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Joshua Figueroa

TitleResearcher
InstitutionUniversity of California San Diego
DepartmentChemistry and Biochemistry
Address9500 Gilman Drive #0358
La Jolla CA 92093
Phone858-822-7478
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    Tetrahedral Ni Complexes as Acetyl-CoA Synthase Models
    NIH/NIGMS F32GM074410Jun 27, 2005 - Jun 26, 2007
    Role: Principal Investigator

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    Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help.
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    1. Mokhtarzadeh CC, Moore CE, Rheingold AL, Figueroa J. A Highly-Reduced Cobalt Terminal Carbyne: Divergent Metal- and a-Carbon-Centered Reactivity. J Am Chem Soc. 2018 Jun 15. PMID: 29906387.
      View in: PubMed
    2. Drance MJ, Mokhtarzadeh C, Melaimi M, Agnew DW, Moore C, Rheingold AL, Figueroa J. Controlled Expansion of a Strong-Field Iron-Nitride Cluster: Multi-Site Ligand Substitution as a Strategy for Activating Interstitial Nitride Nucleophilicity. Angew Chem Int Ed Engl. 2018 May 02. PMID: 29719103.
      View in: PubMed
    3. Mandla KA, Moore CE, Rheingold AL, Figueroa J. Regioselective Formation of (E)-ß-Vinylstannanes with a Topologically Controlled Molybdenum-Based Alkyne Hydrostannation Catalyst. Angew Chem Int Ed Engl. 2018 Apr 16. PMID: 29659097.
      View in: PubMed
    4. Wang L, Agnew DW, Yu X, Figueroa J, Cohen SM. A Metal-Organic Framework with Exceptional Activity for C-H Bond Amination. Angew Chem Int Ed Engl. 2018 Jan 08; 57(2):511-515. PMID: 29160961.
      View in: PubMed
    5. Agnew DW, DiMucci IM, Arroyave A, Gembicky M, Moore CE, MacMillan SN, Rheingold AL, Lancaster KM, Figueroa J. Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. J Am Chem Soc. 2017 Dec 06; 139(48):17257-17260. PMID: 29131949.
      View in: PubMed
    6. Mokhtarzadeh CC, Moore CE, Rheingold AL, Figueroa J. Terminal Iron Carbyne Complexes Derived from Arrested CO2 Reductive Disproportionation. Angew Chem Int Ed Engl. 2017 Aug 28; 56(36):10894-10899. PMID: 28670744.
      View in: PubMed
    7. Agnew DW, Moore CE, Rheingold AL, Figueroa J. Comparison of nucleophilic- and radical-based routes to the formation of manganese-main group element single bonds. Dalton Trans. 2017 May 23; 46(20):6700-6707. PMID: 28484760.
      View in: PubMed
    8. Barnett BR, Neville ML, Moore CE, Rheingold AL, Figueroa J. Oxidative-Insertion Reactivity Across a Geometrically Constrained Metal?Borane Interaction. Angew Chem Int Ed Engl. 2017 Jun 12; 56(25):7195-7199. PMID: 28493627.
      View in: PubMed
    9. Barnett BR, Figueroa J. Zero-valent isocyanides of nickel, palladium and platinum as transition metal s-type Lewis bases. Chem Commun (Camb). 2016 Nov 24; 52(96):13829-13839. PMID: 27826607.
      View in: PubMed
    10. Agnew DW, Sampson MD, Moore CE, Rheingold AL, Kubiak CP, Figueroa J. Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes. Inorg Chem. 2016 Dec 05; 55(23):12400-12408. PMID: 27934438.
      View in: PubMed
    11. Agnew DW, Gembicky M, Moore CE, Rheingold AL, Figueroa J. Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m-Terphenyl Isocyanides. J Am Chem Soc. 2016 11 23; 138(46):15138-15141. PMID: 27802031.
      View in: PubMed
    12. Mokhtarzadeh CC, Rheingold AL, Figueroa J. Dinitrogen binding, P4-activation and aza-Büchner ring expansions mediated by an isocyano analogue of the CpCo(CO) fragment. Dalton Trans. 2016 Oct 07; 45(37):14561-9. PMID: 27480670.
      View in: PubMed
    13. Barnett BR, Rheingold AL, Figueroa J. Monomeric Chini-Type Triplatinum Clusters Featuring Dianionic and Radical-Anionic p*-Systems. Angew Chem Int Ed Engl. 2016 Aug 01; 55(32):9253-8. PMID: 27346691.
      View in: PubMed
    14. Smith SJ, Radford RJ, Subramanian RH, Barnett BR, Figueroa J, Tezcan FA. Tunable Helicity, Stability and DNA-Binding Properties of Short Peptides with Hybrid Metal Coordination Motifs. Chem Sci. 2016 Aug 01; 7(8):5453-5461. PMID: 27800151.
      View in: PubMed
    15. Li Y, Huang Y, Wang Z, Carniato F, Xie Y, Patterson JP, Thompson MP, Andolina CM, Ditri TB, Millstone JE, Figueroa J, Rinehart JD, Scadeng M, Botta M, Gianneschi NC. Polycatechol Nanoparticle MRI Contrast Agents. Small. 2016 Feb 03; 12(5):668-77. PMID: 26681255.
      View in: PubMed
    16. Barnett BR, Moore CE, Chandrasekaran P, Sproules S, Rheingold AL, DeBeer S, Figueroa J. Metal-only Lewis pairs between group 10 metals and Tl(i) or Ag(i): insights into the electronic consequences of Z-type ligand binding. Chem Sci. 2015 Dec 01; 6(12):7169-7178. PMID: 29861954.
      View in: PubMed
    17. Agnew DW, Moore CE, Rheingold AL, Figueroa J. Kinetic Destabilization of Metal-Metal Single Bonds: Isolation of a Pentacoordinate Manganese(0) Monoradical. Angew Chem Int Ed Engl. 2015 Oct 19; 54(43):12673-7. PMID: 26331428.
      View in: PubMed
    18. Barnett BR, Labios LA, Moore CE, England J, Rheingold AL, Wieghardt K, Figueroa J. Solution Dynamics of Redox Noninnocent Nitrosoarene Ligands: Mapping the Electronic Criteria for the Formation of Persistent Metal-Coordinated Nitroxide Radicals. Inorg Chem. 2015 Jul 20; 54(14):7110-21. PMID: 26132375.
      View in: PubMed
    19. Mokhtarzadeh CC, Margulieux GW, Carpenter AE, Weidemann N, Moore CE, Rheingold AL, Figueroa J. Synthesis and protonation of an encumbered iron tetraisocyanide dianion. Inorg Chem. 2015 Jun 01; 54(11):5579-87. PMID: 25965161.
      View in: PubMed
    20. Carpenter AE, Mokhtarzadeh CC, Ripatti DS, Havrylyuk I, Kamezawa R, Moore CE, Rheingold AL, Figueroa J. Comparative measure of the electronic influence of highly substituted aryl isocyanides. Inorg Chem. 2015 Mar 16; 54(6):2936-44. PMID: 25700244.
      View in: PubMed
    21. Barnett BR, Moore CE, Rheingold AL, Figueroa J. Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration. Chem Commun (Camb). 2015 Jan 11; 51(3):541-4. PMID: 25412363.
      View in: PubMed
    22. Carpenter AE, McNeece AJ, Barnett BR, Estrada AL, Mokhtarzadeh CC, Moore CE, Rheingold AL, Perrin CL, Figueroa J. Direct observation of ß-chloride elimination from an isolable ß-chloroalkyl complex of square-planar nickel. J Am Chem Soc. 2014 Nov 05; 136(44):15481-4. PMID: 25317481.
      View in: PubMed
    23. Barnett BR, Moore CE, Rheingold AL, Figueroa J. Cooperative transition metal/Lewis acid bond-activation reactions by a bidentate (boryl)iminomethane complex: a significant metal-borane interaction promoted by a small bite-angle LZ chelate. J Am Chem Soc. 2014 Jul 23; 136(29):10262-5. PMID: 25007258.
      View in: PubMed
    24. Ditri TB, Carpenter AE, Ripatti DS, Moore CE, Rheingold AL, Figueroa J. Chloro- and trifluoromethyl-substituted flanking-ring m-terphenyl isocyanides: ?6-arene binding to zero-valent molybdenum centers and comparison to alkyl-substituted derivatives. Inorg Chem. 2013 Nov 18; 52(22):13216-29. PMID: 24171549.
      View in: PubMed
    25. Carpenter AE, Wen I, Moore CE, Rheingold AL, Figueroa J. [1,1-Co2(CO)6(CNAr?Mes?2)2]: a structural mimic of the elusive D2d isomer of [Co2(CO)8]. Chemistry. 2013 Aug 05; 19(32):10452-7. PMID: 23853071.
      View in: PubMed
    26. Lewis RA, George SP, Chapovetsky A, Wu G, Figueroa J, Hayton TW. Synthesis of a cobalt(IV) ketimide with a squashed tetrahedral geometry. Chem Commun (Camb). 2013 Apr 11; 49(28):2888-90. PMID: 23450127.
      View in: PubMed
    27. Carpenter AE, Margulieux GW, Millard MD, Moore CE, Weidemann N, Rheingold AL, Figueroa J. Zwitterionic stabilization of a reactive cobalt tris-isocyanide monoanion by cation coordination. Angew Chem Int Ed Engl. 2012 Sep 10; 51(37):9412-6. PMID: 22893574.
      View in: PubMed
    28. Smith PW, Moore CE, Rheingold AL, Figueroa J. Coordination and structural properties of encumbering 6-mesityl-2-picolinate complexes. Dalton Trans. 2012 Jul 14; 41(26):8031-8. PMID: 22549113.
      View in: PubMed
    29. Ditri TB, Moore CE, Rheingold AL, Figueroa J. Oxidative decarbonylation of m-terphenyl isocyanide complexes of molybdenum and tungsten: precursors to low-coordinate isocyanide complexes. Inorg Chem. 2011 Oct 17; 50(20):10448-59. PMID: 21923128.
      View in: PubMed
    30. Stauber JM, Wadler AL, Moore CE, Rheingold AL, Figueroa J. Coordination properties of 2,5-dimesitylpyridine: an encumbering and versatile ligand for transition-metal chemistry. Inorg Chem. 2011 Aug 01; 50(15):7309-16. PMID: 21710998.
      View in: PubMed
    31. Tomson NC, Labios LA, Weyhermüller T, Figueroa J, Wieghardt K. Redox noninnocence of nitrosoarene ligands in transition metal complexes. Inorg Chem. 2011 Jun 20; 50(12):5763-76. PMID: 21612186.
      View in: PubMed
    32. Stewart MA, Moore CE, Ditri TB, Labios LA, Rheingold AL, Figueroa J. Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides. Chem Commun (Camb). 2011 Jan 07; 47(1):406-8. PMID: 20852769.
      View in: PubMed
    33. Millard MD, Moore CE, Rheingold AL, Figueroa J. Four-coordinate iridium(I) monohydrides: reversible dinitrogen binding, bond activations, and deprotonations. J Am Chem Soc. 2010 Jul 07; 132(26):8921-3. PMID: 20550129.
      View in: PubMed
    34. Radford RJ, Nguyen PC, Ditri TB, Figueroa J, Tezcan FA. Controlled protein dimerization through hybrid coordination motifs. Inorg Chem. 2010 May 03; 49(9):4362-9. PMID: 20377257; PMCID: PMC2896031.
    35. Margulieux GW, Weidemann N, Lacy DC, Moore CE, Rheingold AL, Figueroa J. Isocyano analogues of [Co(CO)(4)](n): a tetraisocyanide of cobalt isolated in three states of charge. J Am Chem Soc. 2010 Apr 14; 132(14):5033-5. PMID: 20302355.
      View in: PubMed
    36. Pang K, Figueroa J, Tonks IA, Sattler W, Parkin G. 2-Mercapto-1-t-butylimidazolyl as a Bridging Ligand: Synthesis and Structural Characterization of Nickel and Palladium Paddlewheel Complexes. Inorganica Chim Acta. 2009 Sep 15; 362(12):4609-4615. PMID: 20161357.
      View in: PubMed
    37. Ditri TB, Fox BJ, Moore CE, Rheingold AL, Figueroa J. Effective control of ligation and geometric isomerism: direct comparison of steric properties associated with bis-mesityl and bis-diisopropylphenyl m-terphenyl isocyanides. Inorg Chem. 2009 Sep 07; 48(17):8362-75. PMID: 19653646.
      View in: PubMed
    38. Labios LA, Millard MD, Rheingold AL, Figueroa J. Bond activation, substrate addition and catalysis by an isolable two-coordinate Pd(0) bis-isocyanide monomer. J Am Chem Soc. 2009 Aug 19; 131(32):11318-9. PMID: 19630396.
      View in: PubMed
    39. Fox BJ, Millard MD, DiPasquale AG, Rheingold AL, Figueroa J. Thallium(I) as a coordination site protection agent: preparation of an isolable zero-valent nickel tris-isocyanide. Angew Chem Int Ed Engl. 2009; 48(19):3473-7. PMID: 19173272.
      View in: PubMed
    40. Fox BJ, Sun QY, DiPasquale AG, Fox AR, Rheingold AL, Figueroa J. Solution behavior and structural properties of Cu(I) complexes featuring m-terphenyl isocyanides. Inorg Chem. 2008 Oct 06; 47(19):9010-20. PMID: 18759427.
      View in: PubMed
    41. Figueroa J, Yurkerwich K, Melnick J, Buccella D, Parkin G. Applications of bis(1-R-imidazol-2-yl)disulfides and diselenides as ligands for main-group and transition metals: kappa2-(N,N) coordination, S-S bond cleavage, and S-S/E-E (E = S, Se) bond metathesis reactions. Inorg Chem. 2007 Oct 29; 46(22):9234-44. PMID: 17900186; PMCID: PMC2440639.
    42. Figueroa J, Melnick JG, Parkin G. Reactivity of the metal-->BX3 dative sigma-bond: 1,2-addition reactions of the Fe-->BX3 moiety of the ferraboratrane complex [kappa4-B(mimBu t)3]Fe(CO)2. Inorg Chem. 2006 Sep 04; 45(18):7056-8. PMID: 16933903.
      View in: PubMed
    43. Piro NA, Figueroa J, McKellar JT, Cummins CC. Triple-bond reactivity of diphosphorus molecules. Science. 2006 Sep 01; 313(5791):1276-9. PMID: 16946068.
      View in: PubMed
    44. Zhu G, Janak KE, Figueroa J, Parkin G. Oxidative addition of dihydrogen to (eta6-arene)Mo(PMe3)3 complexes: origin of the naphthalene and anthracene effects. J Am Chem Soc. 2006 Apr 26; 128(16):5452-61. PMID: 16620117.
      View in: PubMed
    45. Figueroa J, Cummins CC. A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer. Dalton Trans. 2006 May 14; (18):2161-8. PMID: 16673028.
      View in: PubMed
    46. Figueroa J, Piro NA, Clough CR, Cummins CC. A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling. J Am Chem Soc. 2006 Jan 25; 128(3):940-50. PMID: 16417385.
      View in: PubMed
    47. Figueroa J, Cummins CC. Triatomic EP2 triangles (E=Ge, Sn, Pb) as mu2:eta3,eta3-bridging ligands. Angew Chem Int Ed Engl. 2005 Jul 18; 44(29):4592-6. PMID: 15991199.
      View in: PubMed
    48. Mendiratta A, Figueroa J, Cummins CC. Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate. Chem Commun (Camb). 2005 Jul 21; (27):3403-5. PMID: 15997278.
      View in: PubMed
    49. Murahashi T, Clough CR, Figueroa J, Cummins CC. A ligand composed of dinitrogen and methyldiphenylphosphane in a cationic molybdenum complex. Angew Chem Int Ed Engl. 2005 Apr 22; 44(17):2560-3. PMID: 15782376.
      View in: PubMed
    50. Figueroa J, Cummins CC. Phosphaalkynes from acid chlorides via P for O(Cl) metathesis: a recyclable niobium phosphide (P(3-)) reagent that effects C-P triple-bond formation. J Am Chem Soc. 2004 Nov 03; 126(43):13916-7. PMID: 15506740.
      View in: PubMed
    51. Soo HS, Figueroa J, Cummins CC. A homoleptic molybdenum(IV) enolate complex: synthesis, molecular and electronic structure, and NCN group transfer to form a terminal cyanoimide of molybdenum(VI). J Am Chem Soc. 2004 Sep 15; 126(36):11370-6. PMID: 15355120.
      View in: PubMed
    52. Clough CR, Greco JB, Figueroa J, Diaconescu PL, Davis WM, Cummins CC. Organic nitriles from acid chlorides: an isovalent N for (O)CL exchange reaction mediated by a tungsten nitride complex. J Am Chem Soc. 2004 Jun 30; 126(25):7742-3. PMID: 15212498.
      View in: PubMed
    53. Figueroa J, Cummins CC. Diorganophosphanylphosphinidenes as complexed ligands: synthesis via an anionic terminal phosphide of niobium. Angew Chem Int Ed Engl. 2004 Feb 13; 43(8):984-8. PMID: 14966886.
      View in: PubMed
    54. Stephens FH, Figueroa J, Diaconescu PL, Cummins CC. Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex. J Am Chem Soc. 2003 Aug 06; 125(31):9264-5. PMID: 12889934.
      View in: PubMed
    55. Figueroa J, Cummins CC. The niobaziridine-hydride functional group: synthesis and divergent reactivity. J Am Chem Soc. 2003 Apr 09; 125(14):4020-1. PMID: 12670202.
      View in: PubMed
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