 Guy Bertrand
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| Title(s) | Professor, Chemistry And Biochemistry |
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| School | Academic Aff |
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| Phone | 858-534-5412 |
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| vCard | Download vCard |
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 Bibliographic
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Mantanona AJ, Tolentino DR, Cay KS, Gembicky M, Jazzar R, Bertrand G, Rinehart JD. Tuning electronic structure through halide modulation of mesoionic carbene cobalt complexes. Dalton Trans. 2020 Feb 12. PMID: 32048665.
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Sau SC, Hota PK, Mandal SK, Soleilhavoup M, Bertrand G. Stable abnormal N-heterocyclic carbenes and their applications. Chem Soc Rev. 2020 Jan 30. PMID: 31998907.
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Romero EA, Chen G, Gembicky M, Jazzar R, Yu JQ, Bertrand G. Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline Ligands in Palladium-Catalyzed ß-C(sp3)-H Bond Arylation Reactions. J Am Chem Soc. 2019 Oct 23; 141(42):16726-16733. PMID: 31565934.
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Pichon D, Soleilhavoup M, Morvan J, Junor GP, Vives T, Crévisy C, Lavallo V, Campagne JM, Mauduit M, Jazzar R, Bertrand G. The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis. Chem Sci. 2019 Sep 07; 10(33):7807-7811. PMID: 31588330.
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Tolentino DR, Neale SE, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, Bertrand G. Reductive Elimination at Carbon under Steric Control. J Am Chem Soc. 2019 Jun 26; 141(25):9823-9826. PMID: 31180660.
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Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. Correction to "?'Quick-Silver' from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes". J Am Chem Soc. 2019 Jun 26; 141(25):10118. PMID: 31199623.
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Hamze R, Shi S, Kapper SC, Muthiah Ravinson DS, Estergreen L, Jung MC, Tadle AC, Haiges R, Djurovich PI, Peltier JL, Jazzar R, Bertrand G, Bradforth SE, Thompson ME. "Quick-Silver" from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes. J Am Chem Soc. 2019 May 29; 141(21):8616-8626. PMID: 31062972.
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Schiegerl LJ, Melaimi M, Tolentino DR, Klein W, Bertrand G, Fässler TF. Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes. Inorg Chem. 2019 Mar 04; 58(5):3256-3264. PMID: 30741546.
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Hamze R, Peltier JL, Sylvinson D, Jung M, Cardenas J, Haiges R, Soleilhavoup M, Jazzar R, Djurovich PI, Bertrand G, Thompson ME. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime. Science. 2019 02 08; 363(6427):601-606. PMID: 30733411.
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Junor GP, Romero EA, Chen X, Jazzar R, Bertrand G. Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis. Angew Chem Int Ed Engl. 2019 Feb 25; 58(9):2875-2878. PMID: 30618172.
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Regnier V, Romero EA, Molton F, Jazzar R, Bertrand G, Martin D. What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis? J Am Chem Soc. 2019 Jan 16; 141(2):1109-1117. PMID: 30561990.
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Guisado-Barrios G, Soleilhavoup M, Bertrand G. 1 H-1,2,3-Triazol-5-ylidenes: Readily Available Mesoionic Carbenes. Acc Chem Res. 2018 12 18; 51(12):3236-3244. PMID: 30417642.
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Nakano R, Jazzar R, Bertrand G. A crystalline monosubstituted carbene. Nat Chem. 2018 12; 10(12):1196-1200. PMID: 30323332.
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Weinstein CM, Junor GP, Tolentino DR, Jazzar R, Melaimi M, Bertrand G. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 07 25; 140(29):9255-9260. PMID: 29954178.
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Hinz A, Hansmann MM, Bertrand G, Goicoechea JM. Intercepting a Transient Phosphino-Arsinidene. Chemistry. 2018 Jul 05; 24(38):9514-9519. PMID: 29723432.
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Hansmann MM, Melaimi M, Munz D, Bertrand G. Modular Approach to Kekulé Diradicaloids Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 21; 140(7):2546-2554. PMID: 29382199.
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Hansmann MM, Melaimi M, Bertrand G. Organic Mixed Valence Compounds Derived from Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2018 02 14; 140(6):2206-2213. PMID: 29342351.
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Li Z, Hou Y, Li Y, Hinz A, Harmer JR, Su CY, Bertrand G, Grützmacher H. L3 C3 P3 : Tricarbontriphosphide Tricyclic Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2018 01 02; 57(1):198-202. PMID: 29106069.
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Hansmann MM, Melaimi M, Bertrand G. Crystalline Monomeric Allenyl/Propargyl Radical. J Am Chem Soc. 2017 11 08; 139(44):15620-15623. PMID: 29046060.
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Hamze R, Jazzar R, Soleilhavoup M, Djurovich PI, Bertrand G, Thompson ME. Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu(i) complexes. Chem Commun (Camb). 2017 Aug 08; 53(64):9008-9011. PMID: 28745735.
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Soleilhavoup M, Bertrand G. Borylenes: An Emerging Class of Compounds. Angew Chem Int Ed Engl. 2017 08 21; 56(35):10282-10292. PMID: 28577325.
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Melaimi M, Jazzar R, Soleilhavoup M, Bertrand G. Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments. Angew Chem Int Ed Engl. 2017 08 14; 56(34):10046-10068. PMID: 28376253.
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Tomás-Mendivil E, Hansmann MM, Weinstein CM, Jazzar R, Melaimi M, Bertrand G. Bicyclic (Alkyl)(amino)carbenes (BICAACs): Stable Carbenes More Ambiphilic than CAACs. J Am Chem Soc. 2017 06 14; 139(23):7753-7756. PMID: 28541687.
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Hansmann MM, Ruiz DA, Liu LL, Jazzar R, Bertrand G. (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles. Chem Sci. 2017 May 01; 8(5):3720-3725. PMID: 28580107.
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Romero EA, Olsen PM, Jazzar R, Soleilhavoup M, Gembicky M, Bertrand G. Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride. Angew Chem Int Ed Engl. 2017 03 27; 56(14):4024-4027. PMID: 28251762.
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Mahoney JK, Jazzar R, Royal G, Martin D, Bertrand G. The Advantages of Cyclic Over Acyclic Carbenes To Access Isolable Capto-Dative C-Centered Radicals. Chemistry. 2017 May 02; 23(25):6206-6212. PMID: 28105672.
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Kleinhans G, Hansmann MM, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation. J Am Chem Soc. 2016 12 14; 138(49):15873-15876. PMID: 27960301.
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Hansmann MM, Bertrand G. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. J Am Chem Soc. 2016 12 14; 138(49):15885-15888. PMID: 27960331.
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Munz D, Chu J, Melaimi M, Bertrand G. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angew Chem Int Ed Engl. 2016 10 04; 55(41):12886-90. PMID: 27628756.
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Romero EA, Peltier JL, Jazzar R, Bertrand G. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chem Commun (Camb). 2016 Aug 18; 52(69):10563-5. PMID: 27498971.
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Romero EA, Jazzar R, Bertrand G. Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane. Chem Sci. 2017 Jan 01; 8(1):165-168. PMID: 28451161.
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Hansmann MM, Jazzar R, Bertrand G. Singlet (Phosphino)phosphinidenes are Electrophilic. J Am Chem Soc. 2016 07 13; 138(27):8356-9. PMID: 27340902.
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Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. J Am Chem Soc. 2016 06 29; 138(25):7884-7. PMID: 27304485.
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Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. Chemistry. 2016 Jun 27; 22(27):9404-9. PMID: 27238837.
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Li Z, Chen X, Benko Z, Liu L, Ruiz DA, Peltier JL, Bertrand G, Su CY, Grützmacher H. N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. Angew Chem Int Ed Engl. 2016 05 10; 55(20):6018-22. PMID: 27060924.
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Pranckevicius C, Liu L, Bertrand G, Stephan DW. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angew Chem Int Ed Engl. 2016 04 25; 55(18):5536-40. PMID: 27028936.
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Peltier JL, Jazzar R, Melaimi M, Bertrand G. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chem Commun (Camb). 2016 Feb 14; 52(13):2733-5. PMID: 26757745.
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Martin D, Marx VM, Grubbs RH, Bertrand G. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Adv Synth Catal. 2016 Mar 17; 358(6):965-969. PMID: 27594819.
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Kleinhans G, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. A rhodium(I)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chem Commun (Camb). 2016 Feb 28; 52(17):3504-7. PMID: 26838677.
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Liu L, Ruiz DA, Dahcheh F, Bertrand G, Suter R, Tondreau AM, Grützmacher H. Isolation of Au-, Co-?1PCO and Cu-?2PCO complexes, conversion of an Ir-?1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion. Chem Sci. 2016 Mar 01; 7(3):2335-2341. PMID: 29997776.
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Jin L, Romero EA, Melaimi M, Bertrand G. The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. J Am Chem Soc. 2015 Dec 23; 137(50):15696-8. PMID: 26611196.
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Jin L, Melaimi M, Kostenko A, Karni M, Apeloig Y, Moore CE, Rheingold AL, Bertrand G. Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes. Chem Sci. 2016 Jan 01; 7(1):150-154. PMID: 28966767.
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Rao B, Tang H, Zeng X, Liu L, Melaimi M, Bertrand G. Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong s-Donating and p-Accepting Ligands for Transition Metals. Angew Chem Int Ed Engl. 2015 Dec 01; 54(49):14915-9. PMID: 26457345.
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Liu L, Ruiz DA, Dahcheh F, Bertrand G. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chem Commun (Camb). 2015 Aug 18; 51(64):12732-5. PMID: 26166485.
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Jin L, Tolentino DR, Melaimi M, Bertrand G. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Sci Adv. 2015 Jun; 1(5):e1500304. PMID: 26601202.
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Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. Air-persistent monomeric (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2015 Jun 17; 137(23):7519-25. PMID: 26011769.
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Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry. 2015 Jun 01; 21(23):8441-6. PMID: 25925367.
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Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. A simple access to transition metal cyclopropenylidene complexes. Chem Commun (Camb). 2015 Mar 21; 51(23):4778-81. PMID: 25621852.
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Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3. Angew Chem Int Ed Engl. 2015 May 11; 54(20):6008-11. PMID: 25802096.
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Tolentino DR, Jin L, Melaimi M, Bertrand G. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chem Asian J. 2015 Oct; 10(10):2139-42. PMID: 25597889.
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Marx VM, Sullivan AH, Melaimi M, Virgil SC, Keitz BK, Weinberger DS, Bertrand G, Grubbs RH. Cyclic alkyl amino carbene (CAAC) ruthenium complexes as remarkably active catalysts for ethenolysis. Angew Chem Int Ed Engl. 2015 Feb 02; 54(6):1919-23. PMID: 25522160.
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Soleilhavoup M, Bertrand G. Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise. Acc Chem Res. 2015 Feb 17; 48(2):256-66. PMID: 25515548.
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Jerabek P, Roesky HW, Bertrand G, Frenking G. Coinage metals binding as main group elements: structure and bonding of the carbene complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). J Am Chem Soc. 2014 Dec 10; 136(49):17123-35. PMID: 25394669.
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Dahcheh F, Stephan DW, Bertrand G. Oxidative addition at a carbene center: synthesis of an iminoboryl-CAAC adduct. Chemistry. 2015 Jan 02; 21(1):199-204. PMID: 25414006.
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Dielmann F, Bertrand G. Reactivity of a stable phosphinonitrene towards small molecules. Chemistry. 2015 Jan 02; 21(1):191-8. PMID: 25395098.
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Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and reactivity of a CAAC-aminoborylene adduct: a hetero-allene or an organoboron isoelectronic with singlet carbenes. Angew Chem Int Ed Engl. 2014 Nov 24; 53(48):13159-63. PMID: 25267591.
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Hu X, Martin D, Melaimi M, Bertrand G. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. J Am Chem Soc. 2014 Oct 01; 136(39):13594-7. PMID: 25222130.
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Ruiz DA, Melaimi M, Bertrand G. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb). 2014 Jul 25; 50(58):7837-9. PMID: 24909943.
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Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. Trinuclear gold clusters supported by cyclic (alkyl)(amino)carbene ligands: mimics for gold heterogeneous catalysts. Angew Chem Int Ed Engl. 2014 Aug 18; 53(34):9059-63. PMID: 24985149.
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Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. One-, two-, and three-electron reduction of a cyclic alkyl(amino)carbene-SbCl3 adduct. Angew Chem Int Ed Engl. 2014 Jul 28; 53(31):8176-9. PMID: 24961494.
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Ung G, Rittle J, Soleilhavoup M, Bertrand G, Peters JC. Two-coordinate Fe° and Co° complexes supported by cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2014 Aug 04; 53(32):8427-31. PMID: 24953342.
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Weinstein CM, Martin CD, Liu L, Bertrand G. Cross-coupling reactions between stable carbenes. Angew Chem Int Ed Engl. 2014 Jun 16; 53(25):6550-3. PMID: 24838590.
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Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. J Am Chem Soc. 2014 Apr 30; 136(17):6235-8. PMID: 24731250.
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Martin D, Canac Y, Lavallo V, Bertrand G. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. J Am Chem Soc. 2014 Apr 02; 136(13):5023-30. PMID: 24634983.
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Dielmann F, Andrada DM, Frenking G, Bertrand G. Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc. 2014 Mar 12; 136(10):3800-2. PMID: 24559041.
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Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G. Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. Chem Commun (Camb). 2014 Mar 07; 50(19):2431-3. PMID: 24448261.
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Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2013 Dec 18; 135(50):18766-9. PMID: 24304381.
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Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. Experimental and computational studies of anti-Bredt amidinium salts. Chemistry. 2013 Oct 25; 19(44):14895-901. PMID: 24105742.
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Dielmann F, Moore CE, Rheingold AL, Bertrand G. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). J Am Chem Soc. 2013 Sep 25; 135(38):14071-3. PMID: 24007472.
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Ung G, Bertrand G. ß- and a-Hydride abstraction in Gold(I) alkyl complexes. Angew Chem Int Ed Engl. 2013 Oct 18; 52(43):11388-91. PMID: 24027200.
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Ruiz DA, Melaimi M, Bertrand G. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chem Asian J. 2013 Dec; 8(12):2940-2. PMID: 23960023.
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Martin CD, Soleilhavoup M, Bertrand G. Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci. 2013 Aug 01; 4(8):3020-3030. PMID: 23878717.
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Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8964-7. PMID: 23861304.
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Ruiz DA, Ung G, Melaimi M, Bertrand G. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl. 2013 Jul 15; 52(29):7590-2. PMID: 23765789.
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Martin D, Moore CE, Rheingold AL, Bertrand G. An air-stable oxyallyl radical cation. Angew Chem Int Ed Engl. 2013 Jul 01; 52(27):7014-7. PMID: 23720417.
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Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb). 2013 May 18; 49(40):4486-8. PMID: 23571800.
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López-Gómez MJ, Martin D, Bertrand G. Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. Chem Commun (Camb). 2013 May 18; 49(40):4483-5. PMID: 23552965.
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Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the p-accepting properties of carbenes. Angew Chem Int Ed Engl. 2013 Mar 04; 52(10):2939-43. PMID: 23364832.
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Ung G, Soleilhavoup M, Bertrand G. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angew Chem Int Ed Engl. 2013 Jan 07; 52(2):758-61. PMID: 23169762.
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Yan X, Bouffard J, Guisado-Barrios G, Donnadieu B, Bertrand G. Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes. Chemistry. 2012 Nov 12; 18(46):14627-31. PMID: 23042507.
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Dielmann F, Back O, Henry-Ellinger M, Jerabek P, Frenking G, Bertrand G. A crystalline singlet phosphinonitrene: a nitrogen atom-transfer agent. Science. 2012 Sep 21; 337(6101):1526-8. PMID: 22997335.
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Ung G, Bertrand G. C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions. Chemistry. 2012 Oct 08; 18(41):12955-7. PMID: 22961643.
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Ung G, Mendoza-Espinosa D, Bertrand G. Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). Chem Commun (Camb). 2012 Jul 18; 48(56):7088-90. PMID: 22684100.
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Martin D, Lassauque N, Donnadieu B, Bertrand G. A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity. Angew Chem Int Ed Engl. 2012 Jun 18; 51(25):6172-5. PMID: 22565863.
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Celik MA, Sure R, Klein S, Kinjo R, Bertrand G, Frenking G. Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry. 2012 Apr 27; 18(18):5676-92. PMID: 22434609.
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Ung G, Frey GD, Schoeller WW, Bertrand G. Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C=C-S-C(S)NR2. Angew Chem Int Ed Engl. 2011 Oct 10; 50(42):9923-5. PMID: 23210141.
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Martin D, Melaimi M, Soleilhavoup M, Bertrand G. A Brief Survey of our Contribution to Stable Carbene Chemistry. Organometallics. 2011 Oct 24; 30(20):5304-5313. PMID: 22707843.
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Mendoza-Espinosa D, Ung G, Donnadieu B, Bertrand G. Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. Chem Commun (Camb). 2011 Oct 14; 47(38):10614-6. PMID: 21879048.
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Dehope A, Donnadieu B, Bertrand G. Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene. J Organomet Chem. 2011 Aug 15; 696(17):2899-2903. PMID: 21765542.
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Kinjo R, Donnadieu B, Celik MA, Frenking G, Bertrand G. Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science. 2011 Jul 29; 333(6042):610-3. PMID: 21798945.
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Ung G, Bertrand G. Stability and electronic properties of imidazole-based mesoionic carbenes. Chemistry. 2011 Jul 18; 17(30):8269-72. PMID: 21656597.
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Keitz BK, Bouffard J, Bertrand G, Grubbs RH. Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. J Am Chem Soc. 2011 Jun 08; 133(22):8498-501. PMID: 21574621.
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Kinjo R, Donnadieu B, Bertrand G. Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. Angew Chem Int Ed Engl. 2011 Jun 06; 50(24):5560-3. PMID: 21574224.
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Ung G, Mendoza-Espinosa D, Bouffard J, Bertrand G. A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene. Angew Chem Int Ed Engl. 2011 Apr 26; 50(18):4215-8. PMID: 21472947.
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Bouffard J, Keitz BK, Tonner R, Lavallo V, Guisado-Barrios G, Frenking G, Grubbs RH, Bertrand G. Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics. 2011 Mar 09; 30(9):2617-2627. PMID: 21572542.
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Mendoza-Espinosa D, Donnadieu B, Bertrand G. Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts. Chem Asian J. 2011 Apr 04; 6(4):1099-103. PMID: 21322115.
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Lavallo V, El-Batta A, Bertrand G, Grubbs RH. Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. Angew Chem Int Ed Engl. 2011 Jan 03; 50(1):268-71. PMID: 21110365.
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Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). Organometallics. 2011; 30(21):6017-6021. PMID: 22096269.
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Martin D, Soleilhavoup M, Bertrand G. Stable singlet carbenes as mimics for transition metal centers. Chem Sci. 2011 Jan 01; 2(3):389-399. PMID: 21743834.
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Dehope A, Mendoza-Espinosa D, Donnadieu B, Bertrand G. A persistent (amino)(ferrocenyl)carbene(). New J Chem. 2011 Jan 01; 35(10):2037-2042. PMID: 22707878.
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Frey GD, Masuda JD, Donnadieu B, Bertrand G. Activation of Si-H, B-H, and P-H bonds at a single nonmetal center. Angew Chem Int Ed Engl. 2010 Dec 03; 49(49):9444-7. PMID: 21031393.
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Melaimi M, Soleilhavoup M, Bertrand G. Stable cyclic carbenes and related species beyond diaminocarbenes. Angew Chem Int Ed Engl. 2010 Nov 15; 49(47):8810-49. PMID: 20836099.
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Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. Synthesis of a room-temperature-stable dimeric copper(I) hydride. Chem Asian J. 2011 Feb 01; 6(2):402-5. PMID: 20945453.
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Kinjo R, Donnadieu B, Bertrand G. Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). Angew Chem Int Ed Engl. 2010 Aug 09; 49(34):5930-3. PMID: 20632430.
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Back O, Celik MA, Frenking G, Melaimi M, Donnadieu B, Bertrand G. A crystalline phosphinyl radical cation. J Am Chem Soc. 2010 Aug 04; 132(30):10262-3. PMID: 20662507.
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Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). Angew Chem Int Ed Engl. 2010 Jun 28; 49(28):4759-62. PMID: 20509134.
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Mendoza-Espinosa D, Donnadieu B, Bertrand G. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. J Am Chem Soc. 2010 Jun 02; 132(21):7264-5. PMID: 20443633.
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Back O, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nat Chem. 2010 May; 2(5):369-73. PMID: 20414236.
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Zeng X, Kinjo R, Donnadieu B, Bertrand G. Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. Angew Chem Int Ed Engl. 2010; 49(5):942-5. PMID: 20058283.
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Kuchenbeiser G, Soleilhavoup M, Donnadieu B, Bertrand G. Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts. Chem Asian J. 2009 Nov 02; 4(11):1745-50. PMID: 19780080.
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Aldeco-Perez E, Rosenthal AJ, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science. 2009 Oct 23; 326(5952):556-9. PMID: 19900893.
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Fuks G, Saffon N, Maron L, Bertrand G, Bourissou D. Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids. J Am Chem Soc. 2009 Sep 30; 131(38):13681-9. PMID: 19772363.
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Fernández I, Dyker CA, DeHope A, Donnadieu B, Frenking G, Bertrand G. Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. J Am Chem Soc. 2009 Aug 26; 131(33):11875-81. PMID: 19645451.
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Zeng X, Soleilhavoup M, Bertrand G. Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. Org Lett. 2009 Aug 06; 11(15):3166-9. PMID: 19719176.
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Tran HN, Donnadieu B, Bertrand G, Mathey F. Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes. Chem Asian J. 2009 Aug 03; 4(8):1225-8. PMID: 19557786.
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Dyker CA, Bertrand G. Chemical bonding: Rethinking carbon. Nat Chem. 2009 Jul; 1(4):265-6. PMID: 21378867.
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Zeng X, Frey GD, Kinjo R, Donnadieu B, Bertrand G. Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. J Am Chem Soc. 2009 Jun 24; 131(24):8690-6. PMID: 19456108.
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Melaimi M, Parameswaran P, Donnadieu B, Frenking G, Bertrand G. Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. Angew Chem Int Ed Engl. 2009; 48(26):4792-5. PMID: 19472243.
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Asay M, Donnadieu B, Schoeller WW, Bertrand G. Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions. Angew Chem Int Ed Engl. 2009; 48(26):4796-9. PMID: 19472245.
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Back O, Kuchenbeiser G, Donnadieu B, Bertrand G. Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angew Chem Int Ed Engl. 2009; 48(30):5530-3. PMID: 19544519.
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Kinjo R, Ishida Y, Donnadieu B, Bertrand G. Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family. Angew Chem Int Ed Engl. 2009; 48(3):517-20. PMID: 19072812.
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Zeng X, Frey GD, Kousar S, Bertrand G. A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine. Chemistry. 2009; 15(13):3056-60. PMID: 19219866.
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Giziroglu E, Donnadieu B, Bertrand G. Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines. Inorg Chem. 2008 Nov 03; 47(21):9751-3. PMID: 18841958.
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Frey GD, Song M, Bourg JB, Donnadieu B, Soleilhavoup M, Bertrand G. A persistent P,N-heterocyclic carbene. Chem Commun (Camb). 2008 Oct 21; (39):4711-3. PMID: 18830468.
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Dyker CA, Bertrand G. Chemistry. Soluble allotropes of main-group elements. Science. 2008 Aug 22; 321(5892):1050-1. PMID: 18719272.
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Rodriguez A, Fuks G, Bourg JB, Bourissou D, Tham FS, Bertrand G. 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker. Dalton Trans. 2008 Sep 07; (33):4482-7. PMID: 18698452.
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Asay M, Donnadieu B, Baceiredo A, Soleilhavoup M, Bertrand G. Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes. Inorg Chem. 2008 May 19; 47(10):3949-51. PMID: 18422308.
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Frey GD, Dewhurst RD, Kousar S, Donnadieu B, Bertrand G. Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. J Organomet Chem. 2008 Apr; 693(8-9):1674-1682. PMID: 19343084.
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Kuchenbeiser G, Donnadieu B, Bertrand G. Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes. J Organomet Chem. 2008 Mar 01; 693(5):899-904. PMID: 19255609.
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Anderson DR, Ung T, Mkrtumyan G, Bertrand G, Grubbs RH, Schrodi Y. Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. Organometallics. 2008 Jan 12; 27(4):563-566. PMID: 18584055.
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Asay M, Kato T, Saffon-Merceron N, Cossío FP, Baceiredo A, Bertrand G. Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane. Angew Chem Int Ed Engl. 2008; 47(39):7530-3. PMID: 18704912.
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Gandon V, Bourg JB, Tham FS, Schoeller WW, Bertrand G. The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus. Angew Chem Int Ed Engl. 2008; 47(1):155-9. PMID: 18022990.
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Vignolle J, Gornitzka H, Donnadieu B, Bourissou D, Bertrand G. Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes. Angew Chem Int Ed Engl. 2008; 47(12):2271-4. PMID: 18273845.
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Dyker CA, Lavallo V, Donnadieu B, Bertrand G. Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. Angew Chem Int Ed Engl. 2008; 47(17):3206-9. PMID: 18311741.
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Lavallo V, Dyker CA, Donnadieu B, Bertrand G. Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. Angew Chem Int Ed Engl. 2008; 47(29):5411-4. PMID: 18551494.
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Schoeller WW, Frey GD, Bertrand G. Tuning the nucleophilicity in cyclopropenylidenes. Chemistry. 2008; 14(15):4711-8. PMID: 18404754.
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Lavallo V, Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. Angew Chem Int Ed Engl. 2008; 47(28):5224-8. PMID: 18528830.
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Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. NHC-mediated aggregation of P4: isolation of a P12 cluster. J Am Chem Soc. 2007 Nov 21; 129(46):14180-1. PMID: 17973395.
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Lavallo V, Frey GD, Kousar S, Donnadieu B, Bertrand G. Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. Proc Natl Acad Sci U S A. 2007 Aug 21; 104(34):13569-73. PMID: 17698808.
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Song M, Donnadieu B, Soleilhavoup M, Bertrand G. Synthesis of phosphaformamidines and phosphaformamidinates. Chem Asian J. 2007 Jul 02; 2(7):904-8. PMID: 17551916.
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Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. Science. 2007 Apr 20; 316(5823):439-41. PMID: 17446400.
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Jazzar R, Bourg JB, Dewhurst RD, Donnadieu B, Bertrand G. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. J Org Chem. 2007 Apr 27; 72(9):3492-9. PMID: 17408289.
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Vignolle J, Gornitzka H, Maron L, Schoeller WW, Bourissou D, Bertrand G. Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation). J Am Chem Soc. 2007 Jan 31; 129(4):978-85. PMID: 17243835.
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Masuda JD, Martin D, Lyon-Saunier C, Baceiredo A, Gornitzka H, Donnadieu B, Bertrand G. Stable P-heterocyclic carbenes: scope and limitations. Chem Asian J. 2007 Jan 08; 2(1):178-87. PMID: 17441152.
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Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. Carbene activation of P4 and subsequent derivatization. Angew Chem Int Ed Engl. 2007; 46(37):7052-5. PMID: 17705209.
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Pascual S, Asay M, Illa O, Kato T, Bertrand G, Saffon-Merceron N, Branchadell V, Baceiredo A. Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2. Angew Chem Int Ed Engl. 2007; 46(47):9078-80. PMID: 17960549.
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DeHope A, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. Recently reported crystalline isothiazole carbenes: myth or reality. Angew Chem Int Ed Engl. 2007; 46(36):6922-5; discussion 6926. PMID: 17661300.
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Bourg JB, Rodriguez A, Scheschkewitz D, Gornitzka H, Bourissou D, Bertrand G. Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls. Angew Chem Int Ed Engl. 2007; 46(30):5741-5. PMID: 17592605.
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Anderson DR, Lavallo V, O'Leary DJ, Bertrand G, Grubbs RH. Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2007; 46(38):7262-5. PMID: 17623287.
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Jazzar R, Dewhurst RD, Bourg JB, Donnadieu B, Canac Y, Bertrand G. Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Angew Chem Int Ed Engl. 2007; 46(16):2899-902. PMID: 17352445.
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Canac Y, Aniol GE, Conejero S, Donnadieu B, Bertrand G. A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane. Eur J Inorg Chem. 2006 Dec 01; 2006(24):5076-5080. PMID: 19763185.
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Vignolle J, Donnadieu B, Bourissou D, Soleilhavoup M, Bertrand G. Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals. J Am Chem Soc. 2006 Nov 22; 128(46):14810-1. PMID: 17105283.
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Martin D, Tham FS, Baceiredo A, Bertrand G. Synthesis of extended polyphosphacumulenes. Chemistry. 2006 Nov 15; 12(33):8444-50. PMID: 17009365.
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Lavallo V, Ishida Y, Donnadieu B, Bertrand G. Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. Angew Chem Int Ed Engl. 2006 Oct 13; 45(40):6652-5. PMID: 16986195.
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Ishida Y, Donnadieu B, Bertrand G. Stable four-pi-electron, four-membered heterocyclic cations and carbenes. Proc Natl Acad Sci U S A. 2006 Sep 12; 103(37):13585-8. PMID: 16950877.
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Conejero S, Song M, Martin D, Canac Y, Soleilhavoup M, Bertrand G. New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. Chem Asian J. 2006 Jul 17; 1(1-2):155-60. PMID: 17441050.
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Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. Angew Chem Int Ed Engl. 2006 May 19; 45(21):3488-91. PMID: 16637087.
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Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory. Science. 2006 May 05; 312(5774):722-4. PMID: 16614171.
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Canac Y, Conejero S, Soleilhavoup M, Donnadieu B, Bertrand G. Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. J Am Chem Soc. 2006 Jan 18; 128(2):459-64. PMID: 16402832.
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Jazzar R, Liang H, Donnadieu B, Bertrand G. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. J Organomet Chem. 2006; 691(14):3201-3205. PMID: 19543436.
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Lavallo V, Canac Y, DeHope A, Donnadieu B, Bertrand G. A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. Angew Chem Int Ed Engl. 2005 Nov 11; 44(44):7236-9. PMID: 16229037.
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Lavallo V, Canac Y, Präsang C, Donnadieu B, Bertrand G. Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. Angew Chem Int Ed Engl. 2005 Sep 05; 44(35):5705-9. PMID: 16059961.
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Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds. Angew Chem Int Ed Engl. 2005 Aug 26; 44(34):5497-500. PMID: 16052642.
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Präsang C, Donnadieu B, Bertrand G. Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. J Am Chem Soc. 2005 Jul 27; 127(29):10182-3. PMID: 16028925.
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Martin D, Illa O, Baceiredo A, Bertrand G, Ortuño RM, Branchadell V. Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. J Org Chem. 2005 Jul 08; 70(14):5671-7. PMID: 15989352.
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Canac Y, Conejero S, Donnadieu B, Schoeller WW, Bertrand G. Persistent (amino)(silyl)carbenes. J Am Chem Soc. 2005 May 25; 127(20):7312-3. PMID: 15898770.
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Cattoën X, Miqueu K, Gornitzka H, Bourissou D, Bertrand G. Evidence for radical fragmentations from persistent singlet carbenes. J Am Chem Soc. 2005 Mar 16; 127(10):3292-3. PMID: 15755142.
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Martin D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G. A stable P-heterocyclic carbene. Angew Chem Int Ed Engl. 2005 Mar 04; 44(11):1700-3. PMID: 15712311.
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Teuma E, Lyon-Saunier C, Gornitzka H, Mignani G, Baceiredo A, Bertrand G. A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity. J Organomet Chem. 2005; 690(24-25):5541-5545. PMID: 19543437.
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Dumitrescu A, Rudzevich VL, Romanenko VD, Mari A, Schoeller WW, Bourissou D, Bertrand G. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. Inorg Chem. 2004 Oct 18; 43(21):6546-8. PMID: 15476350.
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Rodriguez A, Olsen RA, Ghaderi N, Scheschkewitz D, Tham FS, Mueller LJ, Bertrand G. Evidence for the coexistence of two bond-stretch isomers in solution. Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4880-3. PMID: 15372558.
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Rodriguez A, Tham FS, Schoeller WW, Bertrand G. Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid). Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4876-80. PMID: 15372559.
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Bertrand G. Chemistry. The modest undressing of a silicon center. Science. 2004 Aug 06; 305(5685):783-5. PMID: 15297652.
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Conejero S, Canac Y, Tham FS, Bertrand G. Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. Angew Chem Int Ed Engl. 2004 Aug 06; 43(31):4089-93. PMID: 15300703.
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Lavallo V, Mafhouz J, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. Synthesis, reactivity, and ligand properties of a stable alkyl carbene. J Am Chem Soc. 2004 Jul 21; 126(28):8670-1. PMID: 15250717.
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Krysiak J, Lyon C, Baceiredo A, Gornitzka H, Mikolajczyk M, Bertrand G. Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. Chemistry. 2004 Apr 19; 10(8):1982-6. PMID: 15079838.
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Otto M, Conejero S, Canac Y, Romanenko VD, Rudzevitch V, Bertrand G. Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. J Am Chem Soc. 2004 Feb 04; 126(4):1016-7. PMID: 14746458.
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Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Sigma-bond stretching: a static approach for a dynamic process. Angew Chem Int Ed Engl. 2004 Feb 01; 43(5):585-7. PMID: 14743410.
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Miqueu K, Despagnet-Ayoub E, Dyer PW, Bourissou D, Bertrand G. Theoretical study of rhodium(I) carbene complexes: the structural versatility of phosphino- compared with aminocarbenes. Chemistry. 2003 Dec 05; 9(23):5858-64. PMID: 14673857.
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Illa O, Gornitzka H, Baceiredo A, Bertrand G, Branchadell V, Ortuño RM. Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a nucleophilic stable carbene to aromatic aldehydes. J Org Chem. 2003 Oct 03; 68(20):7707-10. PMID: 14510546.
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Merceron-Saffon N, Baceiredo A, Gornitzka H, Bertrand G. Synthesis of carbenes through substitution reactions at a carbene center. Science. 2003 Aug 29; 301(5637):1223-5. PMID: 12947194.
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Canac Y, Bertrand G. nido-Five-vertex clusters: in and out of boron chemistry. Angew Chem Int Ed Engl. 2003 Aug 11; 42(31):3578-80. PMID: 12916028.
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Schoeller WW, Rozhenko A, Bourissou D, Bertrand G. On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As). Chemistry. 2003 Aug 04; 9(15):3611-7. PMID: 12898688.
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Amsallem D, Mazières S, Piquet-Fauré V, Gornitzka H, Baceiredo A, Bertrand G. A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete. Chemistry. 2002 Dec 02; 8(23):5305-11. PMID: 12432498.
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Merceron N, Baceiredo A, Gornitzka H, Bertrand G. C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents. Chem Commun (Camb). 2002 Oct 07; (19):2250-1. PMID: 12398001.
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Despagnet E, Gornitzka H, Rozhenko AB, Schoeller WW, Bourissou D, Bertrand G. Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene. Angew Chem Int Ed Engl. 2002 Aug 02; 41(15):2835-7. PMID: 12203501.
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Otto M, Scheschkewitz D, Kato T, Midland MM, Lambert JB, Bertrand G. The stable pentamethylcyclopentadienyl cation remains unknown. Angew Chem Int Ed Engl. 2002 Jul 02; 41(13):2275-6. PMID: 12203563.
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Merceron N, Miqueu K, Baceiredo A, Bertrand G. Stable (amino)(phosphino)carbenes: difunctional molecules. J Am Chem Soc. 2002 Jun 19; 124(24):6806-7. PMID: 12059184.
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Rudzevich VL, Gornitzka H, Miqueu K, Sotiropoulos JM, Pfister-Guillouzo G, Romanenko VD, Bertrand G. The first "naked" primary phosphanide anion [ArPH](-). Angew Chem Int Ed Engl. 2002 Apr 02; 41(7):1193-5. PMID: 12491256.
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Kato T, Gornitzka H, Baceiredo A, Schoeller WW, Bertrand G. Synthesis and rearrangement of diphosphorus analogues of amidinium salts. J Am Chem Soc. 2002 Mar 20; 124(11):2506-12. PMID: 11890799.
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Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Singlet diradicals: from transition states to crystalline compounds. Science. 2002 Mar 08; 295(5561):1880-1. PMID: 11884750.
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Goumri-Magnet S, Gornitzka H, Baceiredo A, Bertrand G. Synthetic Utility of Stable Phosphanylcarbenes: Synthesis and Crystal Structure of an a-(Lithiomethylene)phosphorane. Angew Chem Int Ed Engl. 1999 Mar 01; 38(5):678-680. PMID: 29711539.
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Emig N, Gabbaï FP, Krautscheid H, Réau R, Bertrand G. The Azide-Nitrilimine Analogy in Aluminum Chemistry. Angew Chem Int Ed Engl. 1998 Apr 20; 37(7):989-992. PMID: 29711487.
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Bertrand G. Ylidic Four p Electron Four-Membered ?5 -Phosphorus Heterocycles: Electronical Isomers of Heterocyclobutadienes. Angew Chem Int Ed Engl. 1998 Feb 16; 37(3):270-281. PMID: 29711272.
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Palacios F, Pagalday J, Piquet V, Dahan F, Baceiredo A, Bertrand G. N-Phosphino- and N-Phosphonionitrilimines: From Nucleophilic to Electrophilic 1,3-Dipoles. J Org Chem. 1997 Jan 24; 62(2):292-296. PMID: 11671401.
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Alcaraz G, Baceiredo A, Nieger M, Schoeller WW, Bertrand G. X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2lambda(5)-Diazaphosphetes: A New Type of 4-pi-Electron 4-Membered Heterocycle. Inorg Chem. 1996 Apr 24; 35(9):2458-2462. PMID: 11666457.
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