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Alexander Trifonov

Title(s)Postdoctoral Scholar, Nanoengineering
SchoolVc-academic Affairs
Address9500 Gilman Drive #
La Jolla CA 92093
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    1. Ln(II) amido complexes coordinated by ring-expanded N-heterocyclic carbenes - promising catalysts for olefin hydrophosphination. Chem Commun (Camb). 2020 Sep 24. Lapshin IV, Cherkasov AV, Asachenko AF, Trifonov AA. PMID: 32969455.
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    2. Single-molecule magnet behavior in heterolopetic Dy3+-chloro-diazabutadiene complexes: influence of the nuclearity and ligand redox state. Dalton Trans. 2020 Sep 01; 49(34):11890-11901. Long J, Tolpygin AO, Cherkasov AV, Lyssenko KA, Guari Y, Larionova J, Trifonov AA. PMID: 32808617.
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    3. Synthesis, structure, magnetic and photoluminescent properties of dysprosium(III) Schiff Base single-molecule magnets: investigation of the relaxation of the magnetization. Chem Asian J. 2020 Jul 07. Long J, Basalov IV, Lyssenko KA, Cherkasov AV, Mamontova E, Guari Y, Larionova J, Trifonov AA. PMID: 32633054.
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    4. Single-molecule magnet behavior in luminescent carbazolyl Dy(iii) octahedral complexes with a quasi linear N--Dy-N- angle. Dalton Trans. 2020 Apr 01; 49(13):4039-4043. Long J, Selikhov AN, Mamontova E, Lyssenko KA, Guari Y, Larionova J, Trifonov AA. PMID: 32154817.
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    5. Synthesis, structure and magnetic properties of a series of Ln(iii) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization. Dalton Trans. 2019 Aug 28; 48(32):12018-12022. Long J, Skvortsov GG, Cherkasov AV, Lyssenko KA, Poddel'sky AI, Guari Y, Larionova J, Trifonov AA. PMID: 31373595.
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    6. Alternative (?1-N:?6-arene vs.?2-N,N) coordination of a sterically demanding amidinate ligand: are size and electronic structure of the Ln ion decisive factors? Dalton Trans. 2019 Jun 21; 48(23):8317-8326. Tolpygin AO, Shavyrin AS, Cherkasov AV, Fukin GK, Del Rosal I, Maron L, Trifonov AA. PMID: 31111858.
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    7. Correction: Amido Ca(ii) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes. Dalton Trans. 2019 04 23; 48(17):5842. Forosenko NV, Basalov IV, Cherkasov AV, Fukin GK, Shubina ES, Trifonov AA. PMID: 30973563.
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    8. Thermally Stable Ln(II) and Ca(II) Bis(benzhydryl) Complexes: Excellent Precatalysts for Intermolecular Hydrophosphination of C-C Multiple Bonds. Inorg Chem. 2019 Apr 15; 58(8):5325-5334. Selikhov AN, Plankin GS, Cherkasov AV, Shavyrin AS, Louyriac E, Maron L, Trifonov AA. PMID: 30933487.
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    9. Single-molecule magnet behaviour in a Dy(iii) pentagonal bipyramidal complex with a quasi-linear Cl-Dy-Cl sequence. Dalton Trans. 2018 Dec 18; 48(1):35-39. Long J, Selikhov AN, Mamontova E, Lyssenko KA, Guari Y, Larionova J, Trifonov AA. PMID: 30444521.
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    10. CaII , YbII and SmII Bis(Amido) Complexes Coordinated by NHC Ligands: Efficient Catalysts for Highly Regio- and Chemoselective Consecutive Hydrophosphinations with PH3. Chemistry. 2019 Jan 07; 25(2):459-463. Lapshin IV, Basalov IV, Lyssenko KA, Cherkasov AV, Trifonov AA. PMID: 30411413.
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    11. Dysprosium Single-Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change. Chemistry. 2019 Jan 07; 25(2):474-478. Long J, Basalov IV, Forosenko NV, Lyssenko KA, Mamontova E, Cherkasov AV, Damjanovic M, Chibotaru LF, Guari Y, Larionova J, Trifonov AA. PMID: 30376601.
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    12. Amido Ca(ii) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes. Dalton Trans. 2018 Sep 18; 47(36):12570-12581. Forosenko NV, Basalov IV, Cherkasov AV, Fukin GK, Shubina ES, Trifonov AA. PMID: 29877538.
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    13. Synthesis, structure and magnetic properties of tris(pyrazolyl)methane lanthanide complexes: effect of the anion on the slow relaxation of magnetization. Dalton Trans. 2018 Apr 17; 47(15):5153-5156. Long J, Lyubov DM, Mahrova TV, Cherkasov AV, Fukin GK, Guari Y, Larionova J, Trifonov AA. PMID: 29557466.
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    14. Amido Ca and Yb(II) Complexes Coordinated by Amidine-Amidopyridinate Ligands for Catalytic Intermolecular Olefin Hydrophosphination. Inorg Chem. 2018 Mar 05; 57(5):2942-2952. Lapshin IV, Yurova OS, Basalov IV, Rad'kov VY, Musina EI, Cherkasov AV, Fukin GK, Karasik AA, Trifonov AA. PMID: 29443529.
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    15. Steric control in the metal-ligand electron transfer of iminopyridine-ytterbocene complexes. Dalton Trans. 2018 Jan 30; 47(5):1566-1576. Trifonov AA, Mahrova TV, Luconi L, Giambastiani G, Lyubov DM, Cherkasov AV, Sorace L, Louyriac E, Maron L, Lyssenko KA. PMID: 29322131.
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    16. Rare-earth metal-mediated PhC[triple bond, length as m-dash]N insertion into N,N-bis(trimethylsilyl)naphthalene-1,8-diamido dianion - a synthetic approach to complexes coordinated by ansa-bridged amido-amidinato ligand. Dalton Trans. 2018 Jan 02; 47(2):438-451. Lyubov DM, Cherkasov AV, Fukin GK, Lyssenko KA, Rychagova EA, Ketkov SY, Trifonov AA. PMID: 29226296.
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    17. An organolanthanide(iii) single-molecule magnet with an axial crystal-field: influence of the Raman process over the slow relaxation. Chem Commun (Camb). 2017 Apr 25; 53(34):4706-4709. Long J, Shestakov BG, Liu D, Chibotaru LF, Guari Y, Cherkasov AV, Fukin GK, Trifonov AA, Larionova J. PMID: 28401213.
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    18. Engineered Au Core@Prussian Blue Analogous Shell Nanoheterostructures: Their Magnetic and Optical Properties. Chemistry. 2017 Jun 01; 23(31):7483-7496. Maurin-Pasturel G, Long J, Palacios MA, Guérin C, Charnay C, Willinger MG, Trifonov AA, Larionova J, Guari Y. PMID: 28186343.
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    19. Half-Sandwich Alkyl, Amido, and Iodo Samarium(II) Complexes: Non-Conventional Sterically Governed Oxidation of (tBu4 Carb)2 Sm. Chemistry. 2017 Jan 26; 23(6):1436-1443. Selikhov AN, Mahrova TV, Cherkasov AV, Fukin GK, Maron L, Trifonov AA. PMID: 27865012.
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    20. Bis(alkyl) rare-earth complexes coordinated by bulky tridentate amidinate ligands bearing pendant Ph2P[double bond, length as m-dash]O and Ph2P[double bond, length as m-dash]NR groups. Synthesis, structures and catalytic activity in stereospecific isoprene polymerization. Dalton Trans. 2016 Nov 22; 45(46):18572-18584. Rad'kova NY, Tolpygin AO, Rad'kov VY, Khamaletdinova NM, Cherkasov AV, Fukin GK, Trifonov AA. PMID: 27819095.
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    21. Tandem C(sp(2))-OMe Activation/C(sp(2))-C(sp(2)) Coupling in Early Transition-Metal Complexes: Aromatic C-O Activation beyond Late Transition Metals. J Am Chem Soc. 2016 Apr 06; 138(13):4350-3. Radkov V, Roisnel T, Trifonov A, Carpentier JF, Kirillov E. PMID: 26999638.
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    22. Amido Ln(II) Complexes Coordinated by Bi- and Tridentate Amidinate Ligands: Nonconventional Coordination Modes of Amidinate Ligands and Catalytic Activity in Intermolecular Hydrophosphination of Styrenes and Tolane. Inorg Chem. 2016 Feb 01; 55(3):1236-44. Basalov IV, Yurova OS, Cherkasov AV, Fukin GK, Trifonov AA. PMID: 26751850.
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    23. Bis(alkyl) rare-earth complexes supported by a new tridentate amidinate ligand with a pendant diphenylphosphine oxide group. Synthesis, structures and catalytic activity in isoprene polymerization. Dalton Trans. 2015 Oct 07; 44(37):16465-74. Tolpygin AO, Glukhova TA, Cherkasov AV, Fukin GK, Aleksanyan DV, Cui D, Trifonov AA. PMID: 26314896.
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    24. An Organoytterbium(III) Complex Exhibiting Field-Induced Single-Ion-Magnet Behavior. Inorg Chem. 2015 Aug 17; 54(16):7667-9. Trifonov AA, Shestakov B, Long J, Lyssenko K, Guari Y, Larionova J. PMID: 26218528.
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    25. Neutral binuclear rare-earth metal complexes with four µ2-bridging hydrides. Chem Commun (Camb). 2015 Mar 25; 51(24):5063-5. Rong W, He D, Wang M, Mou Z, Cheng J, Yao C, Li S, Trifonov AA, Lyubov DM, Cui D. PMID: 25713818.
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    26. Highly active, chemo- and regioselective Yb(II) and Sm(II) catalysts for the hydrophosphination of styrene with phenylphosphine. Chemistry. 2015 Apr 13; 21(16):6033-6. Basalov IV, Dorcet V, Fukin GK, Carpentier JF, Sarazin Y, Trifonov AA. PMID: 25760678.
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    27. Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination. Dalton Trans. 2015 Jul 21; 44(27):12137-48. Kissel AA, Mahrova TV, Lyubov DM, Cherkasov AV, Fukin GK, Trifonov AA, Del Rosal I, Maron L. PMID: 25710900.
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    28. Trinuclear alkyl hydrido rare-earth complexes supported by amidopyridinato ligands: synthesis, structures, C-Si bond activation and catalytic activity in ethylene polymerization. Dalton Trans. 2014 Oct 14; 43(38):14450-60. Lyubov DM, Cherkasov AV, Fukin GK, Ketkov SY, Shavyrin AS, Trifonov AA. PMID: 24983231.
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    29. Metal-to-ligand alkyl migration inducing carbon-sulfur bond cleavage in dialkyl yttrium complexes supported by thiazole-containing amidopyridinate ligands: synthesis, characterization, and catalytic activity in the intramolecular hydroamination reaction. Chemistry. 2014 Mar 17; 20(12):3487-99. Lyubov DM, Luconi L, Rossin A, Tuci G, Cherkasov AV, Fukin GK, Giambastiani G, Trifonov AA. PMID: 24616174.
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    30. Reversible switching of coordination mode of ansa bis(amidinate) ligand in ytterbium complexes driven by oxidation state of the metal atom. Inorg Chem. 2014 Feb 03; 53(3):1537-43. Tolpygin AO, Cherkasov AV, Fukin GK, Trifonov AA. PMID: 24446704.
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    31. Divalent heteroleptic ytterbium complexes--effective catalysts for intermolecular styrene hydrophosphination and hydroamination. Inorg Chem. 2014 Feb 03; 53(3):1654-61. Basalov IV, Rosca SC, Lyubov DM, Selikhov AN, Fukin GK, Sarazin Y, Carpentier JF, Trifonov AA. PMID: 24422473.
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    32. Investigation on NMR relaxivity of nano-sized cyano-bridged coordination polymers. Inorg Chem. 2013 Dec 02; 52(23):13402-14. Perrier M, Kenouche S, Long J, Thangavel K, Larionova J, Goze-Bac C, Lascialfari A, Mariani M, Baril N, Guérin C, Donnadieu B, Trifonov A, Guari Y. PMID: 24245933.
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    33. Rare-earth dichloro and bis(alkyl) complexes supported by bulky amido-imino ligand. Synthesis, structure, reactivity and catalytic activity in isoprene polymerization. Dalton Trans. 2013 Jul 07; 42(25):9211-25. Kissel AA, Lyubov DM, Mahrova TV, Fukin GK, Cherkasov AV, Glukhova TA, Cui D, Trifonov AA. PMID: 23511720.
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    34. LiCl-effect on asymmetric intramolecular hydroamination catalyzed by binaphthylamido yttrium complexes. Dalton Trans. 2013 Jan 14; 42(2):507-20. Chapurina Y, Guillot R, Lyubov D, Trifonov A, Hannedouche J, Schulz E. PMID: 23086513.
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    35. Bifunctional mixed-lanthanide cyano-bridged coordination polymers Ln(0.5)Ln'(0.5)(H2O)5[W(CN)8] (Ln/Ln' = Eu3+/Tb3+, Eu3+/Gd3+, Tb3+/Sm3+). Inorg Chem. 2012 Aug 20; 51(16):9005-16. Chelebaeva E, Long J, Larionova J, Ferreira RA, Carlos LD, Almeida Paz FA, Gomes JB, Trifonov A, Guérin C, Guari Y. PMID: 22849813.
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    36. A double addition of Ln-H to a carbon-carbon triple bond and competitive oxidation of ytterbium(II) and hydrido centers. Angew Chem Int Ed Engl. 2012 Apr 02; 51(14):3444-7. Basalov IV, Lyubov DM, Fukin GK, Shavyrin AS, Trifonov AA. PMID: 22374856.
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    37. Catalytic, enantioselective intramolecular hydroamination of primary amines tethered to di- and trisubstituted alkenes. J Org Chem. 2011 Dec 16; 76(24):10163-72. Chapurina Y, Ibrahim H, Guillot R, Kolodziej E, Collin J, Trifonov A, Schulz E, Hannedouche J. PMID: 22059438.
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    38. Near-infrared luminescent and magnetic cyano-bridged coordination polymers Nd(phen)n(DMF)m[M(CN)8] (M = Mo, W). Inorg Chem. 2011 Oct 17; 50(20):9924-6. Long J, Chelebaeva E, Larionova J, Guari Y, Ferreira RA, Carlos LD, Almeida Paz FA, Trifonov A, Guérin C. PMID: 21942867.
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    39. Steric control on the redox chemistry of (?5-C9H7)2Yb(II)(THF)2 by 6-aryl substituted iminopyridines. Dalton Trans. 2011 Oct 28; 40(40):10568-75. Trifonov AA, Shestakov BG, Gudilenkov ID, Fukin GK, Giambastiani G, Bianchini C, Rossin A, Luconi L, Filippi J, Sorace L. PMID: 21566826.
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    40. Selective protonation of the Y-C bond in trinuclear yttrium alkyl-hydrido clusters and formation of the cationic polyhydrido core. Chemistry. 2011 Mar 28; 17(14):3824-6. Lyubov DM, Döring C, Ketkov SY, Kempe R, Trifonov AA. PMID: 21381143.
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    41. Nanoscale coordination polymers exhibiting luminescence properties and NMR relaxivity. Nanoscale. 2011 Mar; 3(3):1200-10. Chelebaeva E, Larionova J, Guari Y, Ferreira RA, Carlos LD, Trifonov AA, Kalaivani T, Lascialfari A, Guérin C, Molvinger K, Datas L, Maynadier M, Gary-Bobo M, Garcia M. PMID: 21258695.
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    42. Scandium alkyl complex with phosphinimino-amine ligand: synthesis, structure and catalysis on ethylene polymerization. Dalton Trans. 2011 Mar 14; 40(10):2151-3. Li D, Li S, Cui D, Zhang X, Trifonov AA. PMID: 21103546.
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    43. Well-defined and easily accessible yttrium complexes for enantioselective cyclisation of amines tethered to 1,2-di-substituted alkenes. Chem Commun (Camb). 2010 Oct 07; 46(37):6918-20. Chapurina Y, Hannedouche J, Collin J, Guillot R, Schulz E, Trifonov A. PMID: 20730194.
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    44. Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates. Dalton Trans. 2010 Sep 28; 39(36):8363-76. Ajellal N, Carpentier JF, Guillaume C, Guillaume SM, Helou M, Poirier V, Sarazin Y, Trifonov A. PMID: 20424735.
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    45. Luminescent and magnetic cyano-bridged coordination polymers containing 4d-4f ions: toward multifunctional materials. Inorg Chem. 2009 Jul 06; 48(13):5983-95. Chelebaeva E, Larionova J, Guari Y, Ferreira RA, Carlos LD, Paz FA, Trifonov A, Guérin C. PMID: 20507102.
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    46. Yttrium complexes supported by linked bis(amide) ligand: synthesis, structure, and catalytic activity in the ring-opening polymerization of cyclic esters. Inorg Chem. 2009 May 04; 48(9):4258-66. Mahrova TV, Fukin GK, Cherkasov AV, Trifonov AA, Ajellal N, Carpentier JF. PMID: 19391633.
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    47. Convenient method for the rapid generation of highly active and enantioselective yttrium catalysts for asymmetric hydroamination. Chem Commun (Camb). 2008 Aug 14; (30):3552-4. Hannedouche J, Aillaud I, Collin J, Schulz E, Trifonov A. PMID: 18654710.
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    48. Lanthanide chloride complexes of amine-bis(phenolate) ligands and their reactivity in the ring-opening polymerization of epsilon-caprolactone. Dalton Trans. 2008 Jul 21; (27):3592-8. Willans CE, Sinenkov MA, Fukin GK, Sheridan K, Lynam JM, Trifonov AA, Kerton FM. PMID: 18594708.
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    49. A Luminescent and magnetic cyano-bridged Tb3+-Mo5+ coordination polymer: toward multifunctional materials. Inorg Chem. 2008 Feb 04; 47(3):775-7. Chelebaeva E, Larionova J, Guari Y, Ferreira RA, Carlos LD, Paz FA, Trifonov A, Guérin C. PMID: 18186631.
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    50. New chiral lanthanide amide ate complexes for the catalysed synthesis of scalemic nitrogen-containing heterocycles. Chemistry. 2008; 14(7):2189-200. Aillaud I, Collin J, Duhayon C, Guillot R, Lyubov D, Schulz E, Trifonov A. PMID: 18081126.
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    51. Bis(guanidinate) alkoxide complexes of lanthanides: synthesis, structures and use in immortal and stereoselective ring-opening polymerization of cyclic esters. Chemistry. 2008; 14(18):5440-8. Ajellal N, Lyubov DM, Sinenkov MA, Fukin GK, Cherkasov AV, Thomas CM, Carpentier JF, Trifonov AA. PMID: 18491334.
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    52. N,N'-diisopropyl-N''-bis(trimethylsilyl)guanidinate ligand as a supporting coordination environment in yttrium chemistry. Synthesis, structure, and properties of complexes [(Me(3)Si)(2)NC(Ni-Pr)(2)]YCl(2)(THF)(2), [(Me(3)Si)(2)NC(Ni-Pr)(2)]Y(CH(2)SiMe(3))(2)(THF)(2), and [(Me(3)Si)(2)NC(Ni-Pr)(2)]Y[(mu-H)(mu-Et)(2)BEt](2)(THF). Inorg Chem. 2007 Dec 24; 46(26):11450-6. Lyubov DM, Fukin GK, Trifonov AA. PMID: 18020328.
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    53. Metal template assembly of highly functionalized octacyanoporphyrazine framework from TCNE structural units. Chem Commun (Camb). 2007 May 21; (19):1942-4. Klapshina LG, Grigoryev IS, Douglas WE, Trifonov AA, Gudilenkov ID, Semenov VV, Bushuk BA, Bushuk SB. PMID: 17695237.
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    54. Ytterbocenes as one- and two-electron reductants in their reactions with diazadienes: YbIII mixed-ligand bent-sandwich complexes containing a dianion of diazabutadiene. Chemistry. 2007; 13(17):4981-7. Trifonov AA, Borovkov IA, Fedorova EA, Fukin GK, Larionova J, Druzhkov NO, Cherkasov VK. PMID: 17366494.
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    55. Postmetallocene lanthanide-hydrido chemistry: A new family of complexes [{Ln{(Me3Si)2NC(NiPr)2}2(mu-H)}2] (Ln = Y, Nd, Sm, Gd, Yb) supported by guanidinate ligands-synthesis, structure, and catalytic activity in olefin polymerization. Chemistry. 2006 Jul 05; 12(20):5320-7. Trifonov AA, Skvortsov GG, Lyubov DM, Skorodumova NA, Fukin GK, Baranov EV, Glushakova VN. PMID: 16680789.
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    56. Bridging mu-eta(5):eta(4)-coordination of an indenyl ligand and reductive coupling of diazabutadienes in the assembly of di- and tetranuclear mixed-valent ytterbium indenyldiazabutadiene complexes. Chemistry. 2006 Mar 20; 12(10):2752-7. Trifonov AA, Fedorova EA, Fukin GK, Baranov EV, Druzhkov NO, Bochkarev MN. PMID: 16425169.
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    57. Enantioselective intramolecular hydroamination catalyzed by lanthanide ate complexes coordinated by N-substituted (R)-1,1'-binaphthyl-2,2'-diamido ligands. J Org Chem. 2006 Mar 17; 71(6):2514-7. Riegert D, Collin J, Meddour A, Schulz E, Trifonov A. PMID: 16526807.
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    58. Lanthanide complexes coordinated by N-substituted (R)-1,1'-binaphthyl-2,2'-diamido ligands in the catalysis of enantioselective intramolecular hydroamination. Chemistry. 2005 May 20; 11(11):3455-62. Collin J, Daran JC, Jacquet O, Schulz E, Trifonov A. PMID: 15786500.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    59. C-C coupling and C-H bond activation-unexpected pathways in the reactions of [Yb(eta5-C13H9)2(thf)2] with diazadienes. Angew Chem Int Ed Engl. 2004 Sep 27; 43(38):5045-8. Trifonov AA, Fedorova EA, Fukin GK, Druzhkov NO, Bochkarev MN. PMID: 15384108.
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    60. Hydrosilylation of dienes by yttrium hydrido complexes containing a linked amido-cyclopentadienyl ligand. Dalton Trans. 2004 Aug 07; (15):2245-50. Trifonov AA, Spaniol TP, Okuda J. PMID: 15278114.
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    61. Lanthanide complexes derived from (R)-1,1'-binaphthyl-2,2'-bis(neopentylamine)--(Li(THF)4)(Ln[(R)-C20H12N2(C10H22)]2) (Ln = Sm, Yb)--novel catalysts for enantioselective intramolecular hydroamination. Chem Commun (Camb). 2003 Dec 21; (24):3048-9. Collin J, Daran JC, Schulz E, Trifonov A. PMID: 14703851.
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