Clifford Kubiak

Title(s)Professor, Chemistry and Biochemistry
SchoolVc-academic Affairs
Address9500 Gilman Drive #
La Jolla CA 92093
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    1. A Resilient Platform for the Discrete Functionalization of Gold Surfaces Based on N-Heterocyclic Carbene Self-Assembled Monolayers. J Am Chem Soc. 2024 Apr 07. Palasz JM, Long Z, Meng J, Videla PE, Kelly HR, Lian T, Batista VS, Kubiak CP. PMID: 38584354.
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    2. In situ x-ray absorption investigations of a heterogenized molecular catalyst and its interaction with a carbon nanotube support. J Chem Phys. 2023 Feb 21; 158(7):074703. Zoric MR, Chan T, Musgrave CB, Goddard WA, Kubiak CP, Cordones AA. PMID: 36813711.
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    3. Amine Hole Scavengers Facilitate Both Electron and Hole Transfer in a Nanocrystal/Molecular Hybrid Photocatalyst. J Am Chem Soc. 2023 Feb 08; 145(5):3238-3247. Gebre ST, Kiefer LM, Guo F, Yang KR, Miller C, Liu Y, Kubiak CP, Batista VS, Lian T. PMID: 36706437; PMCID: PMC9912264.
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    4. PM-IRRAS and DFT investigation of the surface orientation of new Ir piano-stool complexes attached to Au(111). Dalton Trans. 2022 Nov 29; 51(46):17688-17699. Miller CJ, Brunner FM, Kelly HR, Cheung PL, Torquato NA, Gembicky M, Okuno S, Chan T, Batista VS, Kubiak CP. PMID: 36345597.
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    5. Synthesis, structure and reactivity of μ3-SnH capped trinuclear nickel cluster. Chem Sci. 2022 Oct 05; 13(38):11382-11387. Torquato NA, Palasz JM, Bertrand QC, Brunner FM, Chan T, Gembicky M, Mrse AA, Kubiak CP. PMID: 36320577; PMCID: PMC9533397.
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    6. Sub-Nanometer Mapping of the Interfacial Electric Field Profile Using a Vibrational Stark Shift Ruler. J Am Chem Soc. 2022 08 10; 144(31):14330-14338. Bhattacharyya D, Videla PE, Palasz JM, Tangen I, Meng J, Kubiak CP, Batista VS, Lian T. PMID: 35905473.
      View in: PubMed   Mentions: 4     Fields:    
    7. The electrochemical reduction of a flexible Mn(II) salen-based metal-organic framework. Dalton Trans. 2021 Sep 28; 50(37):12821-12825. Solomon MB, Hua C, Chan B, Church TL, Cohen SM, Kubiak CP, Jolliffe KA, D'Alessandro DM. PMID: 34498023.
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    8. Vibrational Stark shift spectroscopy of catalysts under the influence of electric fields at electrode-solution interfaces. Chem Sci. 2021 Aug 04; 12(30):10131-10149. Bhattacharyya D, Videla PE, Cattaneo M, Batista VS, Lian T, Kubiak CP. PMID: 34377403; PMCID: PMC8336477.
      View in: PubMed   Mentions: 7  
    9. Investigation of Immobilization Effects on Ni(P2N2)2 Electrocatalysts. Inorg Chem. 2020 Dec 07; 59(23):16872-16881. Brunner FM, Neville ML, Kubiak CP. PMID: 33197170.
      View in: PubMed   Mentions: 3     Fields:    
    10. Full Conformational Analyses of the Ultrafast Isomerization in Penta-coordinated Ru(S2C2(CF3)2)(CO)(PPh3)2: One Compound, Two Crystal Structures, Three CO Frequencies, 24 Stereoisomers, and 48 Transition States. Inorg Chem. 2020 Aug 17; 59(16):11757-11769. Tang H, Porter TM, Kubiak CP, Hall MB. PMID: 32799482.
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    11. Electronic Structural Studies of the Ru3(III,II,II) Mixed-Valent State of Oxo-Centered Triruthenium Clusters. Inorg Chem. 2020 Aug 03; 59(15):10532-10539. Palasz JM, Porter TM, Kubiak CP. PMID: 32674565.
      View in: PubMed   Mentions: 1     Fields:    
    12. Re(tBu-bpy)(CO)3Cl Supported on Multi-Walled Carbon Nanotubes Selectively Reduces CO2 in Water. J Am Chem Soc. 2019 10 30; 141(43):17270-17277. Zhanaidarova A, Jones SC, Despagnet-Ayoub E, Pimentel BR, Kubiak CP. PMID: 31580669.
      View in: PubMed   Mentions: 8     Fields:    
    13. Thermodynamic targeting of electrocatalytic CO2 reduction: advantages, limitations, and insights for catalyst design. Dalton Trans. 2019 Nov 14; 48(42):15841-15848. Ostericher AL, Porter TM, Reineke MH, Kubiak CP. PMID: 31580359.
      View in: PubMed   Mentions: 1     Fields:    
    14. Improving Photocatalysis for the Reduction of CO2 through Non-covalent Supramolecular Assembly. J Am Chem Soc. 2019 09 25; 141(38):14961-14965. Cheung PL, Kapper SC, Zeng T, Thompson ME, Kubiak CP. PMID: 31490687.
      View in: PubMed   Mentions: 12     Fields:    
    15. Steric and electronic control of an ultrafast isomerization. Chem Sci. 2019 Sep 14; 10(34):7907-7912. Porter TM, Ostericher AL, Kubiak CP. PMID: 31853348; PMCID: PMC6836746.
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    16. Photooxidative Generation of Dodecaborate-Based Weakly Coordinating Anions. Inorg Chem. 2019 Aug 19; 58(16):10516-10526. Axtell JC, Messina MS, Liu JY, Galaktionova D, Schwan J, Porter TM, Savage MD, Wixtrom AI, Rheingold AL, Kubiak CP, Winkler JR, Gray HB, Král P, Alexandrova AN, Spokoyny AM. PMID: 31247818.
      View in: PubMed   Mentions: 1     Fields:    
    17. Heterogenized Molecular Catalysts: Vibrational Sum-Frequency Spectroscopic, Electrochemical, and Theoretical Investigations. Acc Chem Res. 2019 05 21; 52(5):1289-1300. Ge A, Rudshteyn B, Videla PE, Miller CJ, Kubiak CP, Batista VS, Lian T. PMID: 31056907.
      View in: PubMed   Mentions: 5     Fields:    
    18. The spectroelectrochemical behaviour of redox-active manganese salen complexes. Dalton Trans. 2019 Mar 12; 48(11):3704-3713. Solomon MB, Chan B, Kubiak CP, Jolliffe KA, D'Alessandro DM. PMID: 30801575.
      View in: PubMed   Mentions: 1     Fields:    
    19. Dodecaborane-Based Dopants Designed to Shield Anion Electrostatics Lead to Increased Carrier Mobility in a Doped Conjugated Polymer. Adv Mater. 2019 Mar; 31(11):e1805647. Aubry TJ, Axtell JC, Basile VM, Winchell KJ, Lindemuth JR, Porter TM, Liu JY, Alexandrova AN, Kubiak CP, Tolbert SH, Spokoyny AM, Schwartz BJ. PMID: 30672037.
      View in: PubMed   Mentions: 12     Fields:    
    20. CO2 Reduction Catalysts on Gold Electrode Surfaces Influenced by Large Electric Fields. J Am Chem Soc. 2018 12 19; 140(50):17643-17655. Clark ML, Ge A, Videla PE, Rudshteyn B, Miller CJ, Song J, Batista VS, Lian T, Kubiak CP. PMID: 30468391.
      View in: PubMed   Mentions: 13     Fields:    
    21. Direct observation of the intermediate in an ultrafast isomerization. Chem Sci. 2019 Jan 07; 10(1):113-117. Porter TM, Wang J, Li Y, Xiang B, Salsman C, Miller JS, Xiong W, Kubiak CP. PMID: 30713623; PMCID: PMC6333165.
      View in: PubMed   Mentions: 4  
    22. Stable Mixed-Valent Complexes Formed by Electron Delocalization Across Hydrogen Bonds of Pyrimidinone-Linked Metal Clusters. J Am Chem Soc. 2018 10 10; 140(40):12756-12759. Porter TM, Heim GP, Kubiak CP. PMID: 30265005.
      View in: PubMed   Mentions: 4     Fields:    
    23. Electroactive Co(iii) salen metal complexes and the electrophoretic deposition of their porous organic polymers onto glassy carbon. RSC Adv. 2018 Jul 02; 8(43):24128-24142. Solomon MB, Rawal A, Hook JM, Cohen SM, Kubiak CP, Jolliffe KA, D'Alessandro DM. PMID: 35539197; PMCID: PMC9081851.
      View in: PubMed   Mentions: 4  
    24. Covalent attachment of [Ni(alkynyl-cyclam)]2+ catalysts to glassy carbon electrodes. Chem Commun (Camb). 2018 Apr 19; 54(33):4116-4119. Zhanaidarova A, Moore CE, Gembicky M, Kubiak CP. PMID: 29620782.
      View in: PubMed   Mentions: 4     Fields:    
    25. Chelated [Zn(cyclam)]2+ Lewis acid improves the reactivity of the electrochemical reduction of CO2 by Mn catalysts with bulky bipyridine ligands. Dalton Trans. 2017 Sep 26; 46(37):12413-12416. Zhanaidarova A, Steger H, Reineke MH, Kubiak CP. PMID: 28848980.
      View in: PubMed   Mentions: 2     Fields:    
    26. Effects of electron transfer on the stability of hydrogen bonds. Chem Sci. 2017 Nov 01; 8(11):7324-7329. Porter TM, Heim GP, Kubiak CP. PMID: 29163883; PMCID: PMC5672789.
      View in: PubMed   Mentions: 2  
    27. Charged Macromolecular Rhenium Bipyridine Catalysts with Tunable CO2 Reduction Potentials. Chemistry. 2017 Jun 27; 23(36):8619-8622. Sahu S, Cheung PL, Machan CW, Chabolla SA, Kubiak CP, Gianneschi NC. PMID: 28467613.
      View in: PubMed   Mentions: 7     Fields:    
    28. Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups. Faraday Discuss. 2017 06 02; 198:279-300. Chabolla SA, Machan CW, Yin J, Dellamary EA, Sahu S, Gianneschi NC, Gilson MK, Tezcan FA, Kubiak CP. PMID: 28374024; PMCID: PMC5604230.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    29. Concerted One-Electron Two-Proton Transfer Processes in Models Inspired by the Tyr-His Couple of Photosystem II. ACS Cent Sci. 2017 May 24; 3(5):372-380. Huynh MT, Mora SJ, Villalba M, Tejeda-Ferrari ME, Liddell PA, Cherry BR, Teillout AL, Machan CW, Kubiak CP, Gust D, Moore TA, Hammes-Schiffer S, Moore AL. PMID: 28573198; PMCID: PMC5445534.
      View in: PubMed   Mentions: 24  
    30. Hydrophobic Nanoparticles Reduce the β-Sheet Content of SEVI Amyloid Fibrils and Inhibit SEVI-Enhanced HIV Infectivity. Langmuir. 2017 03 14; 33(10):2596-2602. Sheik DA, Chamberlain JM, Brooks L, Clark M, Kim YH, Leriche G, Kubiak CP, Dewhurst S, Yang J. PMID: 28207276.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    31. Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes. Inorg Chem. 2016 Dec 05; 55(23):12400-12408. Agnew DW, Sampson MD, Moore CE, Rheingold AL, Kubiak CP, Figueroa JS. PMID: 27934438.
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    32. Paired Electrolysis in the Simultaneous Production of Synthetic Intermediates and Substrates. J Am Chem Soc. 2016 11 23; 138(46):15110-15113. Llorente MJ, Nguyen BH, Kubiak CP, Moeller KD. PMID: 27933880.
      View in: PubMed   Mentions: 16     Fields:    
    33. Electrocatalytic reduction of carbon dioxide with Mn(terpyridine) carbonyl complexes. Dalton Trans. 2016 Nov 01; 45(43):17179-17186. Machan CW, Kubiak CP. PMID: 27711804.
      View in: PubMed   Mentions: 6     Fields:    
    34. Interrogating heterobimetallic co-catalytic responses for the electrocatalytic reduction of CO2 using supramolecular assembly. Dalton Trans. 2016 Oct 12; 45(40):15942-15950. Machan CW, Kubiak CP. PMID: 27389806.
      View in: PubMed   Mentions: 2     Fields:    
    35. Tuning Electron Delocalization and Transfer Rates in Mixed-Valent Ru3O Complexes through "Push-Pull" Effects. J Phys Chem A. 2016 Aug 18; 120(32):6309-16. Porter TM, Canzi GC, Chabolla SA, Kubiak CP. PMID: 27472559.
      View in: PubMed   Mentions: 1     Fields:    
    36. Improving the Efficiency and Activity of Electrocatalysts for the Reduction of CO2 through Supramolecular Assembly with Amino Acid-Modified Ligands. J Am Chem Soc. 2016 07 06; 138(26):8184-93. Machan CW, Yin J, Chabolla SA, Gilson MK, Kubiak CP. PMID: 27258781.
      View in: PubMed   Mentions: 8     Fields:    Translation:Cells
    37. A Series of Diamagnetic Pyridine Monoimine Rhenium Complexes with Different Degrees of Metal-to-Ligand Charge Transfer: Correlating (13) C NMR Chemical Shifts with Bond Lengths in Redox-Active Ligands. Chemistry. 2016 Jul 18; 22(30):10638-50. Sieh D, Kubiak CP. PMID: 27319753.
      View in: PubMed   Mentions: 1     Fields:    
    38. Re(I) NHC Complexes for Electrocatalytic Conversion of CO2. Inorg Chem. 2016 Mar 21; 55(6):3136-44. Stanton CJ, Machan CW, Vandezande JE, Jin T, Majetich GF, Schaefer HF, Kubiak CP, Li G, Agarwal J. PMID: 26950549.
      View in: PubMed   Mentions: 5     Fields:    
    39. Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions. Inorg Chem Front. 2016 May 01; 3(5):711-717. Wixtrom AI, Shao Y, Jung D, Machan CW, Kevork SN, Qian EA, Axtell JC, Khan SI, Kubiak CP, Spokoyny AM. PMID: 27885335; PMCID: PMC5117651.
      View in: PubMed   Mentions: 11  
    40. Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3. Inorg Chem. 2016 Mar 21; 55(6):3192-8. Cheung PL, Machan CW, Malkhasian AY, Agarwal J, Kubiak CP. PMID: 26996527.
      View in: PubMed   Mentions: 11     Fields:    
    41. Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials. J Am Chem Soc. 2016 Feb 03; 138(4):1386-93. Sampson MD, Kubiak CP. PMID: 26745814.
      View in: PubMed   Mentions: 30     Fields:    
    42. Electronic effects on the catalytic disproportionation of formic acid to methanol by [Cp*Ir(III)(R-bpy)Cl]Cl complexes. Dalton Trans. 2016 Feb 14; 45(6):2436-9. Sasayama AF, Moore CE, Kubiak CP. PMID: 26786279.
      View in: PubMed   Mentions: 2     Fields:    Translation:Cells
    43. Competing ferro- and antiferromagnetic interactions in a hexagonal bipyramidal nickel thiolate cluster. Dalton Trans. 2016 Feb 14; 45(6):2374-7. Hamaguchi T, Doud MD, Hilgar J, Rinehart JD, Kubiak CP. PMID: 26750262.
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    44. Short-Range Catalyst-Surface Interactions Revealed by Heterodyne Two-Dimensional Sum Frequency Generation Spectroscopy. J Phys Chem Lett. 2015 Nov 05; 6(21):4204-9. Wang J, Clark ML, Li Y, Kaslan CL, Kubiak CP, Xiong W. PMID: 26538035.
      View in: PubMed   Mentions: 5     Fields:    
    45. A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution. Nat Commun. 2015 Sep 14; 6:8304. Hod I, Deria P, Bury W, Mondloch JE, Kung CW, So M, Sampson MD, Peters AW, Kubiak CP, Farha OK, Hupp JT. PMID: 26365764; PMCID: PMC4647847.
      View in: PubMed   Mentions: 21     Fields:    
    46. Correction to "A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate". J Am Chem Soc. 2015 Sep 09; 137(35):11540. Machan CW, Sampson MD, Kubiak CP. PMID: 26312499.
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    47. Electrocatalytic Reduction of Carbon Dioxide by Mn(CN)(2,2'-bipyridine)(CO)3: CN Coordination Alters Mechanism. Inorg Chem. 2015 Sep 08; 54(17):8849-56. Machan CW, Stanton CJ, Vandezande JE, Majetich GF, Schaefer HF, Kubiak CP, Agarwal J. PMID: 26288172.
      View in: PubMed   Mentions: 11     Fields:    
    48. Electron Dynamics and IR Peak Coalescence in Bridged Mixed Valence Dimers Studied by Ultrafast 2D-IR Spectroscopy. J Phys Chem B. 2015 Aug 20; 119(33):10738-49. Zoerb MC, Henderson JS, Glover SD, Lomont JP, Nguyen SC, Hill AD, Kubiak CP, Harris CB. PMID: 26204239.
      View in: PubMed   Mentions: 1     Fields:    
    49. Photocatalytic CO2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal-Organic Framework. Inorg Chem. 2015 Jul 20; 54(14):6821-8. Fei H, Sampson MD, Lee Y, Kubiak CP, Cohen SM. PMID: 26135673.
      View in: PubMed   Mentions: 33     Fields:    
    50. Electrocatalytic Dihydrogen Production by an Earth-Abundant Manganese Bipyridine Catalyst. Inorg Chem. 2015 Jul 20; 54(14):6674-6. Sampson MD, Kubiak CP. PMID: 26125125.
      View in: PubMed   Mentions: 5     Fields:    
    51. A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate. J Am Chem Soc. 2015 Jul 08; 137(26):8564-71. Machan CW, Sampson MD, Kubiak CP. PMID: 26087401.
      View in: PubMed   Mentions: 13     Fields:    
    52. Incorporation of Pendant Bases into Rh(diphosphine)2 Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO2 Hydrogenation Activity of [Rh(P2N2)2](+) Complexes. J Am Chem Soc. 2015 Jul 01; 137(25):8251-60. Lilio AM, Reineke MH, Moore CE, Rheingold AL, Takase MK, Kubiak CP. PMID: 26042557.
      View in: PubMed   Mentions: 5     Fields:    
    53. Reduction of CO2 by Pyridine Monoimine Molybdenum Carbonyl Complexes: Cooperative Metal-Ligand Binding of CO2. Chemistry. 2015 Jun 01; 21(23):8497-503. Sieh D, Lacy DC, Peters JC, Kubiak CP. PMID: 25924730; PMCID: PMC4523092.
      View in: PubMed   Mentions: 7     Fields:    
    54. Synthesis and structural studies of nickel(0) Tetracarbene complexes with the introduction of a new four-coordinate geometric index, τδ. Inorg Chem. 2015 Apr 06; 54(7):3211-7. Reineke MH, Sampson MD, Rheingold AL, Kubiak CP. PMID: 25757047.
      View in: PubMed   Mentions: 11     Fields:    
    55. The homogeneous reduction of CO₂ by [Ni(cyclam)]⁺: increased catalytic rates with the addition of a CO scavenger. J Am Chem Soc. 2015 Mar 18; 137(10):3565-73. Froehlich JD, Kubiak CP. PMID: 25714353.
      View in: PubMed   Mentions: 29     Fields:    
    56. Correction to "Manganese catalysts with bulky bipyridine ligands for the electrocatalytic reduction of carbon dioxide: eliminating dimerization and altering catalysis". J Am Chem Soc. 2015 Mar 18; 137(10):3718. Sampson MD, Nguyen AD, Grice KA, Moore CE, Rheingold AL, Kubiak CP. PMID: 25738737.
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    57. Improved PeT molecules for optically sensing voltage in neurons. J Am Chem Soc. 2015 Feb 11; 137(5):1817-24. Woodford CR, Frady EP, Smith RS, Morey B, Canzi G, Palida SF, Araneda RC, Kristan WB, Kubiak CP, Miller EW, Tsien RY. PMID: 25584688; PMCID: PMC4513930.
      View in: PubMed   Mentions: 47     Fields:    Translation:HumansAnimalsCells
    58. Electron-Transfer Reactions of Electronically Excited Zinc Tetraphenylporphyrin with Multinuclear Ruthenium Complexes. J Phys Chem B. 2015 Jun 18; 119(24):7473-9. Henderson J, Glover SD, Lear BJ, Walker D, Winkler JR, Gray HB, Kubiak CP. PMID: 25494985.
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    59. Mechanistic contrasts between manganese and rhenium bipyridine electrocatalysts for the reduction of carbon dioxide. J Am Chem Soc. 2014 Nov 19; 136(46):16285-98. Riplinger C, Sampson MD, Ritzmann AM, Kubiak CP, Carter EA. PMID: 25327956.
      View in: PubMed   Mentions: 31     Fields:    
    60. Supramolecular assembly promotes the electrocatalytic reduction of carbon dioxide by Re(I) bipyridine catalysts at a lower overpotential. J Am Chem Soc. 2014 Oct 15; 136(41):14598-607. Machan CW, Chabolla SA, Yin J, Gilson MK, Tezcan FA, Kubiak CP. PMID: 25226161.
      View in: PubMed   Mentions: 17     Fields:    Translation:Cells
    61. Photoinduced mixed valency in zinc porphyrin dimer of triruthenium cluster dyads. Inorg Chem. 2014 Oct 20; 53(20):11298-306. Henderson J, Kubiak CP. PMID: 25260187.
      View in: PubMed   Mentions: 2     Fields:    
    62. Synthesis, Spectroscopy, and Electrochemistry of (α-Diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction. Organometallics. 2014 Sep 09; 34(1):3-12. Vollmer MV, Machan CW, Clark ML, Antholine WE, Agarwal J, Schaefer HF, Kubiak CP, Walensky JR. PMID: 25892841; PMCID: PMC4399245.
      View in: PubMed   Mentions: 10  
    63. Manganese catalysts with bulky bipyridine ligands for the electrocatalytic reduction of carbon dioxide: eliminating dimerization and altering catalysis. J Am Chem Soc. 2014 Apr 09; 136(14):5460-71. Sampson MD, Nguyen AD, Grice KA, Moore CE, Rheingold AL, Kubiak CP. PMID: 24641545.
      View in: PubMed   Mentions: 58     Fields:    
    64. On the observation of intervalence charge transfer bands in hydrogen-bonded mixed-valence complexes. J Am Chem Soc. 2014 Feb 05; 136(5):1710-3. Canzi G, Goeltz JC, Henderson JS, Park RE, Maruggi C, Kubiak CP. PMID: 24437710.
      View in: PubMed   Mentions: 3     Fields:    Translation:Cells
    65. Elucidation of the selectivity of proton-dependent electrocatalytic CO2 reduction by fac-Re(bpy)(CO)3Cl. J Am Chem Soc. 2013 Oct 23; 135(42):15823-9. Keith JA, Grice KA, Kubiak CP, Carter EA. PMID: 24053131.
      View in: PubMed   Mentions: 34     Fields:    
    66. Carbon monoxide release catalysed by electron transfer: electrochemical and spectroscopic investigations of [Re(bpy-R)(CO)4](OTf) complexes relevant to CO2 reduction. Dalton Trans. 2013 Jun 21; 42(23):8498-503. Grice KA, Gu NX, Sampson MD, Kubiak CP. PMID: 23629511.
      View in: PubMed   Mentions: 7     Fields:    
    67. The electronic states of rhenium bipyridyl electrocatalysts for CO2 reduction as revealed by X-ray absorption spectroscopy and computational quantum chemistry. Angew Chem Int Ed Engl. 2013 Apr 26; 52(18):4841-4. Benson EE, Sampson MD, Grice KA, Smieja JM, Froehlich JD, Friebel D, Keith JA, Carter EA, Nilsson A, Kubiak CP. PMID: 23526656.
      View in: PubMed   Mentions: 16     Fields:    
    68. Manganese as a substitute for rhenium in CO2 reduction catalysts: the importance of acids. Inorg Chem. 2013 Mar 04; 52(5):2484-91. Smieja JM, Sampson MD, Grice KA, Benson EE, Froehlich JD, Kubiak CP. PMID: 23418912.
      View in: PubMed   Mentions: 47     Fields:    Translation:Cells
    69. Inorganic electron transfer: sharpening a fuzzy border in mixed valency and extending mixed valency across supramolecular systems. Inorg Chem. 2013 May 20; 52(10):5663-76. Kubiak CP. PMID: 23320756.
      View in: PubMed   Mentions: 10     Fields:    
    70. Structural investigations into the deactivation pathway of the CO2 reduction electrocatalyst Re(bpy)(CO)3Cl. Chem Commun (Camb). 2012 Jul 28; 48(59):7374-6. Benson EE, Kubiak CP. PMID: 22714095.
      View in: PubMed   Mentions: 15     Fields:    
    71. Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO. Proc Natl Acad Sci U S A. 2012 Sep 25; 109(39):15646-50. Smieja JM, Benson EE, Kumar B, Grice KA, Seu CS, Miller AJ, Mayer JM, Kubiak CP. PMID: 22652573; PMCID: PMC3465436.
      View in: PubMed   Mentions: 26     Fields:    Translation:Cells
    72. Controlling the rate of electron transfer between a quantum dot and a tri-ruthenium molecular cluster by tuning the chemistry of the interface. Phys Chem Chem Phys. 2012 Oct 28; 14(40):13794-801. Morris-Cohen AJ, Aruda KO, Rasmussen AM, Canzi G, Seideman T, Kubiak CP, Weiss EA. PMID: 22588225.
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    73. Homogeneous CO2 reduction by Ni(cyclam) at a glassy carbon electrode. Inorg Chem. 2012 Apr 02; 51(7):3932-4. Froehlich JD, Kubiak CP. PMID: 22435533.
      View in: PubMed   Mentions: 38     Fields:    
    74. Photochemical and photoelectrochemical reduction of CO2. Annu Rev Phys Chem. 2012; 63:541-69. Kumar B, Llorente M, Froehlich J, Dang T, Sathrum A, Kubiak CP. PMID: 22404587.
      View in: PubMed   Mentions: 73     Fields:    
    75. Photoelectrochemical hydrogen generation by an [FeFe] hydrogenase active site mimic at a p-type silicon/molecular electrocatalyst junction. Chemistry. 2012 Jan 27; 18(5):1295-8. Kumar B, Beyler M, Kubiak CP, Ott S. PMID: 22223148.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    76. Tunable, light-assisted co-generation of CO and H2 from CO2 and H2O by Re(bipy-tbu)(CO)3Cl and p-Si in non-aqueous medium. Chem Commun (Camb). 2012 Jan 07; 48(2):272-4. Kumar B, Smieja JM, Sasayama AF, Kubiak CP. PMID: 22089513.
      View in: PubMed   Mentions: 10     Fields:    
    77. Electrocatalytic oxidation of formate by [Ni(P(R)2N(R')2)2(CH3CN)]2+ complexes. J Am Chem Soc. 2011 Aug 17; 133(32):12767-79. Galan BR, Schöffel J, Linehan JC, Seu C, Appel AM, Roberts JA, Helm ML, Kilgore UJ, Yang JY, DuBois DL, Kubiak CP. PMID: 21692477.
      View in: PubMed   Mentions: 7     Fields:    
    78. Mixed-valence nanoclusters: fast electron transfer in mixed-valence systems with a gold nanoparticle as the bridge. Small. 2011 Jul 18; 7(14):1967-71. Canzi G, Kubiak CP. PMID: 21656906.
      View in: PubMed   Mentions:    Fields:    Translation:Cells
    79. Persistence of the three-state description of mixed valency at the localized-to-delocalized transition. J Am Chem Soc. 2011 Jun 08; 133(22):8721-31. Glover SD, Kubiak CP. PMID: 21561112.
      View in: PubMed   Mentions: 1     Fields:    Translation:Cells
    80. Mixed valency across hydrogen bonds. J Am Chem Soc. 2010 Dec 15; 132(49):17390-2. Goeltz JC, Kubiak CP. PMID: 21087020.
      View in: PubMed   Mentions: 2     Fields:    
    81. Re(bipy-tBu)(CO)3Cl-improved catalytic activity for reduction of carbon dioxide: IR-spectroelectrochemical and mechanistic studies. Inorg Chem. 2010 Oct 18; 49(20):9283-9. Smieja JM, Kubiak CP. PMID: 20845978.
      View in: PubMed   Mentions: 56     Fields:    
    82. Tricarbonylrhenium(I) complexes of highly symmetric hexaazatrinaphthylene ligands (HATN): structural, electrochemical and spectroscopic properties. Dalton Trans. 2010 Dec 07; 39(45):10937-43. Roy S, Kubiak CP. PMID: 20957262.
      View in: PubMed   Mentions: 2     Fields:    
    83. Electronic structural effects in self-exchange reactions. J Phys Chem B. 2010 Nov 18; 114(45):14729-34. Goeltz JC, Benson EE, Kubiak CP. PMID: 20462224.
      View in: PubMed   Mentions: 3     Fields:    
    84. High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes. Nat Chem. 2010 May; 2(5):362-8. Bechlars B, D'Alessandro DM, Jenkins DM, Iavarone AT, Glover SD, Kubiak CP, Long JR. PMID: 20414235.
      View in: PubMed   Mentions: 23     Fields:    Translation:Cells
    85. Synthesis and characterization of 6,6'-(2,4,6-triisopropylphenyl)-2,2'-bipyridine (tripbipy) and its complexes of the late first row transition metals. Inorg Chem. 2010 Feb 15; 49(4):1458-64. Benson EE, Rheingold AL, Kubiak CP. PMID: 20055470.
      View in: PubMed   Mentions: 2     Fields:    
    86. Rates of electron self-exchange reactions between oxo-centered ruthenium clusters are determined by orbital overlap. Inorg Chem. 2009 Jun 01; 48(11):4763-7. Goeltz JC, Hanson CJ, Kubiak CP. PMID: 19371062.
      View in: PubMed   Mentions: 3     Fields:    
    87. Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels. Chem Soc Rev. 2009 Jan; 38(1):89-99. Benson EE, Kubiak CP, Sathrum AJ, Smieja JM. PMID: 19088968.
      View in: PubMed   Mentions: 157     Fields:    
    88. Bis(2,6-dimethyl-phenyl isocyanide-κC)gold(I) tetra-fluorido-borate. Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 06; 64(Pt 10):m1221. Singa TP, Dipasquale AG, Rheingold AL, Kubiak CP. PMID: 21200982; PMCID: PMC2959487.
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    89. Electron transfer at the class II/III borderline of mixed valency: dependence of rates on solvent dynamics and observation of a localized-to-delocalized transition in freezing solvents. Philos Trans A Math Phys Eng Sci. 2008 Jan 13; 366(1862):177-85. Glover SD, Lear BJ, Salsman JC, Londergan CH, Kubiak CP. PMID: 17827120.
      View in: PubMed   Mentions: 1     Fields:    
    90. Solvent dynamical control of ultrafast ground state electron transfer: implications for Class II-III mixed valency. J Am Chem Soc. 2007 Oct 24; 129(42):12772-9. Lear BJ, Glover SD, Salsman JC, Londergan CH, Kubiak CP. PMID: 17902656.
      View in: PubMed   Mentions: 8     Fields:    Translation:Cells
    91. Origins of cooperative noncovalent host-guest chemistry in mixed valence complexes. J Phys Chem B. 2007 Jun 21; 111(24):6766-71. Lear BJ, Kubiak CP. PMID: 17439272.
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    92. Charge gating and electronic delocalization over a denderimeric assembly of trinuclear ruthenium clusters. Inorg Chem. 2006 Sep 04; 45(18):7041-3. Lear BJ, Kubiak CP. PMID: 16933898.
      View in: PubMed   Mentions: 1     Fields:    Translation:Cells
    93. Tuning the electronic communication and rates of intramolecular electron transfer of dimers of trinuclear ruthenium clusters: bridging and ancillary ligand effects. Inorg Chem. 2006 Jan 23; 45(2):547-54. Salsman JC, Ronco S, Londergan CH, Kubiak CP. PMID: 16411689.
      View in: PubMed   Mentions: 4     Fields:    
    94. Intervalence-resonant Raman spectroscopy of strongly coupled mixed-valence cluster dimers of ruthenium. J Phys Chem A. 2005 Oct 13; 109(40):9006-12. Rocha RC, Brown MG, Londergan CH, Salsman JC, Kubiak CP, Shreve AP. PMID: 16332005.
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    95. Infrared spectroscopic determination of the degree of charge transfer in complexes of TCNE with methyl-substituted benzenes. Chem Commun (Camb). 2005 Jul 28; (28):3532-4. Stires JC, McLaurin EJ, Kubiak CP. PMID: 16010314.
      View in: PubMed   Mentions: 2     Fields:    
    96. Mixed valence isomers. J Am Chem Soc. 2005 Mar 02; 127(8):2382-3. Salsman JC, Kubiak CP, Ito T. PMID: 15724979.
      View in: PubMed   Mentions: 2     Fields:    
    97. A trihydroxy tin group that resists oligomerization in the trinuclear nickel cluster [Ni3(mu-P,P'-PPh2CH2PPh2)3(mu3-L)- (mu3-Sn(OH)3)]. Angew Chem Int Ed Engl. 2005 Feb 04; 44(7):1125-1128. Simón-Manso E, Kubiak CP. PMID: 15630680.
      View in: PubMed   Mentions: 2     Fields:    
    98. Observation and dynamics of "charge-transfer isomers". Angew Chem Int Ed Engl. 2004 Mar 05; 43(11):1376-81. Ito T, Imai N, Yamaguchi T, Hamaguchi T, Londergan CH, Kubiak CP. PMID: 15368411.
      View in: PubMed   Mentions: 3     Fields:    
    99. Structural, spectroscopic, and electrochemical studies of the complexes [Ni2(mu-CNR)(CNR)2(mu-dppm)2](n+) (n = 0, 1, 2): unusual examples of nickel(0)-nickel(I) and nickel(0)-nickel(II) mixed valency. Inorg Chem. 2004 Feb 09; 43(3):1071-81. Ferrence GM, Simón-Manso E, Breedlove BK, Meeuwenberg L, Kubiak CP. PMID: 14753830.
      View in: PubMed   Mentions: 1     Fields:    
    100. Electron transfer and dynamic infrared-band coalescence: it looks like dynamic NMR spectroscopy, but a billion times faster. Chemistry. 2003 Dec 15; 9(24):5962-9. Londergan CH, Kubiak CP. PMID: 14679508.
      View in: PubMed   Mentions: 9     Fields:    
    101. Intervalence involvement of bridging ligand vibrations in hexaruthenium mixed-valence clusters probed by resonance Raman spectroscopy. J Am Chem Soc. 2003 Nov 19; 125(46):13912-3. Londergan CH, Rocha RC, Brown MG, Shreve AP, Kubiak CP. PMID: 14611199.
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    102. Hydrocarbation chemistry proceeding from nickel carbenes. J Am Chem Soc. 2003 Aug 13; 125(32):9564-5. Hou H, Gantzel PK, Kubiak CP. PMID: 12904003.
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    103. Infrared activity of symmetric bridging ligand modes in pyrazine-bridged hexaruthenium mixed-valence clusters. Inorg Chem. 2003 Feb 24; 42(4):926-8. Londergan CH, Salsman JC, Ronco S, Kubiak CP. PMID: 12588117.
      View in: PubMed   Mentions: 4     Fields:    
    104. Solvent dynamical control of electron-transfer rates in mixed-valence complexes observed by infrared spectral line shape coalescence. J Am Chem Soc. 2002 Jun 05; 124(22):6236-7. Londergan CH, Salsman JC, Ronco S, Dolkas LM, Kubiak CP. PMID: 12033841.
      View in: PubMed   Mentions: 3     Fields:    
    105. Letter: Isosteganacin. J Am Chem Soc. 1976 Sep 29; 98(20):6389-91. Kende AS, Leibeskind LS, Kubiak C, Eisenberg R. PMID: 965653.
      View in: PubMed   Mentions:    Fields:    Translation:Cells
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