmetal center. Angew Chem Int Ed Engl. 2010 Dec 03; 49(49):9444-7. Frey GD, Masuda JD, Donnadieu B, Bertrand G. PMID: 21031393.
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    131. Stable cyclic carbenes and related species beyond diaminocarbenes. Angew Chem Int Ed Engl. 2010 Nov 15; 49(47):8810-49. Melaimi M, Soleilhavoup M, Bertrand G. PMID: 20836099; PMCID: PMC3130005.
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    132. Synthesis of a room-temperature-stable dimeric copper(I) hydride. Chem Asian J. 2011 Feb 01; 6(2):402-5. Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 20945453; PMCID: PMC3117327.
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    133. Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). Angew Chem Int Ed Engl. 2010 Aug 09; 49(34):5930-3. Kinjo R, Donnadieu B, Bertrand G. PMID: 20632430.
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    134. A crystalline phosphinyl radical cation. J Am Chem Soc. 2010 Aug 04; 132(30):10262-3. Back O, Celik MA, Frenking G, Melaimi M, Donnadieu B, Bertrand G. PMID: 20662507.
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    135. Introduction to main group chemistry. Chem Rev. 2010 Jul 14; 110(7):3851. Bertrand G. PMID: 20672857.
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    136. Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). Angew Chem Int Ed Engl. 2010 Jun 28; 49(28):4759-62. Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. PMID: 20509134; PMCID: PMC3131155.
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    137. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. J Am Chem Soc. 2010 Jun 02; 132(21):7264-5. Mendoza-Espinosa D, Donnadieu B, Bertrand G. PMID: 20443633; PMCID: PMC3134311.
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    138. Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nat Chem. 2010 May; 2(5):369-73. Back O, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. PMID: 20414236.
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    139. Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. Angew Chem Int Ed Engl. 2010; 49(5):942-5. Zeng X, Kinjo R, Donnadieu B, Bertrand G. PMID: 20058283; PMCID: PMC2871156.
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    140. Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts. Chem Asian J. 2009 Nov 02; 4(11):1745-50. Kuchenbeiser G, Soleilhavoup M, Donnadieu B, Bertrand G. PMID: 19780080; PMCID: PMC2869243.
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    141. Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science. 2009 Oct 23; 326(5952):556-9. Aldeco-Perez E, Rosenthal AJ, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. PMID: 19900893; PMCID: PMC2871154.
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    142. Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids. J Am Chem Soc. 2009 Sep 30; 131(38):13681-9. Fuks G, Saffon N, Maron L, Bertrand G, Bourissou D. PMID: 19772363.
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    143. Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. J Am Chem Soc. 2009 Aug 26; 131(33):11875-81. Fernández I, Dyker CA, DeHope A, Donnadieu B, Frenking G, Bertrand G. PMID: 19645451.
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    144. Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. Org Lett. 2009 Aug 06; 11(15):3166-9. Zeng X, Soleilhavoup M, Bertrand G. PMID: 19719176; PMCID: PMC2739117.
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    145. Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes. Chem Asian J. 2009 Aug 03; 4(8):1225-8. Tran HN, Donnadieu B, Bertrand G, Mathey F. PMID: 19557786.
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    146. Carbenes introduction. Chem Rev. 2009 Aug; 109(8):3209-10. Arduengo AJ, Bertrand G. PMID: 19642638.
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    147. Chemical bonding: Rethinking carbon. Nat Chem. 2009 Jul; 1(4):265-6. Dyker CA, Bertrand G. PMID: 21378867.
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    148. Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. J Am Chem Soc. 2009 Jun 24; 131(24):8690-6. Zeng X, Frey GD, Kinjo R, Donnadieu B, Bertrand G. PMID: 19456108; PMCID: PMC2724870.
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    149. Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. Angew Chem Int Ed Engl. 2009; 48(26):4792-5. Melaimi M, Parameswaran P, Donnadieu B, Frenking G, Bertrand G. PMID: 19472243.
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    150. Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions. Angew Chem Int Ed Engl. 2009; 48(26):4796-9. Asay M, Donnadieu B, Schoeller WW, Bertrand G. PMID: 19472245.
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    151. Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angew Chem Int Ed Engl. 2009; 48(30):5530-3. Back O, Kuchenbeiser G, Donnadieu B, Bertrand G. PMID: 19544519.
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    152. Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family. Angew Chem Int Ed Engl. 2009; 48(3):517-20. Kinjo R, Ishida Y, Donnadieu B, Bertrand G. PMID: 19072812.
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    153. A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine. Chemistry. 2009; 15(13):3056-60. Zeng X, Frey GD, Kousar S, Bertrand G. PMID: 19219866; PMCID: PMC2790055.
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    154. Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines. Inorg Chem. 2008 Nov 03; 47(21):9751-3. Giziroglu E, Donnadieu B, Bertrand G. PMID: 18841958.
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    155. A persistent P,N-heterocyclic carbene. Chem Commun (Camb). 2008 Oct 21; (39):4711-3. Frey GD, Song M, Bourg JB, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 18830468; PMCID: PMC2696270.
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    156. Rearrangement of biaryl monoaminocarbenes via concerted asynchronous insertion into aromatic C-H bonds. Org Lett. 2008 Oct 02; 10(19):4299-302. Vignolle J, Asay M, Miqueu K, Bourissou D, Bertrand G. PMID: 18763790; PMCID: PMC2601701.
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    157. Chemistry. Soluble allotropes of main-group elements. Science. 2008 Aug 22; 321(5892):1050-1. Dyker CA, Bertrand G. PMID: 18719272.
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    158. 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker. Dalton Trans. 2008 Sep 07; (33):4482-7. Rodriguez A, Fuks G, Bourg JB, Bourissou D, Tham FS, Bertrand G. PMID: 18698452.
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    159. Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes. Inorg Chem. 2008 May 19; 47(10):3949-51. Asay M, Donnadieu B, Baceiredo A, Soleilhavoup M, Bertrand G. PMID: 18422308; PMCID: PMC2574712.
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    160. Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. J Organomet Chem. 2008 Apr; 693(8-9):1674-1682. Frey GD, Dewhurst RD, Kousar S, Donnadieu B, Bertrand G. PMID: 19343084; PMCID: PMC2394856.
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    161. Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes. J Organomet Chem. 2008 Mar 01; 693(5):899-904. Kuchenbeiser G, Donnadieu B, Bertrand G. PMID: 19255609; PMCID: PMC2405893.
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    162. Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. Organometallics. 2008 Jan 12; 27(4):563-566. Anderson DR, Ung T, Mkrtumyan G, Bertrand G, Grubbs RH, Schrodi Y. PMID: 18584055; PMCID: PMC2440574.
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    163. Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane. Angew Chem Int Ed Engl. 2008; 47(39):7530-3. Asay M, Kato T, Saffon-Merceron N, Cossío FP, Baceiredo A, Bertrand G. PMID: 18704912.
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    164. The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus. Angew Chem Int Ed Engl. 2008; 47(1):155-9. Gandon V, Bourg JB, Tham FS, Schoeller WW, Bertrand G. PMID: 18022990.
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    165. Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes. Angew Chem Int Ed Engl. 2008; 47(12):2271-4. Vignolle J, Gornitzka H, Donnadieu B, Bourissou D, Bertrand G. PMID: 18273845; PMCID: PMC2440682.
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    166. Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. Angew Chem Int Ed Engl. 2008; 47(17):3206-9. Dyker CA, Lavallo V, Donnadieu B, Bertrand G. PMID: 18311741.
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    167. Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. Angew Chem Int Ed Engl. 2008; 47(29):5411-4. Lavallo V, Dyker CA, Donnadieu B, Bertrand G. PMID: 18551494.
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    168. Tuning the nucleophilicity in cyclopropenylidenes. Chemistry. 2008; 14(15):4711-8. Schoeller WW, Frey GD, Bertrand G. PMID: 18404754; PMCID: PMC2409117.
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    169. Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. Angew Chem Int Ed Engl. 2008; 47(28):5224-8. Lavallo V, Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 18528830; PMCID: PMC2529152.
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    170. NHC-mediated aggregation of P4: isolation of a P12 cluster. J Am Chem Soc. 2007 Nov 21; 129(46):14180-1. Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. PMID: 17973395.
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    171. Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. Proc Natl Acad Sci U S A. 2007 Aug 21; 104(34):13569-73. Lavallo V, Frey GD, Kousar S, Donnadieu B, Bertrand G. PMID: 17698808; PMCID: PMC1959421.
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    172. Synthesis of phosphaformamidines and phosphaformamidinates. Chem Asian J. 2007 Jul 02; 2(7):904-8. Song M, Donnadieu B, Soleilhavoup M, Bertrand G. PMID: 17551916; PMCID: PMC2405896.
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    173. Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. Science. 2007 Apr 20; 316(5823):439-41. Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. PMID: 17446400.
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    174. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. J Org Chem. 2007 Apr 27; 72(9):3492-9. Jazzar R, Bourg JB, Dewhurst RD, Donnadieu B, Bertrand G. PMID: 17408289; PMCID: PMC2440693.
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    175. Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation). J Am Chem Soc. 2007 Jan 31; 129(4):978-85. Vignolle J, Gornitzka H, Maron L, Schoeller WW, Bourissou D, Bertrand G. PMID: 17243835; PMCID: PMC2430930.
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    176. Stable P-heterocyclic carbenes: scope and limitations. Chem Asian J. 2007 Jan 08; 2(1):178-87. Masuda JD, Martin D, Lyon-Saunier C, Baceiredo A, Gornitzka H, Donnadieu B, Bertrand G. PMID: 17441152; PMCID: PMC2427278.
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    177. Carbene activation of P4 and subsequent derivatization. Angew Chem Int Ed Engl. 2007; 46(37):7052-5. Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. PMID: 17705209.
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    178. Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2. Angew Chem Int Ed Engl. 2007; 46(47):9078-80. Pascual S, Asay M, Illa O, Kato T, Bertrand G, Saffon-Merceron N, Branchadell V, Baceiredo A. PMID: 17960549.
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    179. An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene. Tetrahedron Lett. 2007; 48(4):685-687. Vignolle J, Donnadieu B, Bourissou D, Bertrand G. PMID: 19513183; PMCID: PMC2692173.
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    180. Recently reported crystalline isothiazole carbenes: myth or reality. Angew Chem Int Ed Engl. 2007; 46(36):6922-5; discussion 6926. DeHope A, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. PMID: 17661300.
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    181. Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls. Angew Chem Int Ed Engl. 2007; 46(30):5741-5. Bourg JB, Rodriguez A, Scheschkewitz D, Gornitzka H, Bourissou D, Bertrand G. PMID: 17592605.
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    182. Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2007; 46(38):7262-5. Anderson DR, Lavallo V, O'Leary DJ, Bertrand G, Grubbs RH. PMID: 17623287; PMCID: PMC2409061.
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    183. Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Angew Chem Int Ed Engl. 2007; 46(16):2899-902. Jazzar R, Dewhurst RD, Bourg JB, Donnadieu B, Canac Y, Bertrand G. PMID: 17352445; PMCID: PMC2440680.
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    184. A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane. Eur J Inorg Chem. 2006 Dec 01; 2006(24):5076-5080. Canac Y, Aniol GE, Conejero S, Donnadieu B, Bertrand G. PMID: 19763185; PMCID: PMC2745179.
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    186. Synthesis of extended polyphosphacumulenes. Chemistry. 2006 Nov 15; 12(33):8444-50. Martin D, Tham FS, Baceiredo A, Bertrand G. PMID: 17009365.
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    187. Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. Angew Chem Int Ed Engl. 2006 Oct 13; 45(40):6652-5. Lavallo V, Ishida Y, Donnadieu B, Bertrand G. PMID: 16986195; PMCID: PMC2562330.
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    188. Stable four-pi-electron, four-membered heterocyclic cations and carbenes. Proc Natl Acad Sci U S A. 2006 Sep 12; 103(37):13585-8. Ishida Y, Donnadieu B, Bertrand G. PMID: 16950877; PMCID: PMC1564229.
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    189. New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. Chem Asian J. 2006 Jul 17; 1(1-2):155-60. Conejero S, Song M, Martin D, Canac Y, Soleilhavoup M, Bertrand G. PMID: 17441050; PMCID: PMC2427273.
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    190. CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. Angew Chem Int Ed Engl. 2006 May 19; 45(21):3488-91. Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. PMID: 16637087; PMCID: PMC2440683.
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    191. Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory. Science. 2006 May 05; 312(5774):722-4. Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. PMID: 16614171; PMCID: PMC2427275.
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    192. Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. J Am Chem Soc. 2006 Jan 18; 128(2):459-64. Canac Y, Conejero S, Soleilhavoup M, Donnadieu B, Bertrand G. PMID: 16402832; PMCID: PMC2440685.
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    193. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. J Organomet Chem. 2006; 691(14):3201-3205. Jazzar R, Liang H, Donnadieu B, Bertrand G. PMID: 19543436; PMCID: PMC2699275.
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    194. Toward phenanthridin-2-ylidene: electrophilicity versus acidity in planar-constrained C-aryl iminium salts. Tetrahedron Lett. 2006; 47(4):531-534. Cattoën X, Bourissou D, Bertrand G. PMID: 18776944; PMCID: PMC2529453.
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    195. A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. Angew Chem Int Ed Engl. 2005 Nov 11; 44(44):7236-9. Lavallo V, Canac Y, DeHope A, Donnadieu B, Bertrand G. PMID: 16229037; PMCID: PMC2427277.
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    196. Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. Angew Chem Int Ed Engl. 2005 Sep 05; 44(35):5705-9. Lavallo V, Canac Y, Präsang C, Donnadieu B, Bertrand G. PMID: 16059961; PMCID: PMC2427276.
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    197. Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds. Angew Chem Int Ed Engl. 2005 Aug 26; 44(34):5497-500. Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. PMID: 16052642.
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    198. Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. J Am Chem Soc. 2005 Jul 27; 127(29):10182-3. Präsang C, Donnadieu B, Bertrand G. PMID: 16028925; PMCID: PMC2440681.
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    199. Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. J Org Chem. 2005 Jul 08; 70(14):5671-7. Martin D, Illa O, Baceiredo A, Bertrand G, Ortuño RM, Branchadell V. PMID: 15989352.
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    200. Persistent (amino)(silyl)carbenes. J Am Chem Soc. 2005 May 25; 127(20):7312-3. Canac Y, Conejero S, Donnadieu B, Schoeller WW, Bertrand G. PMID: 15898770.
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    201. Evidence for radical fragmentations from persistent singlet carbenes. J Am Chem Soc. 2005 Mar 16; 127(10):3292-3. Cattoën X, Miqueu K, Gornitzka H, Bourissou D, Bertrand G. PMID: 15755142.
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    202. A stable P-heterocyclic carbene. Angew Chem Int Ed Engl. 2005 Mar 04; 44(11):1700-3. Martin D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G. PMID: 15712311.
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    203. A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity. J Organomet Chem. 2005; 690(24-25):5541-5545. Teuma E, Lyon-Saunier C, Gornitzka H, Mignani G, Baceiredo A, Bertrand G. PMID: 19543437; PMCID: PMC2699277.
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    204. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. Inorg Chem. 2004 Oct 18; 43(21):6546-8. Dumitrescu A, Rudzevich VL, Romanenko VD, Mari A, Schoeller WW, Bourissou D, Bertrand G. PMID: 15476350.
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    205. Evidence for the coexistence of two bond-stretch isomers in solution. Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4880-3. Rodriguez A, Olsen RA, Ghaderi N, Scheschkewitz D, Tham FS, Mueller LJ, Bertrand G. PMID: 15372558.
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    206. Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid). Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4876-80. Rodriguez A, Tham FS, Schoeller WW, Bertrand G. PMID: 15372559.
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    207. Chemistry. The modest undressing of a silicon center. Science. 2004 Aug 06; 305(5685):783-5. Bertrand G. PMID: 15297652.
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    208. Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. Angew Chem Int Ed Engl. 2004 Aug 06; 43(31):4089-93. Conejero S, Canac Y, Tham FS, Bertrand G. PMID: 15300703.
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    209. Synthesis, reactivity, and ligand properties of a stable alkyl carbene. J Am Chem Soc. 2004 Jul 21; 126(28):8670-1. Lavallo V, Mafhouz J, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. PMID: 15250717.
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    210. Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. Chemistry. 2004 Apr 19; 10(8):1982-6. Krysiak J, Lyon C, Baceiredo A, Gornitzka H, Mikolajczyk M, Bertrand G. PMID: 15079838.
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    211. Amino-aryl-carbenes: alternative ligands for transition metals? J Am Chem Soc. 2004 Feb 11; 126(5):1342-3. Cattoën X, Gornitzka H, Bourissou D, Bertrand G. PMID: 14759183.
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    212. Radical-type reactivity of the 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyl. J Am Chem Soc. 2004 Feb 11; 126(5):1344-5. Amii H, Vranicar L, Gornitzka H, Bourissou D, Bertrand G. PMID: 14759184.
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    213. Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. J Am Chem Soc. 2004 Feb 04; 126(4):1016-7. Otto M, Conejero S, Canac Y, Romanenko VD, Rudzevitch V, Bertrand G. PMID: 14746458.
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    214. Sigma-bond stretching: a static approach for a dynamic process. Angew Chem Int Ed Engl. 2004 Feb 01; 43(5):585-7. Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. PMID: 14743410.
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    215. Theoretical study of rhodium(I) carbene complexes: the structural versatility of phosphino- compared with aminocarbenes. Chemistry. 2003 Dec 05; 9(23):5858-64. Miqueu K, Despagnet-Ayoub E, Dyer PW, Bourissou D, Bertrand G. PMID: 14673857.
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    216. Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a nucleophilic stable carbene to aromatic aldehydes. J Org Chem. 2003 Oct 03; 68(20):7707-10. Illa O, Gornitzka H, Baceiredo A, Bertrand G, Branchadell V, Ortuño RM. PMID: 14510546.
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    217. Synthesis of carbenes through substitution reactions at a carbene center. Science. 2003 Aug 29; 301(5637):1223-5. Merceron-Saffon N, Baceiredo A, Gornitzka H, Bertrand G. PMID: 12947194.
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    218. nido-Five-vertex clusters: in and out of boron chemistry. Angew Chem Int Ed Engl. 2003 Aug 11; 42(31):3578-80. Canac Y, Bertrand G. PMID: 12916028.
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    219. On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As). Chemistry. 2003 Aug 04; 9(15):3611-7. Schoeller WW, Rozhenko A, Bourissou D, Bertrand G. PMID: 12898688.
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    220. Transient azomethine-ylides from a stable amino-carbene and an aldiminium salt. J Org Chem. 2003 Feb 07; 68(3):911-4. Cattoën X, Solé S, Pradel C, Gornitzka H, Miqueu K, Bourissou D, Bertrand G. PMID: 12558415.
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    221. (Phosphino)(aryl)carbenes: effect of aryl substituents on their stabilization mode. J Am Chem Soc. 2003 Jan 08; 125(1):124-30. Despagnet-Ayoub E, Solé S, Gornitzka H, Rozhenko AB, Schoeller WW, Bourissou D, Bertrand G. PMID: 12515513.
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    222. A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete. Chemistry. 2002 Dec 02; 8(23):5305-11. Amsallem D, Mazières S, Piquet-Fauré V, Gornitzka H, Baceiredo A, Bertrand G. PMID: 12432498.
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    224. C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents. Chem Commun (Camb). 2002 Oct 07; (19):2250-1. Merceron N, Baceiredo A, Gornitzka H, Bertrand G. PMID: 12398001.
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    226. The stable pentamethylcyclopentadienyl cation remains unknown. Angew Chem Int Ed Engl. 2002 Jul 02; 41(13):2275-6. Otto M, Scheschkewitz D, Kato T, Midland MM, Lambert JB, Bertrand G. PMID: 12203563.
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    228. The first "naked" primary phosphanide anion [ArPH](-). Angew Chem Int Ed Engl. 2002 Apr 02; 41(7):1193-5. Rudzevich VL, Gornitzka H, Miqueu K, Sotiropoulos JM, Pfister-Guillouzo G, Romanenko VD, Bertrand G. PMID: 12491256.
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    231. Stable Carbenes. Chem Rev. 2000 Jan 12; 100(1):39-92. Bourissou D, Guerret O, Gabbaï FP, Bertrand G. PMID: 11749234.
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    233. Synthetic Utility of Stable Phosphanylcarbenes: Synthesis and Crystal Structure of an α-(Lithiomethylene)phosphorane. Angew Chem Int Ed Engl. 1999 Mar 01; 38(5):678-680. Goumri-Magnet S, Gornitzka H, Baceiredo A, Bertrand G. PMID: 29711539.
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    234. The Azide-Nitrilimine Analogy in Aluminum Chemistry. Angew Chem Int Ed Engl. 1998 Apr 20; 37(7):989-992. Emig N, Gabbaï FP, Krautscheid H, Réau R, Bertrand G. PMID: 29711487.
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    235. Ylidic Four π Electron Four-Membered λ5 -Phosphorus Heterocycles: Electronical Isomers of Heterocyclobutadienes. Angew Chem Int Ed Engl. 1998 Feb 16; 37(3):270-281. Bertrand G. PMID: 29711272.
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    236. N-Phosphino- and N-Phosphonionitrilimines: From Nucleophilic to Electrophilic 1,3-Dipoles. J Org Chem. 1997 Jan 24; 62(2):292-296. Palacios F, Pagalday J, Piquet V, Dahan F, Baceiredo A, Bertrand G. PMID: 11671401.
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    237. X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2lambda(5)-Diazaphosphetes: A New Type of 4-pi-Electron 4-Membered Heterocycle. Inorg Chem. 1996 Apr 24; 35(9):2458-2462. Alcaraz G, Baceiredo A, Nieger M, Schoeller WW, Bertrand G. PMID: 11666457.
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    238. Synthesis of Stable Multifunctional C-Phosphonio Phosphorus Vinyl Ylides. Inorg Chem. 1996 Jan 03; 35(1):46-50. Dyer P, Baceiredo A, Bertrand G. PMID: 11666162.
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    239. A cholesterol-isopropanol gel. Nature. 1977 Sep 29; 269(5627):450. Acree WE, Bertrand GL. PMID: 909595.
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