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    Joshua Figueroa

    Address9500 Gilman Drive #0358
    CA La Jolla 92093
    Phone858-822-7478
    vCardDownload vCard

      Collapse Research 
      Collapse Research Activities and Funding
      Tetrahedral Ni Complexes as Acetyl-CoA Synthase Models
      NIH/NIGMS F32GM074410Jun 27, 2005 - Jun 26, 2007
      Role: Principal Investigator

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      Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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      1. Mokhtarzadeh CC, Moore CE, Rheingold AL, Figueroa J. Terminal Iron Carbyne Complexes Derived from Arrested CO2 Reductive Disproportionation. Angew Chem Int Ed Engl. 2017 Aug 28; 56(36):10894-10899. PMID: 28670744.
        View in: PubMed
      2. Agnew DW, Moore CE, Rheingold AL, Figueroa J. Comparison of nucleophilic- and radical-based routes to the formation of manganese-main group element single bonds. Dalton Trans. 2017 May 23; 46(20):6700-6707. PMID: 28484760.
        View in: PubMed
      3. Barnett BR, Neville ML, Moore CE, Rheingold AL, Figueroa J. Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal?Borane Interaction. Angew Chem Int Ed Engl. 2017 Jun 12; 56(25):7195-7199. PMID: 28493627.
        View in: PubMed
      4. Agnew DW, Sampson MD, Moore CE, Rheingold AL, Kubiak CP, Figueroa J. Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes. Inorg Chem. 2016 Dec 05; 55(23):12400-12408. PMID: 27934438.
        View in: PubMed
      5. Barnett BR, Figueroa J. Zero-valent isocyanides of nickel, palladium and platinum as transition metal s-type Lewis bases. Chem Commun (Camb). 2016 Nov 9. PMID: 27826607.
        View in: PubMed
      6. Agnew DW, Gembicky M, Moore CE, Rheingold AL, Figueroa J. Robust, Transformable and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides. J Am Chem Soc. 2016 Nov 1. PMID: 27802031.
        View in: PubMed
      7. Mokhtarzadeh CC, Rheingold AL, Figueroa J. Dinitrogen binding, P4-activation and aza-Büchner ring expansions mediated by an isocyano analogue of the CpCo(CO) fragment. Dalton Trans. 2016 Oct 7; 45(37):14561-9. PMID: 27480670.
        View in: PubMed
      8. Barnett BR, Rheingold AL, Figueroa J. Monomeric Chini-Type Triplatinum Clusters Featuring Dianionic and Radical-Anionic p*-Systems. Angew Chem Int Ed Engl. 2016 Aug 1; 55(32):9253-8. PMID: 27346691.
        View in: PubMed
      9. Smith SJ, Radford RJ, Subramanian RH, Barnett BR, Figueroa J, Tezcan FA. Tunable Helicity, Stability and DNA-Binding Properties of Short Peptides with Hybrid Metal Coordination Motifs. Chem Sci. 2016 Aug 1; 7(8):5453-5461. PMID: 27800151.
        View in: PubMed
      10. Agnew DW, Moore CE, Rheingold AL, Figueroa J. Kinetic Destabilization of Metal-Metal Single Bonds: Isolation of a Pentacoordinate Manganese(0) Monoradical. Angew Chem Int Ed Engl. 2015 Oct 19; 54(43):12673-7. PMID: 26331428.
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      11. Barnett BR, Labios LA, Moore CE, England J, Rheingold AL, Wieghardt K, Figueroa J. Solution Dynamics of Redox Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals. Inorg Chem. 2015 Jul 20; 54(14):7110-21. PMID: 26132375.
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      12. Mokhtarzadeh CC, Margulieux GW, Carpenter AE, Weidemann N, Moore CE, Rheingold AL, Figueroa J. Synthesis and protonation of an encumbered iron tetraisocyanide dianion. Inorg Chem. 2015 Jun 1; 54(11):5579-87. PMID: 25965161.
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      13. Carpenter AE, Mokhtarzadeh CC, Ripatti DS, Havrylyuk I, Kamezawa R, Moore CE, Rheingold AL, Figueroa J. Comparative measure of the electronic influence of highly substituted aryl isocyanides. Inorg Chem. 2015 Mar 16; 54(6):2936-44. PMID: 25700244.
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      14. Barnett BR, Moore CE, Rheingold AL, Figueroa J. Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration. Chem Commun (Camb). 2015 Jan 11; 51(3):541-4. PMID: 25412363.
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      15. Carpenter AE, McNeece AJ, Barnett BR, Estrada AL, Mokhtarzadeh CC, Moore CE, Rheingold AL, Perrin CL, Figueroa J. Direct Observation of ß-Chloride Elimination from an Isolable ß-Chloroalkyl Complex of Square-Planar Nickel. J Am Chem Soc. 2014 Nov 5; 136(44):15481-4. PMID: 25317481.
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      16. Barnett BR, Moore CE, Rheingold AL, Figueroa J. Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal-Borane Interaction Promoted by a Small Bite-Angle LZ Chelate. J Am Chem Soc. 2014 Jul 23; 136(29):10262-5. PMID: 25007258.
        View in: PubMed
      17. Ditri TB, Carpenter AE, Ripatti DS, Moore CE, Rheingold AL, Figueroa J. Chloro- and Trifluoromethyl-Substituted Flanking-Ring m-Terphenyl Isocyanides: ?(6)-Arene Binding to Zero-Valent Molybdenum Centers and Comparison to Alkyl-Substituted Derivatives. Inorg Chem. 2013 Nov 18; 52(22):13216-29. PMID: 24171549.
        View in: PubMed
      18. Carpenter AE, Wen I, Moore CE, Rheingold AL, Figueroa J. [1,1-Co2(CO)6(CNAr?Mes?2)2]: a structural mimic of the elusive D2d isomer of [Co2(CO)8]. Chemistry. 2013 Aug 5; 19(32):10452-7. PMID: 23853071.
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      19. Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa J, Hayton TW. Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 2013 Apr 11; 49(28):2888-90. PMID: 23450127.
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      20. Carpenter AE, Margulieux GW, Millard MD, Moore CE, Weidemann N, Rheingold AL, Figueroa J. Zwitterionic stabilization of a reactive cobalt tris-isocyanide monoanion by cation coordination. Angew Chem Int Ed Engl. 2012 Sep 10; 51(37):9412-6. PMID: 22893574.
        View in: PubMed
      21. Smith PW, Moore CE, Rheingold AL, Figueroa J. Coordination and structural properties of encumbering 6-mesityl-2-picolinate complexes. Dalton Trans. 2012 Jul 14; 41(26):8031-8. PMID: 22549113.
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      22. Ditri TB, Moore CE, Rheingold AL, Figueroa J. Oxidative decarbonylation of m-terphenyl isocyanide complexes of molybdenum and tungsten: precursors to low-coordinate isocyanide complexes. Inorg Chem. 2011 Oct 17; 50(20):10448-59. PMID: 21923128.
        View in: PubMed
      23. Stauber JM, Wadler AL, Moore CE, Rheingold AL, Figueroa J. Coordination properties of 2,5-dimesitylpyridine: an encumbering and versatile ligand for transition-metal chemistry. Inorg Chem. 2011 Aug 1; 50(15):7309-16. PMID: 21710998.
        View in: PubMed
      24. Tomson NC, Labios LA, Weyhermüller T, Figueroa J, Wieghardt K. Redox noninnocence of nitrosoarene ligands in transition metal complexes. Inorg Chem. 2011 Jun 20; 50(12):5763-76. PMID: 21612186.
        View in: PubMed
      25. Stewart MA, Moore CE, Ditri TB, Labios LA, Rheingold AL, Figueroa J. Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides. Chem Commun (Camb). 2011 Jan 7; 47(1):406-8. PMID: 20852769.
        View in: PubMed
      26. Millard MD, Moore CE, Rheingold AL, Figueroa J. Four-coordinate iridium(I) monohydrides: reversible dinitrogen binding, bond activations, and deprotonations. J Am Chem Soc. 2010 Jul 7; 132(26):8921-3. PMID: 20550129.
        View in: PubMed
      27. Radford RJ, Nguyen PC, Ditri TB, Figueroa J, Tezcan FA. Controlled protein dimerization through hybrid coordination motifs. Inorg Chem. 2010 May 3; 49(9):4362-9. PMID: 20377257.
        View in: PubMed
      28. Margulieux GW, Weidemann N, Lacy DC, Moore CE, Rheingold AL, Figueroa J. Isocyano analogues of [Co(CO)(4)](n): a tetraisocyanide of cobalt isolated in three states of charge. J Am Chem Soc. 2010 Apr 14; 132(14):5033-5. PMID: 20302355.
        View in: PubMed
      29. Pang K, Figueroa J, Tonks IA, Sattler W, Parkin G. 2-Mercapto-1-t-butylimidazolyl as a Bridging Ligand: Synthesis and Structural Characterization of Nickel and Palladium Paddlewheel Complexes. Inorganica Chim Acta. 2009 Sep 15; 362(12):4609-4615. PMID: 20161357.
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      30. Ditri TB, Fox BJ, Moore CE, Rheingold AL, Figueroa J. Effective control of ligation and geometric isomerism: direct comparison of steric properties associated with bis-mesityl and bis-diisopropylphenyl m-terphenyl isocyanides. Inorg Chem. 2009 Sep 7; 48(17):8362-75. PMID: 19653646.
        View in: PubMed
      31. Labios LA, Millard MD, Rheingold AL, Figueroa J. Bond activation, substrate addition and catalysis by an isolable two-coordinate Pd(0) bis-isocyanide monomer. J Am Chem Soc. 2009 Aug 19; 131(32):11318-9. PMID: 19630396.
        View in: PubMed
      32. Fox BJ, Millard MD, DiPasquale AG, Rheingold AL, Figueroa J. Thallium(I) as a coordination site protection agent: preparation of an isolable zero-valent nickel tris-isocyanide. Angew Chem Int Ed Engl. 2009; 48(19):3473-7. PMID: 19173272.
        View in: PubMed
      33. Fox BJ, Sun QY, DiPasquale AG, Fox AR, Rheingold AL, Figueroa J. Solution behavior and structural properties of Cu(I) complexes featuring m-terphenyl isocyanides. Inorg Chem. 2008 Oct 6; 47(19):9010-20. PMID: 18759427.
        View in: PubMed
      34. Figueroa J, Yurkerwich K, Melnick J, Buccella D, Parkin G. Applications of bis(1-R-imidazol-2-yl)disulfides and diselenides as ligands for main-group and transition metals: kappa2-(N,N) coordination, S-S bond cleavage, and S-S/E-E (E = S, Se) bond metathesis reactions. Inorg Chem. 2007 Oct 29; 46(22):9234-44. PMID: 17900186.
        View in: PubMed
      35. Figueroa J, Melnick JG, Parkin G. Reactivity of the metal-->BX3 dative sigma-bond: 1,2-addition reactions of the Fe-->BX3 moiety of the ferraboratrane complex [kappa4-B(mimBu t)3]Fe(CO)2. Inorg Chem. 2006 Sep 4; 45(18):7056-8. PMID: 16933903.
        View in: PubMed
      36. Piro NA, Figueroa J, McKellar JT, Cummins CC. Triple-bond reactivity of diphosphorus molecules. Science. 2006 Sep 1; 313(5791):1276-9. PMID: 16946068.
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      37. Zhu G, Janak KE, Figueroa J, Parkin G. Oxidative addition of dihydrogen to (eta6-arene)Mo(PMe3)3 complexes: origin of the naphthalene and anthracene effects. J Am Chem Soc. 2006 Apr 26; 128(16):5452-61. PMID: 16620117.
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      38. Figueroa J, Cummins CC. A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer. Dalton Trans. 2006 May 14; (18):2161-8. PMID: 16673028.
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      39. Figueroa J, Piro NA, Clough CR, Cummins CC. A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling. J Am Chem Soc. 2006 Jan 25; 128(3):940-50. PMID: 16417385.
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      40. Figueroa J, Cummins CC. Triatomic EP2 triangles (E=Ge, Sn, Pb) as mu2:eta3,eta3-bridging ligands. Angew Chem Int Ed Engl. 2005 Jul 18; 44(29):4592-6. PMID: 15991199.
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      41. Mendiratta A, Figueroa J, Cummins CC. Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate. Chem Commun (Camb). 2005 Jul 21; (27):3403-5. PMID: 15997278.
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      42. Murahashi T, Clough CR, Figueroa J, Cummins CC. A ligand composed of dinitrogen and methyldiphenylphosphane in a cationic molybdenum complex. Angew Chem Int Ed Engl. 2005 Apr 22; 44(17):2560-3. PMID: 15782376.
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      43. Figueroa J, Cummins CC. Phosphaalkynes from acid chlorides via P for O(Cl) metathesis: a recyclable niobium phosphide (P(3-)) reagent that effects C-P triple-bond formation. J Am Chem Soc. 2004 Nov 3; 126(43):13916-7. PMID: 15506740.
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      44. Soo HS, Figueroa J, Cummins CC. A homoleptic molybdenum(IV) enolate complex: synthesis, molecular and electronic structure, and NCN group transfer to form a terminal cyanoimide of molybdenum(VI). J Am Chem Soc. 2004 Sep 15; 126(36):11370-6. PMID: 15355120.
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      45. Clough CR, Greco JB, Figueroa J, Diaconescu PL, Davis WM, Cummins CC. Organic nitriles from acid chlorides: an isovalent N for (O)CL exchange reaction mediated by a tungsten nitride complex. J Am Chem Soc. 2004 Jun 30; 126(25):7742-3. PMID: 15212498.
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      46. Figueroa J, Cummins CC. Diorganophosphanylphosphinidenes as complexed ligands: synthesis via an anionic terminal phosphide of niobium. Angew Chem Int Ed Engl. 2004 Feb 13; 43(8):984-8. PMID: 14966886.
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      47. Stephens FH, Figueroa J, Diaconescu PL, Cummins CC. Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex. J Am Chem Soc. 2003 Aug 6; 125(31):9264-5. PMID: 12889934.
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      48. Figueroa J, Cummins CC. The niobaziridine-hydride functional group: synthesis and divergent reactivity. J Am Chem Soc. 2003 Apr 9; 125(14):4020-1. PMID: 12670202.
        View in: PubMed
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