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    Guy Bertrand

    TitleProfessor
    SchoolUniversity of California, San Diego
    DepartmentChemistry and Biochemistry
    Address9500 Gilman Drive #0358
    CA La Jolla 92093
    Phone858-534-5412
    vCardDownload vCard

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Mahoney J, Jazzar R, Royal G, Martin D, Bertrand G. On the Advantage of Cyclic over Acyclic Carbenes to Access Isolable Capto-Dative C-Centered Radicals. Chemistry. 2017 Jan 19. PMID: 28105672.
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      2. Kleinhans G, Hansmann MM, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation. J Am Chem Soc. 2016 Dec 14; 138(49):15873-15876. PMID: 27960301.
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      3. Hansmann MM, Bertrand G. Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene. J Am Chem Soc. 2016 Dec 14; 138(49):15885-15888. PMID: 27960331.
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      4. Munz D, Chu J, Melaimi M, Bertrand G. NHC-CAAC Heterodimers with Three Stable Oxidation States. Angew Chem Int Ed Engl. 2016 Oct 4; 55(41):12886-90. PMID: 27628756.
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      5. Romero EA, Peltier JL, Jazzar R, Bertrand G. Catalyst-free dehydrocoupling of amines, alcohols, and thiols with pinacol borane and 9-borabicyclononane (9-BBN). Chem Commun (Camb). 2016 Aug 18; 52(69):10563-5. PMID: 27498971.
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      6. Hansmann MM, Jazzar R, Bertrand G. Singlet (Phosphino)phosphinidenes are Electrophilic. J Am Chem Soc. 2016 Jul 13; 138(27):8356-9. PMID: 27340902.
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      7. Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G. Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry. J Am Chem Soc. 2016 Jun 29; 138(25):7884-7. PMID: 27304485.
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      8. Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes. Chemistry. 2016 Jun 27; 22(27):9404-9. PMID: 27238837.
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      9. Li Z, Chen X, Benko Z, Liu L, Ruiz DA, Peltier JL, Bertrand G, Su CY, Grützmacher H. N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism. Angew Chem Int Ed Engl. 2016 May 10; 55(20):6018-22. PMID: 27060924.
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      10. Pranckevicius C, Liu L, Bertrand G, Stephan DW. Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene based Solely on Carbon. Angew Chem Int Ed Engl. 2016 Apr 25; 55(18):5536-40. PMID: 27028936.
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      11. Martin D, Marx VM, Grubbs RH, Bertrand G. A Ruthenium Catalyst for Olefin Metathesis Featuring an Anti-Bredt N-Heterocyclic Carbene Ligand. Adv Synth Catal. 2016 Mar 17; 358(6):965-969. PMID: 27594819.
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      12. Peltier JL, Jazzar R, Melaimi M, Bertrand G. Ancillary ligand-free copper catalysed hydrohydrazination of terminal alkynes with NH2NH2. Chem Commun (Camb). 2016 Feb 4; 52(13):2733-5. PMID: 26757745.
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      13. Kleinhans G, Guisado-Barrios G, Liles DC, Bertrand G, Bezuidenhout DI. A rhodium(i)-oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chem Commun (Camb). 2016 Feb 28; 52(17):3504-7. PMID: 26838677.
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      14. Jin L, Romero EA, Melaimi M, Bertrand G. The Janus Face of the X Ligand in the Copper-Catalyzed Azide-Alkyne Cycloaddition. J Am Chem Soc. 2015 Dec 23; 137(50):15696-8. PMID: 26611196.
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      15. Rao B, Tang H, Zeng X, Liu L, Melaimi M, Bertrand G. Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong s-Donating and p-Accepting Ligands for Transition Metals. Angew Chem Int Ed Engl. 2015 Dec 1; 54(49):14915-9. PMID: 26457345.
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      16. Liu L, Ruiz DA, Dahcheh F, Bertrand G. Isolation of a Lewis base stabilized parent phosphenium (PH2(+)) and related species. Chem Commun (Camb). 2015 Jul 28; 51(64):12732-5. PMID: 26166485.
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      17. Jin L, Tolentino DR, Melaimi M, Bertrand G. Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction". Sci Adv. 2015 Jun; 1(5):e1500304. PMID: 26601202.
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      18. Mahoney JK, Martin D, Thomas F, Moore CE, Rheingold AL, Bertrand G. Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes. J Am Chem Soc. 2015 Jun 17; 137(23):7519-25. PMID: 26011769.
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      19. Styra S, Melaimi M, Moore CE, Rheingold AL, Augenstein T, Breher F, Bertrand G. Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical. Chemistry. 2015 Jun 1; 21(23):8441-6. PMID: 25925367.
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      20. Hu X, Soleilhavoup M, Melaimi M, Chu J, Bertrand G. Air-Stable (CAAC)CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3 NH3. Angew Chem Int Ed Engl. 2015 May 11; 54(20):6008-11. PMID: 25802096.
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      21. Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, Cazin CS. A simple access to transition metal cyclopropenylidene complexes. Chem Commun (Camb). 2015 Mar 5; 51(23):4778-81. PMID: 25621852.
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      22. Tolentino DR, Jin L, Melaimi M, Bertrand G. Mesoionic Carbene-Gold(I) Catalyzed Bis-Hydrohydrazination of Alkynes with Parent Hydrazine. Chem Asian J. 2015 Oct; 10(10):2139-42. PMID: 25597889.
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      23. Soleilhavoup M, Bertrand G. Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise. Acc Chem Res. 2015 Feb 17; 48(2):256-66. PMID: 25515548.
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      24. Marx VM, Sullivan AH, Melaimi M, Virgil SC, Keitz BK, Weinberger DS, Bertrand G, Grubbs RH. Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis. Angew Chem Int Ed Engl. 2015 Feb 2; 54(6):1919-23. PMID: 25522160.
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      25. Jerabek P, Roesky HW, Bertrand G, Frenking G. Coinage Metals Binding as Main Group Elements: Structure and Bonding of the Carbene Complexes [TM(cAAC)2] and [TM(cAAC)2](+) (TM = Cu, Ag, Au). J Am Chem Soc. 2014 Dec 10; 136(49):17123-35. PMID: 25394669.
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      26. Dahcheh F, Stephan DW, Bertrand G. Oxidative Addition at a Carbene Center: Synthesis of an Iminoboryl-CAAC Adduct. Chemistry. 2015 Jan 2; 21(1):199-204. PMID: 25414006.
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      27. Dielmann F, Bertrand G. Reactivity of a Stable Phosphinonitrene towards Small Molecules. Chemistry. 2015 Jan 2; 21(1):191-8. PMID: 25395098.
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      28. Dahcheh F, Martin D, Stephan DW, Bertrand G. Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes. Angew Chem Int Ed Engl. 2014 Nov 24; 53(48):13159-63. PMID: 25267591.
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      29. Hu X, Martin D, Melaimi M, Bertrand G. Gold-catalyzed hydroarylation of alkenes with dialkylanilines. J Am Chem Soc. 2014 Oct 1; 136(39):13594-7. PMID: 25222130.
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      30. Jin L, Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Bertrand G. Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts. Angew Chem Int Ed Engl. 2014 Aug 18; 53(34):9059-63. PMID: 24985149.
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      31. Ruiz DA, Melaimi M, Bertrand G. An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]. Chem Commun (Camb). 2014 Jun 24; 50(58):7837-9. PMID: 24909943.
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      32. Kretschmer R, Ruiz DA, Moore CE, Rheingold AL, Bertrand G. One-, Two-, and Three-Electron Reduction of a Cyclic Alkyl(amino)carbene-SbCl3 Adduct. Angew Chem Int Ed Engl. 2014 Jul 28; 53(31):8176-9. PMID: 24961494.
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      33. Ung G, Rittle J, Soleilhavoup M, Bertrand G, Peters JC. Two-Coordinate Fe(0) and Co(0) Complexes Supported by Cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2014 Aug 4; 53(32):8427-31. PMID: 24953342.
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      34. Weinstein CM, Martin CD, Liu L, Bertrand G. Cross-Coupling Reactions between Stable Carbenes. Angew Chem Int Ed Engl. 2014 Jun 16; 53(25):6550-3. PMID: 24838590.
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      35. Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes. J Am Chem Soc. 2014 Apr 30; 136(17):6235-8. PMID: 24731250.
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      36. Martin D, Canac Y, Lavallo V, Bertrand G. Comparative reactivity of different types of stable cyclic and acyclic mono- and diamino carbenes with simple organic substrates. J Am Chem Soc. 2014 Apr 2; 136(13):5023-30. PMID: 24634983.
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      37. Dielmann F, Andrada DM, Frenking G, Bertrand G. Isolation of bridging and terminal coinage metal-nitrene complexes. J Am Chem Soc. 2014 Mar 12; 136(10):3800-2. PMID: 24559041.
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      38. Bezuidenhout DI, Kleinhans G, Guisado-Barrios G, Liles DC, Ung G, Bertrand G. Isolation of a potassium bis(1,2,3-triazol-5-ylidene)carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes. Chem Commun (Camb). 2014 Mar 7; 50(19):2431-3. PMID: 24448261.
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      39. Mahoney JK, Martin D, Moore CE, Rheingold AL, Bertrand G. Bottleable (amino)(carboxy) radicals derived from cyclic (alkyl)(amino) carbenes. J Am Chem Soc. 2013 Dec 18; 135(50):18766-9. PMID: 24304381.
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      40. Martin D, Lassauque N, Steinmann F, Manuel G, Bertrand G. Experimental and computational studies of anti-bredt amidinium salts. Chemistry. 2013 Oct 25; 19(44):14895-901. PMID: 24105742.
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      41. Dielmann F, Moore CE, Rheingold AL, Bertrand G. Crystalline, Lewis base-free, cationic phosphoranimines (iminophosphonium salts). J Am Chem Soc. 2013 Sep 25; 135(38):14071-3. PMID: 24007472.
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      42. Ung G, Bertrand G. ß- and a-Hydride abstraction in Gold(I) alkyl complexes. Angew Chem Int Ed Engl. 2013 Oct 18; 52(43):11388-91. PMID: 24027200.
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      43. Ruiz DA, Melaimi M, Bertrand G. Carbodicarbenes, carbon(0) derivatives, can dimerize. Chem Asian J. 2013 Dec; 8(12):2940-2. PMID: 23960023.
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      44. Martin CD, Soleilhavoup M, Bertrand G. Carbene-Stabilized Main Group Radicals and Radical Ions. Chem Sci. 2013 Aug 1; 4(8):3020-3030. PMID: 23878717.
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      45. Weinberger DS, Melaimi M, Moore CE, Rheingold AL, Frenking G, Jerabek P, Bertrand G. Isolation of neutral mono- and dinuclear gold complexes of cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2013 Aug 19; 52(34):8964-7. PMID: 23861304.
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      46. Ruiz DA, Ung G, Melaimi M, Bertrand G. Deprotonation of a borohydride: synthesis of a carbene-stabilized boryl anion. Angew Chem Int Ed Engl. 2013 Jul 15; 52(29):7590-2. PMID: 23765789.
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      47. Martin D, Moore CE, Rheingold AL, Bertrand G. An air-stable oxyallyl radical cation. Angew Chem Int Ed Engl. 2013 Jul 1; 52(27):7014-7. PMID: 23720417.
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      48. Martin CD, Weinstein CM, Moore CE, Rheingold AL, Bertrand G. Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters. Chem Commun (Camb). 2013 May 18; 49(40):4486-8. PMID: 23571800.
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      49. López-Gómez MJ, Martin D, Bertrand G. Anti-Bredt N-heterocyclic carbene: an efficient ligand for the gold(I)-catalyzed hydroamination of terminal alkynes with parent hydrazine. Chem Commun (Camb). 2013 May 18; 49(40):4483-5. PMID: 23552965.
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      50. Back O, Henry-Ellinger M, Martin CD, Martin D, Bertrand G. 31P NMR chemical shifts of carbene-phosphinidene adducts as an indicator of the p-accepting properties of carbenes. Angew Chem Int Ed Engl. 2013 Mar 4; 52(10):2939-43. PMID: 23364832.
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      51. Ung G, Soleilhavoup M, Bertrand G. Gold(III)- versus gold(I)-induced cyclization: synthesis of six-membered mesoionic carbene and acyclic (aryl)(heteroaryl) carbene complexes. Angew Chem Int Ed Engl. 2013 Jan 7; 52(2):758-61. PMID: 23169762.
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      52. Yan X, Bouffard J, Guisado-Barrios G, Donnadieu B, Bertrand G. Anionic 1,2,3-triazole-4,5-diylidene: a 1,2-dihapto ligand for the construction of bimetallic complexes. Chemistry. 2012 Nov 12; 18(46):14627-31. PMID: 23042507.
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      53. Dielmann F, Back O, Henry-Ellinger M, Jerabek P, Frenking G, Bertrand G. A crystalline singlet phosphinonitrene: a nitrogen atom-transfer agent. Science. 2012 Sep 21; 337(6101):1526-8. PMID: 22997335.
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      54. Ung G, Bertrand G. C-F bond activation with an apparently benign ethynyl dithiocarbamate, and subsequent fluoride transfer reactions. Chemistry. 2012 Oct 8; 18(41):12955-7. PMID: 22961643.
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      55. Ung G, Mendoza-Espinosa D, Bertrand G. Ynamides: stable ligand equivalents of unstable oxazol-4-ylidenes (novel mesoionic carbenes). Chem Commun (Camb). 2012 Jul 18; 48(56):7088-90. PMID: 22684100.
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      56. Martin D, Lassauque N, Donnadieu B, Bertrand G. A cyclic diaminocarbene with a pyramidalized nitrogen atom: a stable N-heterocyclic carbene with enhanced electrophilicity. Angew Chem Int Ed Engl. 2012 Jun 18; 51(25):6172-5. PMID: 22565863.
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      57. Celik MA, Sure R, Klein S, Kinjo R, Bertrand G, Frenking G. Borylene complexes (BH)L2 and nitrogen cation complexes (N+)L2: isoelectronic homologues of carbones CL2. Chemistry. 2012 Apr 27; 18(18):5676-92. PMID: 22434609.
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      58. Ung G, Frey GD, Schoeller WW, Bertrand G. Bond activation with an apparently benign ethynyl dithiocarbamate Ar-C=C-S-C(S)NR2. Angew Chem Int Ed Engl. 2011 Oct 10; 50(42):9923-5. PMID: 23210141.
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      59. Martin D, Melaimi M, Soleilhavoup M, Bertrand G. A Brief Survey of our Contribution to Stable Carbene Chemistry. Organometallics. 2011 Oct 24; 30(20):5304-5313. PMID: 22707843.
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      60. Mendoza-Espinosa D, Ung G, Donnadieu B, Bertrand G. Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. Chem Commun (Camb). 2011 Oct 14; 47(38):10614-6. PMID: 21879048.
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      61. Dehope A, Donnadieu B, Bertrand G. Grubbs and Hoveyda-Type Ruthenium Complexes Bearing a Cyclic Bent-Allene. J Organomet Chem. 2011 Aug 15; 696(17):2899-2903. PMID: 21765542.
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      62. Kinjo R, Donnadieu B, Celik MA, Frenking G, Bertrand G. Synthesis and characterization of a neutral tricoordinate organoboron isoelectronic with amines. Science. 2011 Jul 29; 333(6042):610-3. PMID: 21798945.
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      63. Ung G, Bertrand G. Stability and electronic properties of imidazole-based mesoionic carbenes. Chemistry. 2011 Jul 18; 17(30):8269-72. PMID: 21656597.
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      64. Keitz BK, Bouffard J, Bertrand G, Grubbs RH. Protonolysis of a ruthenium-carbene bond and applications in olefin metathesis. J Am Chem Soc. 2011 Jun 8; 133(22):8498-501. PMID: 21574621.
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      65. Kinjo R, Donnadieu B, Bertrand G. Gold-catalyzed hydroamination of alkynes and allenes with parent hydrazine. Angew Chem Int Ed Engl. 2011 Jun 6; 50(24):5560-3. PMID: 21574224.
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      66. Ung G, Mendoza-Espinosa D, Bouffard J, Bertrand G. A stable acyclic ligand equivalent of an unstable 1,3-dithiol-5-ylidene. Angew Chem Int Ed Engl. 2011 Apr 26; 50(18):4215-8. PMID: 21472947.
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      67. Bouffard J, Keitz BK, Tonner R, Lavallo V, Guisado-Barrios G, Frenking G, Grubbs RH, Bertrand G. Synthesis of Highly Stable 1,3-Diaryl-1H-1,2,3-triazol-5-ylidenes and their Applications in Ruthenium-Catalyzed Olefin Metathesis. Organometallics. 2011 Mar 9; 30(9):2617-2627. PMID: 21572542.
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      68. Mendoza-Espinosa D, Donnadieu B, Bertrand G. Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts. Chem Asian J. 2011 Apr 4; 6(4):1099-103. PMID: 21322115.
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      69. Lavallo V, El-Batta A, Bertrand G, Grubbs RH. Insights into the carbene-initiated aggregation of [Fe(cot)(2)]. Angew Chem Int Ed Engl. 2011 Jan 3; 50(1):268-71. PMID: 21110365.
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      70. Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. Bis(1,2,3-triazol-5-ylidenes) (i-bitz) as Stable 1,4-Bidentate Ligands Based on Mesoionic Carbenes (MICs). Organometallics. 2011; 30(21):6017-6021. PMID: 22096269.
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      71. Dehope A, Mendoza-Espinosa D, Donnadieu B, Bertrand G. A persistent (amino)(ferrocenyl)carbene(). New J Chem. 2011 Jan 1; 35(10):2037-2042. PMID: 22707878.
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      72. Martin D, Soleilhavoup M, Bertrand G. Stable singlet carbenes as mimics for transition metal centers. Chem Sci. 2011 Jan 1; 2(3):389-399. PMID: 21743834.
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      73. Frey GD, Masuda JD, Donnadieu B, Bertrand G. Activation of Si-H, B-H, and P-H bonds at a single nonmetal center. Angew Chem Int Ed Engl. 2010 Dec 3; 49(49):9444-7. PMID: 21031393.
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      74. Melaimi M, Soleilhavoup M, Bertrand G. Stable cyclic carbenes and related species beyond diaminocarbenes. Angew Chem Int Ed Engl. 2010 Nov 15; 49(47):8810-49. PMID: 20836099.
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      75. Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. Synthesis of a room-temperature-stable dimeric copper(I) hydride. Chem Asian J. 2011 Feb 1; 6(2):402-5. PMID: 20945453.
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      76. Kinjo R, Donnadieu B, Bertrand G. Isolation of a carbene-stabilized phosphorus mononitride and its radical cation (PN+*). Angew Chem Int Ed Engl. 2010 Aug 9; 49(34):5930-3. PMID: 20632430.
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      77. Back O, Celik MA, Frenking G, Melaimi M, Donnadieu B, Bertrand G. A crystalline phosphinyl radical cation. J Am Chem Soc. 2010 Aug 4; 132(30):10262-3. PMID: 20662507.
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      78. Guisado-Barrios G, Bouffard J, Donnadieu B, Bertrand G. Crystalline 1H-1,2,3-triazol-5-ylidenes: new stable mesoionic carbenes (MICs). Angew Chem Int Ed Engl. 2010 Jun 28; 49(28):4759-62. PMID: 20509134.
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      79. Mendoza-Espinosa D, Donnadieu B, Bertrand G. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene. J Am Chem Soc. 2010 Jun 2; 132(21):7264-5. PMID: 20443633.
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      80. Back O, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. Isolation of crystalline carbene-stabilized P(2)-radical cations and P(2)-dications. Nat Chem. 2010 May; 2(5):369-73. PMID: 20414236.
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      81. Zeng X, Kinjo R, Donnadieu B, Bertrand G. Serendipitous discovery of the catalytic hydroammoniumation and methylamination of alkynes. Angew Chem Int Ed Engl. 2010; 49(5):942-5. PMID: 20058283.
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      82. Kuchenbeiser G, Soleilhavoup M, Donnadieu B, Bertrand G. Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts. Chem Asian J. 2009 Nov 2; 4(11):1745-50. PMID: 19780080.
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      83. Aldeco-Perez E, Rosenthal AJ, Donnadieu B, Parameswaran P, Frenking G, Bertrand G. Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene. Science. 2009 Oct 23; 326(5952):556-9. PMID: 19900893.
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      84. Fuks G, Saffon N, Maron L, Bertrand G, Bourissou D. Ionic-type reactivity of 1,3-dibora-2,4-diphosphoniocyclobutane-1,3-diyls: regio- and stereoselective addition of hydracids. J Am Chem Soc. 2009 Sep 30; 131(38):13681-9. PMID: 19772363.
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      85. Fernández I, Dyker CA, DeHope A, Donnadieu B, Frenking G, Bertrand G. Exocyclic delocalization at the expense of aromaticity in 3,5-bis(pi-donor) substituted pyrazolium ions and corresponding cyclic bent allenes. J Am Chem Soc. 2009 Aug 26; 131(33):11875-81. PMID: 19645451.
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      86. Zeng X, Soleilhavoup M, Bertrand G. Gold-catalyzed intermolecular Markovnikov hydroamination of allenes with secondary amines. Org Lett. 2009 Aug 6; 11(15):3166-9. PMID: 19719176.
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      87. Tran HN, Donnadieu B, Bertrand G, Mathey F. Umpolung of electrophilic terminal phosphinidene complexes by interaction with nucleophilic carbenes. Chem Asian J. 2009 Aug 3; 4(8):1225-8. PMID: 19557786.
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      88. Zeng X, Frey GD, Kinjo R, Donnadieu B, Bertrand G. Synthesis of a simplified version of stable bulky and rigid cyclic (alkyl)(amino)carbenes, and catalytic activity of the ensuing gold(I) complex in the three-component preparation of 1,2-dihydroquinoline derivatives. J Am Chem Soc. 2009 Jun 24; 131(24):8690-6. PMID: 19456108.
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      89. Kinjo R, Ishida Y, Donnadieu B, Bertrand G. Isolation of bicyclopropenylidenes: derivatives of the smallest member of the fulvalene family. Angew Chem Int Ed Engl. 2009; 48(3):517-20. PMID: 19072812.
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      90. Zeng X, Frey GD, Kousar S, Bertrand G. A cationic gold(I) complex as a general catalyst for the intermolecular hydroamination of alkynes: application to the one-pot synthesis of allenes from two alkynes and a sacrificial amine. Chemistry. 2009; 15(13):3056-60. PMID: 19219866.
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      91. Melaimi M, Parameswaran P, Donnadieu B, Frenking G, Bertrand G. Synthesis and ligand properties of a persistent, all-carbon four-membered-ring allene. Angew Chem Int Ed Engl. 2009; 48(26):4792-5. PMID: 19472243.
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      92. Asay M, Donnadieu B, Schoeller WW, Bertrand G. Synthesis of allenylidene lithium and silver complexes, and subsequent transmetalation reactions. Angew Chem Int Ed Engl. 2009; 48(26):4796-9. PMID: 19472245.
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      93. Back O, Kuchenbeiser G, Donnadieu B, Bertrand G. Nonmetal-mediated fragmentation of P4: isolation of P1 and P2 bis(carbene) adducts. Angew Chem Int Ed Engl. 2009; 48(30):5530-3. PMID: 19544519.
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      94. Giziroglu E, Donnadieu B, Bertrand G. Reluctance of 4-chloro-5-metalla-1,3,2-diazaborolines to undergo metal halide beta-elimination: an opportunity for C-functionalization of 1,3,2-diazaborolines. Inorg Chem. 2008 Nov 3; 47(21):9751-3. PMID: 18841958.
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      95. Frey GD, Song M, Bourg JB, Donnadieu B, Soleilhavoup M, Bertrand G. A persistent P,N-heterocyclic carbene. Chem Commun (Camb). 2008 Oct 21; (39):4711-3. PMID: 18830468.
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      96. Dyker CA, Bertrand G. Chemistry. Soluble allotropes of main-group elements. Science. 2008 Aug 22; 321(5892):1050-1. PMID: 18719272.
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      97. Rodriguez A, Fuks G, Bourg JB, Bourissou D, Tham FS, Bertrand G. 1,3-Diborata-2,4-diphosphoniocyclobutane-1,3-diyls communicate through a para-phenylene linker. Dalton Trans. 2008 Sep 7; (33):4482-7. PMID: 18698452.
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      98. Asay M, Donnadieu B, Baceiredo A, Soleilhavoup M, Bertrand G. Cyclic (amino)[bis(ylide)]carbene as an anionic bidentate ligand for transition-metal complexes. Inorg Chem. 2008 May 19; 47(10):3949-51. PMID: 18422308.
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      99. Frey GD, Dewhurst RD, Kousar S, Donnadieu B, Bertrand G. Cyclic (Alkyl)(amino)carbene Gold(I) complexes: A Synthetic and Structural Investigation. J Organomet Chem. 2008 Apr; 693(8-9):1674-1682. PMID: 19343084.
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      100. Kuchenbeiser G, Donnadieu B, Bertrand G. Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes. J Organomet Chem. 2008 Mar 1; 693(5):899-904. PMID: 19255609.
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      101. Anderson DR, Ung T, Mkrtumyan G, Bertrand G, Grubbs RH, Schrodi Y. Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes. Organometallics. 2008 Jan 12; 27(4):563-566. PMID: 18584055.
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      102. Vignolle J, Gornitzka H, Donnadieu B, Bourissou D, Bertrand G. Palladium-oxygen and palladium-arene interactions in complexes derived from biaryl aminocarbenes: comparison with biaryl phosphanes. Angew Chem Int Ed Engl. 2008; 47(12):2271-4. PMID: 18273845.
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      103. Gandon V, Bourg JB, Tham FS, Schoeller WW, Bertrand G. The existence of two short-bond isomers for bicyclo[1.1.0]butane derivatives based on boron and phosphorus. Angew Chem Int Ed Engl. 2008; 47(1):155-9. PMID: 18022990.
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      104. Asay M, Kato T, Saffon-Merceron N, Cossío FP, Baceiredo A, Bertrand G. Synthesis and ligand properties of a stable five-membered-ring vinylidenephosphorane. Angew Chem Int Ed Engl. 2008; 47(39):7530-3. PMID: 18704912.
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      105. Lavallo V, Frey GD, Donnadieu B, Soleilhavoup M, Bertrand G. Homogeneous catalytic hydroamination of alkynes and allenes with ammonia. Angew Chem Int Ed Engl. 2008; 47(28):5224-8. PMID: 18528830.
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      106. Lavallo V, Dyker CA, Donnadieu B, Bertrand G. Synthesis and ligand properties of stable five-membered-ring allenes containing only second-row elements. Angew Chem Int Ed Engl. 2008; 47(29):5411-4. PMID: 18551494.
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      107. Schoeller WW, Frey GD, Bertrand G. Tuning the nucleophilicity in cyclopropenylidenes. Chemistry. 2008; 14(15):4711-8. PMID: 18404754.
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      108. Dyker CA, Lavallo V, Donnadieu B, Bertrand G. Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand. Angew Chem Int Ed Engl. 2008; 47(17):3206-9. PMID: 18311741.
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      109. Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. NHC-mediated aggregation of P4: isolation of a P12 cluster. J Am Chem Soc. 2007 Nov 21; 129(46):14180-1. PMID: 17973395.
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      110. Lavallo V, Frey GD, Kousar S, Donnadieu B, Bertrand G. Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. Proc Natl Acad Sci U S A. 2007 Aug 21; 104(34):13569-73. PMID: 17698808.
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      111. Song M, Donnadieu B, Soleilhavoup M, Bertrand G. Synthesis of phosphaformamidines and phosphaformamidinates. Chem Asian J. 2007 Jul 2; 2(7):904-8. PMID: 17551916.
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      112. Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. Science. 2007 Apr 20; 316(5823):439-41. PMID: 17446400.
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      113. Jazzar R, Bourg JB, Dewhurst RD, Donnadieu B, Bertrand G. Intramolecular "hydroiminiumation and -amidiniumation" of alkenes: a convenient, flexible, and scalable route to cyclic iminium and imidazolinium salts. J Org Chem. 2007 Apr 27; 72(9):3492-9. PMID: 17408289.
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      114. Vignolle J, Gornitzka H, Maron L, Schoeller WW, Bourissou D, Bertrand G. Transient palladadiphosphanylcarbenes: singlet carbenes with an "inverse" electronic configuration (p(pi)2 instead of sigma2) and unusual transannular metal-carbene interactions (piC-->Pd donation and sigmaPd-->C back-donation). J Am Chem Soc. 2007 Jan 31; 129(4):978-85. PMID: 17243835.
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      115. Masuda JD, Martin D, Lyon-Saunier C, Baceiredo A, Gornitzka H, Donnadieu B, Bertrand G. Stable P-heterocyclic carbenes: scope and limitations. Chem Asian J. 2007 Jan 8; 2(1):178-87. PMID: 17441152.
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      116. Bourg JB, Rodriguez A, Scheschkewitz D, Gornitzka H, Bourissou D, Bertrand G. Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls. Angew Chem Int Ed Engl. 2007; 46(30):5741-5. PMID: 17592605.
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      117. DeHope A, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G. Recently reported crystalline isothiazole carbenes: myth or reality. Angew Chem Int Ed Engl. 2007; 46(36):6922-5; discussion 6926. PMID: 17661300.
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      118. Anderson DR, Lavallo V, O'Leary DJ, Bertrand G, Grubbs RH. Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes. Angew Chem Int Ed Engl. 2007; 46(38):7262-5. PMID: 17623287.
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      119. Pascual S, Asay M, Illa O, Kato T, Bertrand G, Saffon-Merceron N, Branchadell V, Baceiredo A. Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2. Angew Chem Int Ed Engl. 2007; 46(47):9078-80. PMID: 17960549.
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      120. Masuda JD, Schoeller WW, Donnadieu B, Bertrand G. Carbene activation of P4 and subsequent derivatization. Angew Chem Int Ed Engl. 2007; 46(37):7052-5. PMID: 17705209.
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      121. Jazzar R, Dewhurst RD, Bourg JB, Donnadieu B, Canac Y, Bertrand G. Intramolecular "hydroiminiumation" of alkenes: application to the synthesis of conjugate acids of cyclic alkyl amino carbenes (CAACs). Angew Chem Int Ed Engl. 2007; 46(16):2899-902. PMID: 17352445.
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      122. Canac Y, Aniol GE, Conejero S, Donnadieu B, Bertrand G. A Facile Synthesis of Carbamoylsilanes, -boranes and -phosphane Oxides - Isolation of the First Uncomplexed Carbamoylborane. Eur J Inorg Chem. 2006 Dec 1; 2006(24):5076-5080. PMID: 19763185.
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      123. Vignolle J, Donnadieu B, Bourissou D, Soleilhavoup M, Bertrand G. Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals. J Am Chem Soc. 2006 Nov 22; 128(46):14810-1. PMID: 17105283.
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      124. Martin D, Tham FS, Baceiredo A, Bertrand G. Synthesis of extended polyphosphacumulenes. Chemistry. 2006 Nov 15; 12(33):8444-50. PMID: 17009365.
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      125. Lavallo V, Ishida Y, Donnadieu B, Bertrand G. Isolation of cyclopropenylidene-lithium adducts: the Weiss-Yoshida reagent. Angew Chem Int Ed Engl. 2006 Oct 13; 45(40):6652-5. PMID: 16986195.
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      126. Ishida Y, Donnadieu B, Bertrand G. Stable four-pi-electron, four-membered heterocyclic cations and carbenes. Proc Natl Acad Sci U S A. 2006 Sep 12; 103(37):13585-8. PMID: 16950877.
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      127. Conejero S, Song M, Martin D, Canac Y, Soleilhavoup M, Bertrand G. New synthetic routes to C-amino phosphorus ylides and their subsequent fragmentation into carbenes and phosphines. Chem Asian J. 2006 Jul 17; 1(1-2):155-60. PMID: 17441050.
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      128. Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap. Angew Chem Int Ed Engl. 2006 May 19; 45(21):3488-91. PMID: 16637087.
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      129. Lavallo V, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. Cyclopropenylidenes: from interstellar space to an isolated derivative in the laboratory. Science. 2006 May 5; 312(5774):722-4. PMID: 16614171.
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      130. Canac Y, Conejero S, Soleilhavoup M, Donnadieu B, Bertrand G. Synthesis of transient and stable C-amino phosphorus ylides and their fragmentation into transient and stable carbenes. J Am Chem Soc. 2006 Jan 18; 128(2):459-64. PMID: 16402832.
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      131. Jazzar R, Liang H, Donnadieu B, Bertrand G. A New Synthetic Method for the Preparation of Protonated-NHCs and Related Compounds. J Organomet Chem. 2006; 691(14):3201-3205. PMID: 19543436.
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      132. Lavallo V, Canac Y, DeHope A, Donnadieu B, Bertrand G. A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes. Angew Chem Int Ed Engl. 2005 Nov 11; 44(44):7236-9. PMID: 16229037.
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      133. Lavallo V, Canac Y, Präsang C, Donnadieu B, Bertrand G. Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference. Angew Chem Int Ed Engl. 2005 Sep 5; 44(35):5705-9. PMID: 16059961.
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      134. Kato T, Gornitzka H, Schoeller WW, Baceiredo A, Bertrand G. Dimerization of a cyclo-1sigma4,3sigma2,4sigma2-triphosphapentadienyl radical: evidence for phosphorus-phosphorus odd-electron bonds. Angew Chem Int Ed Engl. 2005 Aug 26; 44(34):5497-500. PMID: 16052642.
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      135. Präsang C, Donnadieu B, Bertrand G. Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties. J Am Chem Soc. 2005 Jul 27; 127(29):10182-3. PMID: 16028925.
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      136. Martin D, Illa O, Baceiredo A, Bertrand G, Ortuño RM, Branchadell V. Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. J Org Chem. 2005 Jul 8; 70(14):5671-7. PMID: 15989352.
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      137. Canac Y, Conejero S, Donnadieu B, Schoeller WW, Bertrand G. Persistent (amino)(silyl)carbenes. J Am Chem Soc. 2005 May 25; 127(20):7312-3. PMID: 15898770.
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      138. Cattoën X, Miqueu K, Gornitzka H, Bourissou D, Bertrand G. Evidence for radical fragmentations from persistent singlet carbenes. J Am Chem Soc. 2005 Mar 16; 127(10):3292-3. PMID: 15755142.
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      139. Martin D, Baceiredo A, Gornitzka H, Schoeller WW, Bertrand G. A stable P-heterocyclic carbene. Angew Chem Int Ed Engl. 2005 Mar 4; 44(11):1700-3. PMID: 15712311.
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      140. Teuma E, Lyon-Saunier C, Gornitzka H, Mignani G, Baceiredo A, Bertrand G. A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis, Structure, and Catalytic Activity. J Organomet Chem. 2005; 690(24-25):5541-5545. PMID: 19543437.
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      141. Dumitrescu A, Rudzevich VL, Romanenko VD, Mari A, Schoeller WW, Bourissou D, Bertrand G. Persistent phosphinyl radicals featuring a bulky amino substituent and the 2,6-bis(trifluoromethyl)phenyl group. Inorg Chem. 2004 Oct 18; 43(21):6546-8. PMID: 15476350.
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      142. Rodriguez A, Tham FS, Schoeller WW, Bertrand G. Catenation of two singlet diradicals: synthesis of a stable tetraradical (tetraradicaloid). Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4876-80. PMID: 15372559.
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      143. Rodriguez A, Olsen RA, Ghaderi N, Scheschkewitz D, Tham FS, Mueller LJ, Bertrand G. Evidence for the coexistence of two bond-stretch isomers in solution. Angew Chem Int Ed Engl. 2004 Sep 20; 43(37):4880-3. PMID: 15372558.
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      144. Bertrand G. Chemistry. The modest undressing of a silicon center. Science. 2004 Aug 6; 305(5685):783-5. PMID: 15297652.
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      145. Conejero S, Canac Y, Tham FS, Bertrand G. Readily available onio-substituted methyleneiminium salts: single precursors for a variety of aminocarbenes. Angew Chem Int Ed Engl. 2004 Aug 6; 43(31):4089-93. PMID: 15300703.
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      146. Lavallo V, Mafhouz J, Canac Y, Donnadieu B, Schoeller WW, Bertrand G. Synthesis, reactivity, and ligand properties of a stable alkyl carbene. J Am Chem Soc. 2004 Jul 21; 126(28):8670-1. PMID: 15250717.
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      147. Krysiak J, Lyon C, Baceiredo A, Gornitzka H, Mikolajczyk M, Bertrand G. Stable optically pure phosphino(silyl)carbenes: reagents for highly enantioselective cyclopropanation reactions. Chemistry. 2004 Apr 19; 10(8):1982-6. PMID: 15079838.
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      148. Otto M, Conejero S, Canac Y, Romanenko VD, Rudzevitch V, Bertrand G. Mono- and diaminocarbenes from chloroiminium and -amidinium salts: synthesis of metal-free bis(dimethylamino)carbene. J Am Chem Soc. 2004 Feb 4; 126(4):1016-7. PMID: 14746458.
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      149. Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Sigma-bond stretching: a static approach for a dynamic process. Angew Chem Int Ed Engl. 2004 Feb 1; 43(5):585-7. PMID: 14743410.
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      150. Miqueu K, Despagnet-Ayoub E, Dyer PW, Bourissou D, Bertrand G. Theoretical study of rhodium(I) carbene complexes: the structural versatility of phosphino- compared with aminocarbenes. Chemistry. 2003 Dec 5; 9(23):5858-64. PMID: 14673857.
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      151. Illa O, Gornitzka H, Baceiredo A, Bertrand G, Branchadell V, Ortuño RM. Stereoselective synthesis of phosphoranyl aryloxiranes through the addition of a nucleophilic stable carbene to aromatic aldehydes. J Org Chem. 2003 Oct 3; 68(20):7707-10. PMID: 14510546.
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      152. Merceron-Saffon N, Baceiredo A, Gornitzka H, Bertrand G. Synthesis of carbenes through substitution reactions at a carbene center. Science. 2003 Aug 29; 301(5637):1223-5. PMID: 12947194.
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      153. Canac Y, Bertrand G. nido-Five-vertex clusters: in and out of boron chemistry. Angew Chem Int Ed Engl. 2003 Aug 11; 42(31):3578-80. PMID: 12916028.
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      154. Schoeller WW, Rozhenko A, Bourissou D, Bertrand G. On the electronic structures of the 1,3-diboracyclobutane-1,3-diyls and their valence isomers with a B2E2 skeleton (E=N, P, As). Chemistry. 2003 Aug 4; 9(15):3611-7. PMID: 12898688.
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      155. Amsallem D, Mazières S, Piquet-Fauré V, Gornitzka H, Baceiredo A, Bertrand G. A rare example of a rearrangement involving four structural isomers: alpha-phosphinonitrile/C-phosphinoketenimine/1-aza-4- phosphabutadiene/1,2-dihydro-1,2-azaphosphete. Chemistry. 2002 Dec 2; 8(23):5305-11. PMID: 12432498.
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      156. Merceron N, Baceiredo A, Gornitzka H, Bertrand G. C-phosphanyl-C-chloroiminium salts as electrophilic carbene synthetic equivalents. Chem Commun (Camb). 2002 Oct 7; (19):2250-1. PMID: 12398001.
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      157. Despagnet E, Gornitzka H, Rozhenko AB, Schoeller WW, Bourissou D, Bertrand G. Stable non-push-pull phosphanylcarbenes: NMR spectroscopic characterization of a methylcarbene. Angew Chem Int Ed Engl. 2002 Aug 2; 41(15):2835-7. PMID: 12203501.
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      158. Otto M, Scheschkewitz D, Kato T, Midland MM, Lambert JB, Bertrand G. The stable pentamethylcyclopentadienyl cation remains unknown. Angew Chem Int Ed Engl. 2002 Jul 2; 41(13):2275-6. PMID: 12203563.
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      159. Merceron N, Miqueu K, Baceiredo A, Bertrand G. Stable (amino)(phosphino)carbenes: difunctional molecules. J Am Chem Soc. 2002 Jun 19; 124(24):6806-7. PMID: 12059184.
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      160. Rudzevich VL, Gornitzka H, Miqueu K, Sotiropoulos JM, Pfister-Guillouzo G, Romanenko VD, Bertrand G. The first "naked" primary phosphanide anion [ArPH](-). Angew Chem Int Ed Engl. 2002 Apr 2; 41(7):1193-5. PMID: 12491256.
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      161. Kato T, Gornitzka H, Baceiredo A, Schoeller WW, Bertrand G. Synthesis and rearrangement of diphosphorus analogues of amidinium salts. J Am Chem Soc. 2002 Mar 20; 124(11):2506-12. PMID: 11890799.
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      162. Scheschkewitz D, Amii H, Gornitzka H, Schoeller WW, Bourissou D, Bertrand G. Singlet diradicals: from transition states to crystalline compounds. Science. 2002 Mar 8; 295(5561):1880-1. PMID: 11884750.
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      163. Alcaraz G, Baceiredo A, Nieger M, Schoeller WW, Bertrand G. X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2lambda(5)-Diazaphosphetes: A New Type of 4-pi-Electron 4-Membered Heterocycle. Inorg Chem. 1996 Apr 24; 35(9):2458-2462. PMID: 11666457.
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